Single-Photon Molecular Cooling

We propose a general method to cool the translational motion of molecules. Our method is an extension of single photon atomic cooling which was successfully implemented in our laboratory. Requiring a single event of absorption followed by a spontaneous emission, this method circumvents the need for a cycling transition and can be applied to any paramagnetic or polar molecule. In our approach, trapped molecules would be captured near their classical turning points in an optical dipole or RF-trap following an irreversible transition process

A Tale of Two Languages. Latin, the Vernacular, and Leonardo Bruni’s Civic Humanism

A Tale of Two Languages. Latin, the Vernacular, and Leonardo Bruni’s Civic Humanism  This article reconstructs the views of Leonardo Bruni concerning the different natures, historical trajectories, and domains of Latin and the Florentine vernacular. It argues that his encomia of Florentine culture are careful to distinguish the two, and indeed that this distinction holds the key to reconciling the seemingly contradictory positions regarding Dante, Petrarch, and Boccaccio espoused in his Dialogues for Pier Paolo Vergerio. Bruni’s concept of the Latin language, moreover, explains why he believed that humanists were required to restore it to its Ciceronian glory. If Latin regained the functions it had had in Cicero’s day, this would exclude the Ciompi and the lower guilds from Florentine politics, and thus refashion Florence in the image of the Roman Republic both linguistically and politically. The article therefore salvages some of Hans Baron’s civic humanism, in that it shows Bruni – Baron’s archetypical civic humanist – to advocate self-government by the Latinate elites

Hanle effect in the CN violet system with LTE modeling

Weak entangled magnetic fields with mixed polarity occupy the main part of the quiet Sun. The Zeeman effect diagnostics fails to measure such fields because of cancellation in circular polarization. However, the Hanle effect diagnostics, accessible through the second solar spectrum, provides us with a very sensitive tool for studying the distribution of weak magnetic fields on the Sun. Molecular lines are very strong and even dominate in some regions of the second solar spectrum. The CN $B {}^{2} \Sigma - X {}^{2} \Sigma$ system is one of the richest and most promising systems for molecular diagnostics and well suited for the application of the differential Hanle effect method. The aim is to interpret observations of the CN $B {}^{2} \Sigma - X {}^{2} \Sigma$ system using the Hanle effect and to obtain an estimation of the magnetic field strength. We assume that the CN molecular layer is situated above the region where the continuum radiation is formed and employ the single-scattering approximation. Together with the Hanle effect theory this provides us with a model that can diagnose turbulent magnetic fields. We have succeeded in fitting modeled CN lines in several regions of the second solar spectrum to observations and obtained a magnetic field strength in the range from 10--30 G in the upper solar photosphere depending on the considered lines.Comment: Accepted for publication in Astronomy and Astrophysic

Die Aufhebung der Coagulationsfähigkeit gewisser Eiweisskörper durch metallisches Silber.

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Modelling the molecular Zeeman effect in M-dwarfs: methods and first results

We present first quantitative results of the surface magnetic field measurements in selected M-dwarfs based on detailed spectra synthesis conducted simultaneously in atomic and molecular lines of the FeH Wing-Ford $F^4\,\Delta-X^4\,\Delta$ transitions. A modified version of the Molecular Zeeman Library (MZL) was used to compute Land\'e g-factors for FeH lines in different Hund's cases. Magnetic spectra synthesis was performed with the Synmast code. We show that the implementation of different Hund's case for FeH states depending on their quantum numbers allows us to achieve a good fit to the majority of lines in a sunspot spectrum in an automatic regime. Strong magnetic fields are confirmed via the modelling of atomic and FeH lines for three M-dwarfs YZ~CMi, EV~Lac, and AD~Leo, but their mean intensities are found to be systematically lower than previously reported. A much weaker field ($1.7-2$~kG against $2.7$~kG) is required to fit FeH lines in the spectra of GJ~1224. Our method allows us to measure average magnetic fields in very low-mass stars from polarized radiative transfer. The obtained results indicate that the fields reported in earlier works were probably overestimated by about $15-30$\%. Higher quality observations are needed for more definite results.Comment: Accepted by A&A, 13 pages, 7 figures, 1 tabl

A Conduit System Distributes Chemokines and Small Blood-borne Molecules through the Splenic White Pulp

Access to the splenic white pulp is restricted to lymphocytes and dendritic cells. Here we show that movement of molecules from the blood into these confined areas is also limited. Large molecules, such as bovine serum albumin (68 kD), immunoglobulin G (150 kD), and 500 kD dextran are unable to enter the white pulp, whereas smaller blood-borne molecules can directly permeate this compartment. The distribution is restricted to a stromal network that we refer to as the splenic conduit system. The small lumen of the conduit contains collagen fibers and is surrounded in the T cell areas by reticular fibroblasts that express ER-TR7. It also contains the chemokine CCL21. Conversely, in B cell follicles the B cell–attracting chemokine CXCL13 was found to be associated with the conduit and absence of ER-TR7+ fibroblasts. These results show heterogeneity of reticular fibroblasts that enfold the conduit system and suggest that locally produced chemokines are transported through and presented on this reticular network. Therefore, the conduit plays a role in distribution of both blood-borne and locally produced molecules and provides a framework for directing lymphocyte migration and organization of the splenic white pulp

Radiative association and inverse predissociation of oxygen atoms

The formation of \mbox{O}_2 by radiative association and by inverse predissociation of ground state oxygen atoms is studied using quantum-mechanical methods. Cross sections, emission spectra, and rate coefficients are presented and compared with prior experimental and theoretical results. At temperatures below 1000~K radiative association occurs by approach along the $1\,{}^3\Pi_u$ state of \mbox{O}_2 and above 1000~K inverse predissociation through the \mbox{B}\,{}^3\Sigma_u^- state is the dominant mechanism. This conclusion is supported by a quantitative comparison between the calculations and data obtained from hot oxygen plasma spectroscopy.Comment: submitted to Phys. Rev. A (Sept. 7., 1994), 19 pages, 4 figures, latex (revtex3.0 and epsf.sty

The circumstellar shell of the post-AGB star HD 56126: the 12^{12}CN/13^{13}CN isotope ratio and fractionation

We have detected circumstellar absorption lines of the $^{12}$CN and $^{13}$CN Violet and Red System in the spectrum of the post-AGB star HD~56126. From a synthetic spectrum analysis, we derive a Doppler broadening parameter of $b=0.51\pm0.04$ km~s$^{-1}$, $^{12}$CN/$^{13}$CN$=38\pm2$, and a lower limit of $2000$ on $^{12}$CN/$^{14}$CN and $^{12}$C$^{14}$N/$^{12}$C$^{15}$N. A simple chemical model has been computed of the circumstellar shell surrounding HD~56126 that takes into account the gas-phase ion-molecule reaction between CN and C$^{+}$. From this we infer that this reaction leads to isotopic fractionation of CN. Taking into account the isotopic exchange reaction and the observed $^{12}$CN/$^{13}$CN we find $^{12}$C/$^{13}$C$\sim 67$ (for $T_{\rm kin}=25$ K). Our analysis suggests that $^{12}$CN has a somewhat higher rotational temperature than $^{13}$CN: $T_{\rm rot}=11.5\pm0.6$ and $8.0\pm0.6$ K respectively. We identify possible causes for this difference in excitation temperature, among which the $N''$ dependence of the isotopic exchange reaction.Comment: 24 pages, 6 figues Apj accepte

Controlled production of atomic oxygen and nitrogen in a pulsed radio-frequency atmospheric-pressure plasma

International audienceRadio-frequency driven atmospheric pressure plasmas are efficient sources for the production of reactive species at ambient pressure and close to room temperature. Pulsing the radio-frequency power input provides additional control over species production and gas temperature. Here, we demonstrate the controlled production of highly reactive atomic oxygen and nitrogen in a pulsed radio-frequency ( ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn001.gif] 13.56 MHz) atmospheric-pressure plasma, operated with a small ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn002.gif] 0.1 % air-like admixture ( ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn003.gif] \rm N_2 / ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn004.gif] \rm O_2 at ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn005.gif] 4:1 ) through variations in the duty cycle. Absolute densities of atomic oxygen and nitrogen are determined through vacuum-ultraviolet absorption spectroscopy using the DESIRS beamline at the SOLEIL synchrotron coupled with a high resolution Fourier-transform spectrometer. The neutral-gas temperature is measured using nitrogen molecular optical emission spectroscopy. For a fixed applied-voltage amplitude (234?V), varying the pulse duty cycle from 10% to 100% at a fixed 10?kHz pulse frequency enables us to regulate the densities of atomic oxygen and nitrogen over the ranges of ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn006.gif] (0.18±0.03) ? ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn007.gif] (3.7±0.1)× 10^20 ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn008.gif] \rm m^-3 and ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn009.gif] (0.2±0.06) ? ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn010.gif] (4.4±0.8) × 10^19 ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn011.gif] \rm m^-3 , respectively. The corresponding 11?K increase in the neutral-gas temperature with increased duty cycle, up to a maximum of ##IMG## [http://ej.iop.org/images/0022-3727/50/45/455204/daa8da2ieqn012.gif] (314±4) K, is relatively small. This additional degree of control, achieved through regulation of the pulse duty cycle and time-averaged power, could be of particular interest for prospective biomedical applications

A global corporate census: publicly traded and close companies in 1910

In 1910 the world had almost half a million corporations, only one-hundredth of today's total. About one-fifth—with over half of corporate capital—were publicly tradable, higher portions than today. Most publicly quoted corporations traded in Europe and the British Empire, but most close (private) corporations operated in the US, which, until the 1940s, had more corporations per capita than anywhere else. The 83 countries surveyed here differed markedly in company numbers, corporate capital/GDP ratios, and average corporate size. Enclave economies—dominated by quoted (and often foreign-owned) companies—had the largest average sizes, while other nations had more varied mixes of large quoted corporations and close company small and medium enterprises