Photochemical colour change for traditional watercolour pigments in low oxygen levels

An investigation for light exposure on pigments in low-oxygen environments (in the range 0–5% oxygen) was conducted using a purpose-built automated microfadometer for a large sample set including multiple samples of traditional watercolour pigments from nineteenth-century and twentieth-century sources, selected for concerns over their stability in anoxia. The pigments were prepared for usage in watercolour painting: ground and mixed in gum Arabic and applied to historically accurate gelatine glue-sized cotton and linen-based papers. Anoxia benefited many colorants and no colorant fared worse in anoxia than in air, with the exception of Prussian blue and Prussian green (which contains Prussian blue). A Prussian blue sampled from the studio materials of J.M.W. Turner (1775 − 1851) was microfaded in different environments (normal air (20.9% oxygen) 0, 1, 2, 3.5, or 5% oxygen in nitrogen) and the subsequent dark behaviour was measured. The behaviour of the sample (in normal air, anoxia, and 5% oxygen in nitrogen) proved to be consistent with the 55 separately sourced Prussian blue samples. When exposed to light in 5% oxygen in nitrogen, Prussian blue demonstrated the same light stability as in air (at approximately 21°C and 1 atmosphere). Storage in 5% oxygen is proposed for ‘anoxic’ display of paper-based artworks that might contain Prussian blue, to protect this material while reducing light-induced damage to other components of a watercolour, including organic colorants and the paper support

Fast Chopper Structure for the CERN Superconducting Proton Linac

The SPL chopper is a travelling wave device, which deflects a slow beam (b = v/c = 0.08) by its transverse electric field. We discuss the chopper deflecting structure based on a meander line printed on an alumina substrate. This concept profits from the radiation resistance of alumina, its excellent out-gassing properties and its good thermal conductivity. The use of well established MIC (microwave integrated circuit) thick film technology allows easy implementation of prototypes; the thickness of the printed layer should be increased by means of an electrochemical deposition method. The topology of the structure has been chosen from standard MIC layouts and was subsequently optimized using numerical simulations. Several prototypes have been manufactured and measurements have shown encouraging results

First results of the CERN Resonant WISP Search (CROWS)

The CERN Resonant WISP Search (CROWS) probes the existence of Weakly Interacting Sub-eV Particles (WISPs) like axions or hidden sector photons. It is based on the principle of an optical light shining through the wall experiment, adapted to microwaves. Critical aspects of the experiment are electromagnetic shielding, design and operation of low loss cavity resonators and the detection of weak sinusoidal microwave signals. Lower bounds were set on the coupling constant $g = 4.5 \cdot 10^{-8}$GeV$^{-1}$ for axion like particles with a mass of $m_a = 7.2 \mu$eV. For hidden sector photons, lower bounds were set for the coupling constant $\chi = 4.1 \cdot 10^{-9}$ at a mass of $m_{\gamma'} = 10.8 \mu$eV. For the latter we were probing a previously unexplored region in the parameter space

Demonstration of 10−2210^{-22} W Signal Detection Methods in the Microwave Range at Ambient Temperature

The detection of a very faint signal in a noisy environment is of considerable interest in different applications including antihydrogen spectroscopy and also microwave axion and ‘hidden photon’ detection. We demonstrate with a very simple setup using a commercial signal generator and an FFT signal analyzer the detection of a microwave signal of 10**-22 W at ambient temperature

Interface Engineering to Create a Strong Spin Filter Contact to Silicon

Integrating epitaxial and ferromagnetic Europium Oxide (EuO) directly on silicon is a perfect route to enrich silicon nanotechnology with spin filter functionality. To date, the inherent chemical reactivity between EuO and Si has prevented a heteroepitaxial integration without significant contaminations of the interface with Eu silicides and Si oxides. We present a solution to this long-standing problem by applying two complementary passivation techniques for the reactive EuO/Si interface: ($i$) an $in\:situ$ hydrogen-Si $(001)$ passivation and ($ii$) the application of oxygen-protective Eu monolayers --- without using any additional buffer layers. By careful chemical depth profiling of the oxide-semiconductor interface via hard x-ray photoemission spectroscopy, we show how to systematically minimize both Eu silicide and Si oxide formation to the sub-monolayer regime --- and how to ultimately interface-engineer chemically clean, heteroepitaxial and ferromagnetic EuO/Si $(001)$ in order to create a strong spin filter contact to silicon.Comment: 11 pages of scientific paper, 10 high-resolution color figures. Supplemental information on the thermodynamic problem available (PDF). High-resolution abstract graphic available (PNG). Original research (2016

Integration over the quantum diagonal subgroup and associated Fourier-like algebras

By analogy with the classical construction due to Forrest, Samei and Spronk we associate to every compact quantum group $\mathbb{G}$ a completely contractive Banach algebra $A_\Delta(\mathbb{G})$, which can be viewed as a deformed Fourier algebra of $\mathbb{G}$. To motivate the construction we first analyse in detail the quantum version of the integration over the diagonal subgroup, showing that although the quantum diagonal subgroups in fact never exist, as noted earlier by Kasprzak and So{\l}tan, the corresponding integration represented by a certain idempotent state on $C(\mathbb{G})$ makes sense as long as $\mathbb{G}$ is of Kac type. Finally we analyse as an explicit example the algebras $A_\Delta(O_N^+)$, $N\ge 2$, associated to Wang's free orthogonal groups, and show that they are not operator weakly amenable.Comment: Minor updates; Remark 5.7 has been added; 31 page

Generalised Shastry-Sutherland Models in three and higher dimensions

We construct Heisenberg anti-ferromagnetic models in arbitrary dimensions that have isotropic valence bond crystals (VBC) as their exact ground states. The d=2 model is the Shastry-Sutherland model. In the 3-d case we show that it is possible to have a lattice structure, analogous to that of SrCu_2(BO_3)_2, where the stronger bonds are associated with shorter bond lengths. A dimer mean field theory becomes exact at d -> infinity and a systematic 1/d expansion can be developed about it. We study the Neel-VBC transition at large d and find that the transition is first order in even but second order in odd dimensions.Comment: Published version; slightly expande

Geodesics for Efficient Creation and Propagation of Order along Ising Spin Chains

Experiments in coherent nuclear and electron magnetic resonance, and optical spectroscopy correspond to control of quantum mechanical ensembles, guiding them from initial to final target states by unitary transformations. The control inputs (pulse sequences) that accomplish these unitary transformations should take as little time as possible so as to minimize the effects of relaxation and decoherence and to optimize the sensitivity of the experiments. Here we give efficient syntheses of various unitary transformations on Ising spin chains of arbitrary length. The efficient realization of the unitary transformations presented here is obtained by computing geodesics on a sphere under a special metric. We show that contrary to the conventional belief, it is possible to propagate a spin order along an Ising spin chain with coupling strength J (in units of Hz), significantly faster than 1/(2J) per step. The methods presented here are expected to be useful for immediate and future applications involving control of spin dynamics in coherent spectroscopy and quantum information processing

A non-Hermitian critical point and the correlation length of strongly correlated quantum systems

We study a non-Hermitian generalization of quantum systems in which an imaginary vector potential is added to the momentum operator. In the tight-binding approximation, we make the hopping energy asymmetric in the Hermitian Hamiltonian. In a previous article, we conjectured that the non-Hermitian critical point where the energy gap vanishes is equal to the inverse correlation length of the Hermitian system and we confirmed the conjecture for two exactly solvable systems. In this article, we present more evidence for the conjecture. We also argue the basis of our conjecture by noting the dispersion relation of the elementary excitation.Comment: 25 pages, 18 figure