Photoinduced Gratings in Functionalized Azo-Carbazole Compounds in Picosecond Regime

We report results of diffraction grating inscription on thin films prepared from epoxy resin doped with azo-carbazole based dyes. Diffraction gratings were recorded at the wavelength 532 nm and monitored through intensity of first order of diffraction (632 nm). Atomic force microscope scans of the gratings show that a surface relief grating also appeared

A Case Study of Anomalous Snowfall with an Alberta Clipper

An Alberta clipper moved over western New York state on 11-12 January 2004, producing snowfall amounts of up to 27 cm in portions of the region during a roughly 12-h period. In addition, lightning and thunder were reported. Such systems, known primarily for their fast motion and relatively dry nature, are not generally associated with significant snowfalls. A postmortem analysis of this event, following an ingredients-based methodology, revealed that as the weak low approached the lower Great Lakes, it came under the influence of coupled 300-hPa jets that produced enhanced divergence and significant upward vertical motion over western New York, resulting in the enhanced convective snowfall over the region for a limited time. Instability and possible enhancement via the Great Lakes are also investigated, which show that while there was at least modest instability over the region during the time of heavy snowfall, lake enhancement was unlikely

An operational analysis of Lake Surface Water Temperature

Operational analyses of Lake Surface Water Temperature (LSWT) have many potential uses including improvement of numerical weather prediction (NWP) models on regional scales. In November 2011, LSWT was included in the Met Office Operational Sea Surface Temperature and Ice Analysis (OSTIA) product, for 248 lakes globally. The OSTIA analysis procedure, which has been optimised for oceans, has also been used for the lakes in this first version of the product. Infra-red satellite observations of lakes and in situ measurements are assimilated. The satellite observations are based on retrievals optimised for Sea Surface Temperature (SST) which, although they may introduce inaccuracies into the LSWT data, are currently the only near-real-time information available. The LSWT analysis has a global root mean square difference of 1.31 K and a mean difference of 0.65 K (including a cool skin effect of 0.2 K) compared to independent data from the ESA ARC-Lake project for a 3-month period (June to August 2009). It is demonstrated that the OSTIA LSWT is an improvement over the use of climatology to capture the day-to-day variation in global lake surface temperatures

Global wealth disparities drive adherence to COVID-safe pathways in head and neck cancer surgery

Peer reviewe

A numerical investigation of wind speed effects on lake-effect storms

Observations of lake-effect storms that occur over the Great Lakes region during late autumn and winter indicate a high sensitivity to ambient wind speed and direction. In this paper, a two-dimensional version of the Penn State University/National Center for Atmospheric Research (PSU/NCAR) model is used to investigate the wind speed effects on lake-effect snowstorms that occur over the Great Lakes region.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/42510/1/10546_2004_Article_BF00708966.pd

MAGNETIC STRUCTURE OF CuxZn1-xCr2Se4

Magnetic and neutron diffraction measurements on CuxZn1-xCr2Se4 yield a simple spiral structure for x = 0.02 and a conical one for x = 0.11 below 21 K. Cu0.11Zn0.89Cr2Se4 proved to be of the magnetic cluster glass type in contradiction with theoretical predictions of Krok et al. for 0.05 ≤ x ≤ 0.2 [5]

COMMENSURATE-INCOMMENSURATE PHASE TRANSITION IN (Co1-xMnx)2P

Neutron diffraction, a.c. initial magnetic susceptibility, magnetization, and heat capacity measurements allow a better understanding of the metamagnetic-like phase observed at low temperature in (Co1-xMnx)2P. The magnetic structures and phase transitions for x = 0.6 and 0.75 have been determined

Spectral and electrochemical studies on blends of polyaniline and cellulose esters

Blends of chemically prepared polyaniline emeraldine base (PANi) with cellulose esters were studied as films by UV-visible spectroscopy and cyclic voltammetry. The cellulose esters used were acetate, propionate, acetate butyrate, and acetate hydrogen phthalate. Films were prepared by casting from N-methylpyrrolidone or formic acid, and the effect of doping by acids on their spectral and electrochemical properties was studied. Similar behavior was observed with the acetate, propionate, or acetate butyrate, with spectral changes on adding acid due to protonation of the PANi. In agreement with previous studies, kinetic measurements on PANi in a cellulose acetate matrix shows a relatively slow spectral change on protonation. In contrast, with cellulose acetate hydrogen phthalate (CAHP), no changes were observed on adding acid, and it is suggested that the hydrogen phthalate group acts as proton donor. This was mirrored by the cyclic voltammetry behavior in hydrochloric acid solution. Electrochemical studies on films of PANi/CAHP blends in different relative proportions in sulfuric acid solution show a marked dependence on the solvent used for casting, with higher currents and better electrical conductivity being observed in films prepared from N-methylpyrrolidone. This is shown to be due to the presence of PANi particles in the films. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2182-2188, 200