Stability and performance enhancements of Electrokinetic-Fenton soil remediation

<p>Electrokinetic process is a potential in situ soil remediation process which transports the contaminants via electromigration and electroosmosis. For organic compounds contaminated soil, Fenton’s reagent is utilized as a flushing agent in electrokinetic process (Electrokinetic-Fenton) so that removal of organic contaminants could be achieved by in situ oxidation/destruction. However, this process is not applied widely in industries as the stability issue for Fenton’s reagent is the main drawback. The aim of this mini review is to summarize the developments of Electrokinetic-Fenton process on enhancing the stability of Fenton’s reagent and process efficiency in past decades. Generally, the enhancements are conducted via four paths: i) chemical stabilization to delay H2O2 decomposition, ii) increase of oxidant availability by monitoring injection method for Fenton’s reagent, iii) electrodes operation and iron catalysts and iv) operating conditions such as voltage gradient, electrolytes and H2O2 concentration. In addition, the types of soils and contaminants are also showing significant effect as the soil with low acid buffering capacity, adequate iron concentration, low organic matter content and low aromatic ring organic contaminants generally gives better efficiency.</p

Advances in water treatment technologies for removal of polycyclic aromatic hydrocarbons: Existing concepts, emerging trends, and future prospects

In the last two decades, environmental experts have focused on the development of several biological, chemical, physical, and thermal methods/technologies for remediation of PAH-polluted water. Some of the findings have been applied to field-scale treatment, while others have remained as prototypes and semi-pilot studies. Existing treatment options include extraction, chemical oxidation, bioremediation, photocatalytic degradation, and adsorption (employing adsorbents such as biomass derivatives, geosorbents, zeolites, mesoporous silica, polymers, nanocomposites, and graphene-based materials). Electrokinetic remediation, advanced phytoremediation, green nanoremediation, enhanced remediation using biocatalysts, and integrated approaches are still at the developmental stage and hold great potential. Water is an essential component of the ecosystem and highly susceptible to PAH contamination due to crude oil exploration and spillage, and improper municipal and industrial waste management, yet comprehensive reviews on PAH remediation are only available for contaminated soils, despite the several treatment methods developed for the remediation of PAH-polluted water. This review seeks to provide a comprehensive overview of existing and emerging methods/technologies, in order to bridge information gaps toward ensuring a green and sustainable remedial approach for PAH-contaminated aqueous systems.University of Pretoriahttps://onlinelibrary.wiley.com/journal/155475312021-08-01hj2021Chemistr