The Microstructure of Pyrite Blackening in Fossil Shells

The Waynesville formation is part of the stratigraphic succession of Indiana bedrock which allows us to look back on environmental conditions during the late Ordovician period, 450 million years ago. Due in part to a fossil record which is overwhelminlgly dominated by a single species, the Waynesville formation functions as an outdoor labratory illustrating various preservation processes operating on directly comparable shells. Shell blackening during preservation has been a particular point of interest. Based on the correlation of shell blackening with occurrences of shell fragmentation and abrasion in large brachiopods, the shell blackening seen in Upper Ordovician (Cincinnatian) brachiopods has previously been identified as a sign of long residence on the sea floor, and has been attributed to the accumulation of iron sulfides and organics in microborings. This in turn suggests extremely low oxygen microenvironments within shells. The results of our studies are broadly consistent with prior hypotheses.http://opus.ipfw.edu/stu_symp2015/1055/thumbnail.jp

A Simple Model for r-Process Scatter and Halo Evolution

Recent observations of heavy elements produced by rapid neutron capture (r-process) in the halo have shown a striking and unexpected behavior: within a single star, the relative abundances of r-process elements heavier than Eu are the same as the same as those of solar system matter, while across stars with similar metallicity Fe/H, the r/Fe ratio varies over two orders of magnitude. In this paper we present a simple analytic model which describes a star's abundances in terms of its ``ancestry,'' i.e., the number of nucleosynthesis events (e.g., supernova explosions) which contributed to the star's composition. This model leads to a very simple analytic expression for the abundance scatter versus Fe/H, which is in good agreement with the data and with more sophisticated numerical models. We investigate two classes of scenarios for r-process nucleosynthesis, one in which r-process synthesis events occur in only \sim 4% of supernovae but iron synthesis is ubiquitous, and one in which iron nucleosynthesis occurs in only about 9% of supernovae. (the Wasserburg- Qian model). We find that the predictions in these scenarios are similar for [Fe/H] \ga -2.5, but that these models can be readily distinguished observationally by measuring the dispersion in r/Fe at [Fe/H] \la -3.Comment: AASTeX, 21 pages, includes 4 figure

The decompression of the outer neutron star crust and r-process nucleosynthesis

The rapid neutron-capture process, or r-process, is known to be fundamental for explaining the origin of approximately half of the A>60 stable nuclei observed in nature. In recent years nuclear astrophysicists have developed more and more sophisticated r-process models, by adding new astrophysical or nuclear physics ingredients to explain the solar system composition in a satisfactory way. Despite these efforts, the astrophysical site of the r-process remains unidentified. The composition of the neutron star outer crust material is investigated after the decompression that follows its possible ejection. The composition of the outer crust of a neutron star is estimated before and after decompression. Two different possible initial conditions are considered, namely an idealized crust composed of cold catalyzed matter and a crust initially in nuclear statistical equilibrium at temperatures around 10 GK. We show that in this second case before decompression and at temperatures typically corresponding to 8 GK, the Coulomb effect due to the high densities in the crust leads to an overall composition of the outer crust in neutron-rich nuclei with a mass distribution close to the solar system r-abundance distribution. Such distributions differ, however, from the solar one due to a systematic shift in the second peak to lower values. After decompression, the capture of the few neutrons per seed nucleus available in the hot outer crust leads to a final distribution of stable neutron-rich nuclei with a mass distribution of 80 < A < 140 nuclei in excellent agreement with the solar distribution, provided the outer crust is initially at temperatures around 8 GK and all layers of the outer crust are ejected. The decompression of the neutron star matter from the outer crust provides suitable conditions for a robust r-processing of the light species, i.e., r-nuclei with A < 140.Comment: 11 pages, 16 figures; Accepted in A&A main Journa

Pre-galactic metal enrichment - The chemical signatures of the first stars

The emergence of the first sources of light at redshifts of z ~ 10-30 signaled the transition from the simple initial state of the Universe to one of increasing complexity. We review recent progress in our understanding of the formation of the first stars and galaxies, starting with cosmological initial conditions, primordial gas cooling, and subsequent collapse and fragmentation. We emphasize the important open question of how the pristine gas was enriched with heavy chemical elements in the wake of the first supernovae. We conclude by discussing how the chemical abundance patterns conceivably allow us to probe the properties of the first stars and subsequent stellar generations, and allow us to test models of early metal enrichment.Comment: 52 pages, 20 figures, clarifications, references added, accepted for publication in the Reviews of Modern Physic

NLTE determination of the aluminium abundance in a homogeneous sample of extremely metal-poor stars

Aims: Aluminium is a key element to constrain the models of the chemical enrichment and the yields of the first supernovae. But obtaining precise Al abundances in extremely metal-poor (EMP) stars requires that the non-LTE effects be carefully taken into account. Methods: The NLTE profiles of the blue resonance aluminium lines have been computed in a sample of 53 extremely metal-poor stars with a modified version of the program MULTI applied to an atomic model of the Al atom with 78 levels of Al I and 13 levels of Al II, and compared to the observations. Results: With these new determinations, all the stars of the sample show a ratio Al/Fe close to the solar value: [Al/Fe] =-0.06 +- 0.10 with a very small scatter. These results are compared to the models of the chemical evolution of the halo using different models of SN II and are compatible with recent computations. The sodium-rich giants are not found to be also aluminium-rich and thus, as expected, the convection in these giants only brings to the surface the products of the Ne-Na cycle.Comment: To be published on A&

Linking the Metallicity Distribution of Galactic Halo Stars to the Enrichment History of the Universe

We compare the metallicity distribution of Galactic Halo stars with 3D realizations of hierarchical galaxy formation. Outflows from dwarf galaxies enrich the intergalactic medium inhomogeneously, at a rate depending on the local galaxy density. Consequently, the first stars created in small early-forming galaxies are less metal-rich that the first stars formed in more massive galaxies which typically form later. As most halo stars are likely to originate in accreted dwarfs, while disk stars formed out of outflow-enriched gas, this scenario naturally generates a ``metallicity floor'' for old disk stars, which we find to be roughly coincident with the higher end of our predicted metallicity distribution of halo stars, in agreement with observations. The broad and centrally peaked distribution of halo star metallicities is well reproduced in our models, with a natural dispersion depending on the exact accretion history. Our modeling includes the important ``baryonic stripping'' effect of early outflows, which brush away the tenuously held gas in neighboring pre-virialized density perturbations. This stripping process does not significantly modify the predicted shape of the halo star metal distribution but inhibits star-formation and hence the number of accreted stars, helping to reproduce the observed total Galactic halo luminosity and also the lack of low-luminosity local dwarf galaxies relative to N-body predictions.Comment: 5 pages, 1 figure, ApJ Letters, accepte

The NLTE Barium Abundance in Dwarf Stars in the Metallicity Range of -1 < [Fe/H] < +0.3

We present the results of determination of the barium abundance considering the non-LTE (NLTE) effects in 172 dwarf stars in the metallicity range of -1< [Fe/H] <+0.3, assigned to different Galactic substructures by kinematic criteria. We used a model of the Ba atom with 31 levels of Ba I and 101 levels of Ba II. The atmosphere models for the investigated stars were computed using the ATLAS9 code modified by new opacity distribution functions. The NLTE profiles of the unblended Ba II (4554 A, 5853 A, 6496 A) were computed and then compared to those observed. The line 6141 A was also used, but with an allowance for its correlation with the iron line. The average barium abundances in the thin and thick discs are 0.01 +/- 0.08 and -0.03 +/- 0.07, respectively. The comparison to the calculations of the Galactic chemical evolution by Serminato et al. (2009) was conducted. The trend obtained for the Ba abundance versus [Fe/H] suggests a complex barium production process in the thin and thick discs

The barium isotopic mixture for the metal-poor subgiant star HD140283

Current theory regarding heavy element nucleosynthesis in metal-poor environments states that the r-process would be dominant. The star HD140283 has been the subject of debate after it appeared in some studies to be dominated by the s-process. We provide an independent measure of the Ba isotope mixture in HD140283 using an extremely high quality spectrum and an extensive chi^2 analysis. We exploit hyperfine splitting of the BaII 4554 \AA\ and 4934 \AA\ resonance lines in an effort to constrain the isotope ratio in 1D LTE. Using the code ATLAS in conjunction with KURUCZ06 model atmospheres we analyse 93 Fe lines to determine the star's macroturbulence. With this information we construct a grid of Ba synthetic spectra and, using a \chi^2 code, fit these to our observed data to determine the isotopic ratio, fodd, which represents the ratio of odd to even isotopes. We also analyse the Eu lines. We set a new upper limit of the rotation of HD140283 at vsin{i}\leq3.9\kms, a new upper limit on [Eu/H] < -2.80 and abundances [Fe/H] = -2.59\pm0.09, [Ba/H] = -3.46\pm0.11. This leads to a new lower limit on [Ba/Eu] > -0.66. We find that, in the framework of a 1D LTE analysis, the isotopic ratios of Ba in HD140283 indicate fodd=0.02\pm0.06, a purely s-process signature. This implies that observations and analysis do not validate currently accepted theory. We speculate that a 1D code, due to simplifying assumptions, is not adequate when dealing with observations with high levels of resolution and S/N because of the turbulent motions associated with a 3D stellar atmosphere. New approaches to analysing isotopic ratios, in particular 3D hydrodynamics, need to be considered when dealing with the levels of detail required to properly determine them. However published 3D results exacerbate the disagreement between theory and observation.Comment: 16 pages, 10 figures, 7 tables, 1 online appendix Accepted by A&

Hypernova Nucleosynthesis and Galactic Chemical Evolution

We study nucleosynthesis in 'hypernovae', i.e., supernovae with very large explosion energies ( \gsim 10^{52} ergs) for both spherical and aspherical explosions. The hypernova yields compared to those of ordinary core-collapse supernovae show the following characteristics: 1) Complete Si-burning takes place in more extended region, so that the mass ratio between the complete and incomplete Si burning regions is generally larger in hypernovae than normal supernovae. As a result, higher energy explosions tend to produce larger [(Zn, Co)/Fe], small [(Mn, Cr)/Fe], and larger [Fe/O], which could explain the trend observed in very metal-poor stars. 2) Si-burning takes place in lower density regions, so that the effects of $\alpha$-rich freezeout is enhanced. Thus $^{44}$Ca, $^{48}$Ti, and $^{64}$Zn are produced more abundantly than in normal supernovae. The large [(Ti, Zn)/Fe] ratios observed in very metal poor stars strongly suggest a significant contribution of hypernovae. 3) Oxygen burning also takes place in more extended regions for the larger explosion energy. Then a larger amount of Si, S, Ar, and Ca ("Si") are synthesized, which makes the "Si"/O ratio larger. The abundance pattern of the starburst galaxy M82 may be attributed to hypernova explosions. Asphericity in the explosions strengthens the nucleosynthesis properties of hypernovae except for "Si"/O. We thus suggest that hypernovae make important contribution to the early Galactic (and cosmic) chemical evolution.Comment: To be published in "The Influence of Binaries on Stellar Population Studies", ed. D. Vanbeveren (Kluwer), 200

R-process enrichment from a single event in an ancient dwarf galaxy

Elements heavier than zinc are synthesized through the (r)apid and (s)low neutron-capture processes. The main site of production of the r-process elements (such as europium) has been debated for nearly 60 years. Initial studies of chemical abundance trends in old Milky Way halo stars suggested continual r-process production, in sites like core-collapse supernovae. But evidence from the local Universe favors r-process production mainly during rare events, such as neutron star mergers. The appearance of a europium abundance plateau in some dwarf spheroidal galaxies has been suggested as evidence for rare r-process enrichment in the early Universe, but only under the assumption of no gas accretion into the dwarf galaxies. Cosmologically motivated gas accretion favors continual r-process enrichment in these systems. Furthermore, the universal r-process pattern has not been cleanly identified in dwarf spheroidals. The smaller, chemically simpler, and more ancient ultra-faint dwarf galaxies assembled shortly after the first stars formed, and are ideal systems with which to study nucleosynthesis events such as the r-process. Reticulum II is one such galaxy. The abundances of non-neutron-capture elements in this galaxy (and others like it) are similar to those of other old stars. Here, we report that seven of nine stars in Reticulum II observed with high-resolution spectroscopy show strong enhancements in heavy neutron-capture elements, with abundances that follow the universal r-process pattern above barium. The enhancement in this "r-process galaxy" is 2-3 orders of magnitude higher than that detected in any other ultra-faint dwarf galaxy. This implies that a single rare event produced the r-process material in Reticulum II. The r-process yield and event rate are incompatible with ordinary core-collapse supernovae, but consistent with other possible sites, such as neutron star mergers.Comment: Published in Nature, 21 Mar 2016: http://dx.doi.org/10.1038/nature1742