691 research outputs found
Complexity analysis of Klein-Gordon single-particle systems
The Fisher-Shannon complexity is used to quantitatively estimate the
contribution of relativistic effects to on the internal disorder of
Klein-Gordon single-particle Coulomb systems which is manifest in the rich
variety of three-dimensional geometries of its corresponding quantum-mechanical
probability density. It is observed that, contrary to the non-relativistic
case, the Fisher-Shannon complexity of these relativistic systems does depend
on the potential strength (nuclear charge). This is numerically illustrated for
pionic atoms. Moreover, its variation with the quantum numbers (n, l, m) is
analysed in various ground and excited states. It is found that the
relativistic effects enhance when n and/or l are decreasing.Comment: 4 pages, 3 figures, Accepted in EPL (Europhysics Letters
Rapid topography mapping of scalar fields: Large molecular clusters
The following article appeared in Journal of Chemical Physics 137.7 (2012): 074116 and may be found at http://scitation.aip.org/content/aip/journal/jcp/137/7/10.1063/1.4746243An efficient and rapid algorithm for topography mapping of scalar fields, molecular electron density (MED) and molecular electrostatic potential (MESP) is presented. The highlight of the work is the use of fast function evaluation by Deformed-atoms-in-molecules (DAM) method. The DAM method provides very rapid as well as sufficiently accurate function and gradient evaluation. For mapping the topography of large systems, the molecular tailoring approach (MTA) is invoked. This new code is tested out for mapping the MED and MESP critical points (CP's) of small systems. It is further applied to large molecular clusters viz. (H 2O) 25, (C 6H 6) 8 and also to a unit cell of valine crystal at MP26-31G(d) level of theory. The completeness of the topography is checked by extensive search as well as applying the Poincaré-Hopf relation. The results obtained show that the DAM method in combination with MTA provides a rapid and efficient route for mapping the topography of large molecular systemsAuthors thank the Center for Development of Advanced Computing (C-DAC), Pune for financial and computational support. S.R.G. is grateful to the Department of Science and Technology (DST) for the award of J. C. Bose National Fellowship. R. López acknowledges partial funding from the CAM (S2009_PPQ-1545, LIQUORGAS) and MICINN (CTQ2010-19232). Authors are also thankful to Dr. Graeme M. Day, University of Cambridge, for providing the coordinates of unit cell of valine crystal and to Dr. V. Subramanian, CLRI, Chennai for providing some test run
Enabling rapid and accurate construction of CCSD(T)-level potential energy surface of large molecules using molecular tailoring approach
The construction of the potential energy surface (PES) of even a medium-sized
molecule employing correlated theory, such as CCSD(T), is an arduous task due
to the high computational cost. In this Letter, we report the possibility of
efficient construction of such a PES employing the molecular tailoring approach
(MTA) on off-the-shelf hardware. The full calculation (FC) as well as MTA
energies at CCSD(T)/aug-cc-pVTZ level for three test molecules, viz.
acetylacetone, N-methyacetamide, and tropolone are reported. All the MTA
energies are in excellent agreement with their FC counterparts (typical error
being sub-millihartree) with a time advantage factor of 3 to 5. The energy
barrier from the ground- to transition-state is accurately captured. Further,
the accuracy and efficiency of the MTA method for estimating energy gradients
at CCSD(T) level are demonstrated. This work brings out the possibility of the
construction of PES for large molecules using MTA with the computational
economy at a high level of theory and/or basis set
Free expansion of impenetrable bosons on one-dimensional optical lattices
We review recent exact results for the free expansion of impenetrable bosons
on one-dimensional lattices, after switching off a confining potential. When
the system is initially in a superfluid state, far from the regime in which the
Mott-insulator appears in the middle of the trap, the momentum distribution of
the expanding bosons rapidly approaches the momentum distribution of
noninteracting fermions. Remarkably, no loss in coherence is observed in the
system as reflected by a large occupation of the lowest eigenstate of the
one-particle density matrix. In the opposite limit, when the initial system is
a pure Mott insulator with one particle per lattice site, the expansion leads
to the emergence of quasicondensates at finite momentum. In this case,
one-particle correlations like the ones shown to be universal in the
equilibrium case develop in the system. We show that the out-of-equilibrium
behavior of the Shannon information entropy in momentum space, and its contrast
with the one of noninteracting fermions, allows to differentiate the two
different regimes of interest. It also helps in understanding the crossover
between them.Comment: 21 pages, 14 figures, invited brief revie
Quantum-information entropies for highly excited states of single-particle systems with power-type potentials
The asymptotics of the Boltzmann-Shannon information entropy as well as the Renyi entropy for the quantum probability density of a single-particle system with a confining (i.e., bounded below) power-type potential V(x)=x^2k with k∈N and x∈R, is investigated in the position and momentum spaces within the semiclassical (WKB) approximation. It is found that for highly excited states both physical entropies, as well as their sum, have a logarithmic dependence on its quantum number not only when k=1 (harmonic oscillator), but also for any fixed k. As a by-product, the extremal case k→∞ (the infinite well potential) is also rigorously analyzed. It is shown that not only the position-space entropy has the same constant value for all quantum states, which is a known result, but also that the momentum-space entropy is constant for highly excited states
Configuration Complexities of Hydrogenic Atoms
The Fisher-Shannon and Cramer-Rao information measures, and the LMC-like or
shape complexity (i.e., the disequilibrium times the Shannon entropic power) of
hydrogenic stationary states are investigated in both position and momentum
spaces. First, it is shown that not only the Fisher information and the
variance (then, the Cramer-Rao measure) but also the disequilibrium associated
to the quantum-mechanical probability density can be explicitly expressed in
terms of the three quantum numbers (n, l, m) of the corresponding state.
Second, the three composite measures mentioned above are analytically,
numerically and physically discussed for both ground and excited states. It is
observed, in particular, that these configuration complexities do not depend on
the nuclear charge Z. Moreover, the Fisher-Shannon measure is shown to
quadratically depend on the principal quantum number n. Finally, sharp upper
bounds to the Fisher-Shannon measure and the shape complexity of a general
hydrogenic orbital are given in terms of the quantum numbers.Comment: 22 pages, 7 figures, accepted i
First narrow-band search for continuous gravitational waves from known pulsars in advanced detector data
Spinning neutron stars asymmetric with respect to their rotation axis are potential sources of
continuous gravitational waves for ground-based interferometric detectors. In the case of known pulsars a
fully coherent search, based on matched filtering, which uses the position and rotational parameters
obtained from electromagnetic observations, can be carried out. Matched filtering maximizes the signalto-
noise (SNR) ratio, but a large sensitivity loss is expected in case of even a very small mismatch
between the assumed and the true signal parameters. For this reason, narrow-band analysis methods have
been developed, allowing a fully coherent search for gravitational waves from known pulsars over a
fraction of a hertz and several spin-down values. In this paper we describe a narrow-band search of
11 pulsars using data from Advanced LIGO’s first observing run. Although we have found several initial
outliers, further studies show no significant evidence for the presence of a gravitational wave signal.
Finally, we have placed upper limits on the signal strain amplitude lower than the spin-down limit for 5 of
the 11 targets over the bands searched; in the case of J1813-1749 the spin-down limit has been beaten for
the first time. For an additional 3 targets, the median upper limit across the search bands is below the
spin-down limit. This is the most sensitive narrow-band search for continuous gravitational waves carried
out so far
Kinetic energy bounds for particles confined in spherically-symmetric traps with non-standard dimensions
The kinetic energy of non-relativistic single-particle systems with arbitrary D-dimensional central potentials is found to be bounded from below by means of the orbital hyperangular quantum number, the dimensionality and some radial and logarithmic expectation values of the form langrkrang and langrk (ln r)mrang. Beyond the intrinsic physico-mathematical interest of this problem, we want to contribute to the current development of the theory of independent particles confined in spherically symmetric traps with non-standard dimensions. The latter has been motivated by the recent experimental achievements of the evaporative cooling of dilute (i.e. almost non-interacting) fermions in magnetic traps.We are very grateful for partial support from Junta de Andalucía (under the grants
FQM-0207 and FQM-481), Ministerio de Educación y Ciencia (under the project FIS2005-00973), and the European Research Network NeCCA (under the project INTAS-03-51-6637).
RGF acknowledges the support of Junta de Andalucía under the program of Retorno de
Investigadores a Centros de Investigación Andaluces, and PSM the support of Ministerio de Educación y Ciencia under the program FPU
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