2,705 research outputs found
The Influence of the Rhetorical Question on Learning
Two college classes of 45 students were given two sets of materials, each set presented to one group of students with rhetorical questions inserted and to the other group without rhetorical questions. The average value to learning of the questions inserted was 17%
Hexamethylcyclopentadiene: time-resolved photoelectron spectroscopy and ab initio multiple spawning simulations
Progress in our understanding of ultrafast light-induced processes in molecules is best achieved through a close combination of experimental and theoretical approaches. Direct comparison is obtained if theory is able to directly reproduce experimental observables. Here, we present a joint approach comparing time-resolved photoelectron spectroscopy (TRPES) with ab initio multiple spawning (AIMS) simulations on the MS-MR-CASPT2 level of theory. We disentangle the relationship between two phenomena that dominate the immediate molecular response upon light absorption: a spectrally dependent delay of the photoelectron signal and an induction time prior to excited state depopulation in dynamics simulations. As a benchmark molecule, we have chosen hexamethylcyclopentadiene, which shows an unprecedentedly large spectral delay of (310 \ub1 20) fs in TRPES experiments. For the dynamics simulations, methyl groups were replaced by "hydrogen atoms" having mass 15 and TRPES spectra were calculated. These showed an induction time of (108 \ub1 10) fs which could directly be assigned to progress along a torsional mode leading to the intersection seam with the molecular ground state. In a stepladder-type approach, the close connection between the two phenomena could be elucidated, allowing for a comparison with other polyenes and supporting the general validity of this finding for their excited state dynamics. Thus, the combination of TRPES and AIMS proves to be a powerful tool for a thorough understanding of ultrafast excited state dynamics in polyenes.Peer reviewed: YesNRC publication: Ye
Universal behavior of localization of residue fluctuations in globular proteins
Localization properties of residue fluctuations in globular proteins are
studied theoretically by using the Gaussian network model. Participation ratio
for each residue fluctuation mode is calculated. It is found that the
relationship between participation ratio and frequency is similar for all
globular proteins, indicating a universal behavior in spite of their different
size, shape, and architecture.Comment: 4 pages, 3 figures. To appear in Phys. Rev.
Photoionization Dynamics of the Tetraoxo Complexes OsO4 and RuO4
The photoionization dynamics of OsO4 and RuO4, chosen as model systems of small-size mononuclear heavy-metal complexes, has been theoretically studied by the time-dependent density functional theory (TDDFT). Accurate experimental measurements of photoionization dynamics as a benchmarking test for the theory are reported for the photoelectron asymmetry parameters of outer valence ionizations of OsO4, measured in the 17-90 eV photon energy range. The theoretical results are in good agreement with the available experimental data. The observed dynamical behavior of partial cross sections and asymmetry parameters has been related to both the coupling to the continuum of discrete excited states, giving strong modulations in the photon energy dependency, and the atomic composition of the initial ionized states, which determines the rate of decay of ionization probability for increasing excitation energies. Overall, an extensive analysis of the photoionization dynamics for valence and core orbitals is presented, showing good agreement with all the available experimental data. This provides confidence for the validity of the TDDFT approach in describing photoionization of heavy transition element compounds, with the perspective of being used for larger systems. Further experimental work is suggested for RuO4 to gather evidence of the sensitivity of the theoretical method to the nature of the metal atom
A Search for Jet Handedness in Hadronic Decays
We have searched for signatures of polarization in hadronic jets from decays using the ``jet handedness'' method. The polar angle
asymmetry induced by the high SLC electron-beam polarization was used to
separate quark jets from antiquark jets, expected to be left- and
right-polarized, respectively. We find no evidence for jet handedness in our
global sample or in a sample of light quark jets and we set upper limits at the
95% C.L. of 0.063 and 0.099 respectively on the magnitude of the analyzing
power of the method proposed by Efremov {\it et al.}Comment: Revtex, 8 pages, 2 figure
Fermi-LAT observations of the exceptional gamma-ray outbursts of 3C 273 in September 2009
We present the light curves and spectral data of two exceptionally luminous
gamma-ray outburts observed by the Large Area Telescope (LAT) experiment on
board Fermi Gamma-ray Space Telescope from 3C 273 in September 2009. During
these flares, having a duration of a few days, the source reached its highest
gamma-ray flux ever measured. This allowed us to study in some details their
spectral and temporal structures. The rise and decay are asymmetric on
timescales of 6 hours, and the spectral index was significantly harder during
the flares than during the preceding 11 months. We also found that short, very
intense flares put out the same time-integrated energy as long, less intense
flares like that observed in August 2009.Comment: Corresponding authors: E. Massaro, [email protected]; G.
Tosti, [email protected]. 15 pages, 4 figures, published in The
Astrophysical Journal Letters, Volume 714, Issue 1, pp. L73-L78 (2010
Measurement of the branching ratios of the Z0 into heavy quarks
We measure the hadronic branching ratios of the Z0 boson into heavy quarks:
Rb=Gamma(Z0->bb)/Gamma(Z0->hadrons) and Rc=Gamma(Z0->cc/Gamma(Z0->hadrons)
using a multi-tag technique. The measurement was performed using about 400,000
hadronic Z0 events recorded in the SLD experiment at SLAC between 1996 and
1998. The small and stable SLC beam spot and the CCD-based vertex detector were
used to reconstruct bottom and charm hadron decay vertices with high efficiency
and purity, which enables us to measure most efficiencies from data. We obtain,
Rb=0.21604 +- 0.00098(stat.) +- 0.00073(syst.) -+ 0.00012(Rc) and, Rc= 0.1744
+- 0.0031(stat.) +- 0.0020(syst.) -+ 0.0006(Rb)Comment: 37 pages, 8 figures, to be submitted to Phys. Rev. D version 2:
changed title to ratios, used common D production fractions for Rb and Rc and
corrected Zgamma interference. Identical to PRD submissio
Constraints on dark matter models from a Fermi LAT search for high-energy cosmic-ray electrons from the Sun
During its first year of data taking, the Large Area Telescope (LAT) onboard
the Fermi Gamma-Ray Space Telescope has collected a large sample of high-energy
cosmic-ray electrons and positrons (CREs). We present the results of a
directional analysis of the CRE events, in which we searched for a flux excess
correlated with the direction of the Sun. Two different and complementary
analysis approaches were implemented, and neither yielded evidence of a
significant CRE flux excess from the Sun. We derive upper limits on the CRE
flux from the Sun's direction, and use these bounds to constrain two classes of
dark matter models which predict a solar CRE flux: (1) models in which dark
matter annihilates to CREs via a light intermediate state, and (2) inelastic
dark matter models in which dark matter annihilates to CREs.Comment: 18 pages, 8 figures, accepted for publication in Physical Review D -
contact authors: Francesco Loparco ([email protected]), M. Nicola Mazziotta
([email protected]) and Jennifer Siegal-Gaskins ([email protected]
Direct Measurements of A_b and A_c using Vertex/Kaon Charge Tags at SLD
Exploiting the manipulation of the SLC electron-beam polarization, we present
precise direct measurements of the parity violation parameters A_c and A_b in
the Z boson - c quark and Z boson - b quark coupling. Quark/antiquark
discrimination is accomplished via a unique algorithm that takes advantage of
the precise SLD CCD vertex detector, employing the net charge of displaced
vertices as well as the charge of kaons that emanate from those vertices. From
the 1996-98 sample of 400,000 Z decays, produced with an average beam
polarization of 73.4%, we find A_c = 0.673 +/- 0.029 (stat.) +/- 0.023 (syst.)
and A_b = 0.919 +/- 0.018 (stat.) +/- 0.017 (syst.).Comment: 11 pages, 2 figures, 2 tables, to be submitted to Physical Review
Letters; version 2 reflects changes suggested by the refere
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