The Multifragmentation Freeze--Out Volume in Heavy Ion Collisions

The reduced velocity correlation function for fragments from the reaction Fe + Au at 100 A~MeV bombarding energy is investigated using the dynamical--statistical approach QMD+SMM and compared to experimental data to extract the Freeze--Out volume assuming simultaneous multifragmentation.Comment: 8 pages; 3 uuencoded figures available with figures command, LateX, UCRL-J-1157

Generation of Intrinsic Vibrational Gap Modes in Three-Dimensional Ionic Crystals

The existence of anharmonic localization of lattice vibrations in a perfect 3-D diatomic ionic crystal is established for the rigid-ion model by molecular dynamics simulations. For a realistic set of NaI potential parameters, an intrinsic localized gap mode vibrating in the [111] direction is observed for fcc and zinc blende lattices. An axial elastic distortion is an integral feature of this mode which forms more readily for the zinc blende than for the fcc structure. Molecular dynamics simulations verify that in each structure this localized mode may be stable for at least 200 cycles.Comment: 5 pages, 4 figures, RevTeX, using epsf.sty. To be published in Phys. Rev. B. Also available at http://www.msc.cornell.edu/~kiselev

Fine-tuning the balance between peptide thioester cyclization and racemization

Ring-closure towards seven-membered bislactams containing an -amino acid and -alanine is problematic. Such difficult lactamizations are accompanied by side-reactions such as hydrolysis, oligomerization and racemization. By starting from linear peptide 4-methoxythiophenol esters, dilution to 1 mM in combination with phosphate buffer (pH 6.8) intermolecular reactions and racemization could be largely suppressed. Thioesters with the chiral residue at the C-terminus gave the bislactams in yields up to 60% and enantiomeric excess up to 99%. Enantiopure bislactams were obtained exclusively from the reversed sequence bearing -alanine at the C-terminus

quasiharmonic equations of state for dynamically-stabilized soft-mode materials

We introduce a method for treating soft modes within the analytical framework of the quasiharmonic equation of state. The corresponding double-well energy-displacement relation is fitted to a functional form that is harmonic in both the low- and high-energy limits. Using density-functional calculations and statistical physics, we apply the quasiharmonic methodology to solid periclase. We predict the existence of a B1--B2 phase transition at high pressures and temperatures

Optimization of the design of OMNIS, the observatory of multiflavor neutrinos from supernovae

A Monte Carlo code has been developed to simulate the operation of the planned detectors in OMNIS, a supernova neutrino observatory. OMNIS will detect neutrinos originating from a core collapse supernova by the detection of spalled neutrons from Pb- or Fe-nuclei. This might be accomplished using Gd-loaded liquid scintillator. Results for the optimum configuration for such modules with respect to both neutron detection efficiency and cost efficiency are presented. Careful consideration has been given to the expected levels of radioactive backgrounds and their effects. The results show that the amount of data to be processed by a software trigger can be reduced to the <10kHz region and a neutron, once produced in the detector, can be detected and identified with an efficiency of >30%.Comment: Elsevier preprint; 29 pages, 23 figure

The importance of initial-final state correlations for the formation of fragments in heavy ion collisions

Using quantum molecular dynamics simulations, we investigate the formation of fragments in symmetric reactions between beam energies of E=30AMeV and 600AMeV. After a comparison with existing data we investigate some observables relevant to tackle equilibration: dsigma/dErat, the double differential cross section dsigma/pt.dpz.dpt,... Apart maybe from very energetic E>400AMeV and very central reactions, none of our simulations gives evidence that the system passes through a state of equilibrium. Later, we address the production mechanisms and find that, whatever the energy, nucleons finally entrained in a fragment exhibit strong initial-final state correlations, in coordinate as well as in momentum space. At high energy those correlations resemble the ones obtained in the participant-spectator model. At low energy the correlations are equally strong, but more complicated; they are a consequence of the Pauli blocking of the nucleon-nucleon collisions, the geometry, and the excitation energy. Studying a second set of time-dependent variables (radii, densities,...), we investigate in details how those correlations survive the reaction especially in central reactions where the nucleons have to pass through the whole system. It appears that some fragments are made of nucleons which were initially correlated, whereas others are formed by nucleons scattered during the reaction into the vicinity of a group of previously correlated nucleons.Comment: 45 pages text + 20 postscript figures Accepted for publication in Physical Review

Measurement of the electron electric dipole moment using YbF molecules

The most sensitive measurements of the electron electric dipole moment d_e have previously been made using heavy atoms. Heavy polar molecules offer a greater sensitivity to d_e because the interaction energy to be measured is typically 10^3 times larger than in a heavy atom. We report the first measurement of this kind, for which we have used the molecule YbF. Together, the large interaction energy and the strong tensor polarizability of the molecule make our experiment essentially free of the systematic errors that currently limit d_e measurements in atoms. Our first result d_e = (- 0.2 \pm 3.2) x 10^-26 e.cm is less sensitive than the best atom measurement, but is limited only by counting statistics and demonstrates the power of the method.Comment: 4 pages, 4 figures. v2. Minor corrections and clarifications made in response to referee comment

Measurements of Ion Stopping Around the Bragg Peak in High-Energy-Density Plasmas

For the first time, quantitative measurements of ion stopping at energies around the Bragg peak (or peak ion stopping, which occurs at an ion velocity comparable to the average thermal electron velocity), and its dependence on electron temperature (T[subcontract e]) and electron number density (n[subcontract e]) in the range of 0.5–4.0 keV and 3 × 10[superscript 22] to 3 × 10[superscript 23]  cm[superscript −3] have been conducted, respectively. It is experimentally demonstrated that the position and amplitude of the Bragg peak varies strongly with T[subscript e] with n[subscript e]. The importance of including quantum diffraction is also demonstrated in the stopping-power modeling of high-energy-density plasmas.United States. Dept. of Energy (Grant DE-FG03-03SF22691)Lawrence Livermore National Laboratory (Subcontract Grant B504974)University of Rochester. Laboratory for Laser Energetics (Subcontract Grant 412160-001G