1,527 research outputs found
Prerequisites for Successful Fiscal Reform: Some Preliminary Results
Journal of Public Budgeting, Accounting and Financial Management, Winter 1998.Refereed Journal ArticleThis paper examines whether any relationship exists between
success or failure of policy reform on the one hand, and various
political/economic conditions in place at the time of reform on the other.
Nineteen countries were scored using three financial variables to measure the
degree of success or failure of the reform. The independent variables were
country scores for ten different economic and political conditions. The
independent variables were used to try and predict a priori which of the nineteen
countries would succeed and which would fail. Eighteen of the nineteen
countries were correctly placed into their respective success group. However
only three of the ten conditions appeared important in predicting success: a
visionary leader, a crisis, and a comprehensive program. Other writers have
suggested different sets of predicting variables
Encoding dynamics for multiscale community detection: Markov time sweeping for the Map equation
The detection of community structure in networks is intimately related to
finding a concise description of the network in terms of its modules. This
notion has been recently exploited by the Map equation formalism (M. Rosvall
and C.T. Bergstrom, PNAS, 105(4), pp.1118--1123, 2008) through an
information-theoretic description of the process of coding inter- and
intra-community transitions of a random walker in the network at stationarity.
However, a thorough study of the relationship between the full Markov dynamics
and the coding mechanism is still lacking. We show here that the original Map
coding scheme, which is both block-averaged and one-step, neglects the internal
structure of the communities and introduces an upper scale, the `field-of-view'
limit, in the communities it can detect. As a consequence, Map is well tuned to
detect clique-like communities but can lead to undesirable overpartitioning
when communities are far from clique-like. We show that a signature of this
behavior is a large compression gap: the Map description length is far from its
ideal limit. To address this issue, we propose a simple dynamic approach that
introduces time explicitly into the Map coding through the analysis of the
weighted adjacency matrix of the time-dependent multistep transition matrix of
the Markov process. The resulting Markov time sweeping induces a dynamical
zooming across scales that can reveal (potentially multiscale) community
structure above the field-of-view limit, with the relevant partitions indicated
by a small compression gap.Comment: 10 pages, 6 figure
Strong electron correlations in the normal state of FeSe0.42Te0.58
We investigate the normal state of the '11' iron-based superconductor
FeSe0.42Te0.58 by angle resolved photoemission. Our data reveal a highly
renormalized quasiparticle dispersion characteristic of a strongly correlated
metal. We find sheet dependent effective carrier masses between ~ 3 - 16 m_e
corresponding to a mass enhancement over band structure values of m*/m_band ~ 6
- 20. This is nearly an order of magnitude higher than the renormalization
reported previously for iron-arsenide superconductors of the '1111' and '122'
families but fully consistent with the bulk specific heat.Comment: 5 pages, 4 figures, to appear in Phys. Rev. Let
Oxygen vacancies as active sites for water dissociation on rutile TiO<sub>2</sub>(110)
Through an interplay between scanning tunneling microscopy experiments and density functional theory calculations, we determine unambiguously the active surface site responsible for the dissociation of water molecules adsorbed on rutile TiO2(110). Oxygen vacancies in the surface layer are shown to dissociate H2O through the transfer of one proton to a nearby oxygen atom, forming two hydroxyl groups for every vacancy. The amount of water dissociation is limited by the density of oxygen vacancies present on the clean surface exclusively. The dissociation process sets in as soon as molecular water is able to diffuse to the active site
Antiferromagnetic interlayer exchange coupling across an amorphous metallic spacer layer
By means of magneto-optical Kerr effect we observe for the first time
antiferromagnetic coupling between ferromagnetic layers across an amorphous
metallic spacer layer. Biquadratic coupling occurs at the transition from a
ferromagnetically to an antiferromagnetically coupled region. Scanning
tunneling microscopy images of all involved layers are used to extract
thickness fluctuations and to verify the amorphous state of the spacer. The
observed antiferromagnetic coupling behavior is explained by RKKY interaction
taking into account the amorphous structure of the spacer material.Comment: Typset using RevTex, 4 pages with 4 figures (.eps
Dynamics of heteropolymers in dilute solution: effective equation of motion and relaxation spectrum
The dynamics of a heteropolymer chain in solution is studied in the limit of
long chain length. Using functional integral representation we derive an
effective equation of motion, in which the heterogeneity of the chain manifests
itself as a time-dependent excluded volume effect. At the mean field level, the
heteropolymer chain is therefore dynamically equivalent to a homopolymer chain
with both time-independent and time-dependent excluded volume effects. The
perturbed relaxation spectrum is also calculated. We find that heterogeneity
also renormalizes the relaxation spectrum. However, we find, to the lowest
order in heterogeneity, that the relaxation spectrum does not exhibit any
dynamic freezing, at the point when static (equilibrium) ``freezing''
transition occurs in heteropolymer. Namely, the breaking of
fluctuation-dissipation theorem (FDT) proposed for spin glass dynamics does not
have dynamic effect in heteropolymer, as far as relaxation spectrum is
concerned. The implication of this result is discussed
Kognitiv-psychoedukative Gruppenintervention bei stationären Patienten mit depressiven Erkrankungen – Ergebnisse einer prospektiven Pilotstudie
Background: Psychoeducational interventions that provide disorder-related information in a goal-oriented and structured manner have been integrated in psychiatric and psychotherapeutic approaches. The present cognitive psychoeducational group programme for inpatients with affective disorders is based on a multidimensional functional illness concept which covers aspects of vulnerability, stressors and coping strategies. It covers information about the disorder and its treatment options, building up rewarding activities, cognitive restructuring and relapse prevention. Materials und Methods: This programme was developed and modified at the University of Munich, Department of Psychiatry (LMU). A feasibility study was set up in a follow-up single group design and analyses of variance (ANOVAs) were performed. A total of 231 patients participated in 46 groups. Results: 125 patients evaluated the effectiveness of the programme and its treatment strategies. The group programme was widely accepted among patients that were pharmacologically and psychotherapeutically treated: more than three quarters of the patients rated its contents to be informative, helpful and applicable to everyday living. Conclusions: Inpatients with affective disorders may already benefit from a structured group programme if it takes into account their cognitive and motivational deficits. The group leaders' didactic and psychotherapeutic strategies as well as the patients' exchanging ideas with each other play a central role. In the course of further investigations the programme was differentiated for patients with major depression or bipolar disorders
Bonding of gold nanoclusters to oxygen vacancies on rutile TiO2(110)
Through an interplay between scanning tunneling microscopy (STM) and density functional theory (DFT) calculations, we show that bridging oxygen vacancies are the active nucleation sites for Au clusters on the rutile TiO2(110) surface. We find that a direct correlation exists between a decrease in density of vacancies and the amount of Au deposited. From the DFT calculations we find that the oxygen vacancy is indeed the strongest Au binding site. We show both experimentally and theoretically that a single oxygen vacancy can bind 3 Au atoms on average. In view of the presented results, a new growth model for the TiO2(110) system involving vacancy-cluster complex diffusion is presented
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