92 research outputs found
Single Color Centers Implanted in Diamond Nanostructures
The development of materials processing techniques for optical diamond
nanostructures containing a single color center is an important problem in
quantum science and technology. In this work, we present the combination of ion
implantation and top-down diamond nanofabrication in two scenarios: diamond
nanopillars and diamond nanowires. The first device consists of a 'shallow'
implant (~20nm) to generate Nitrogen-vacancy (NV) color centers near the top
surface of the diamond crystal. Individual NV centers are then isolated
mechanically by dry etching a regular array of nanopillars in the diamond
surface. Photon anti-bunching measurements indicate that a high yield (>10%) of
the devices contain a single NV center. The second device demonstrates 'deep'
(~1\mu m) implantation of individual NV centers into pre-fabricated diamond
nanowire. The high single photon flux of the nanowire geometry, combined with
the low background fluorescence of the ultrapure diamond, allows us to sustain
strong photon anti-bunching even at high pump powers.Comment: 20 pages, 7 figure
Van Kampen's expansion approach in an opinion formation model
We analyze a simple opinion formation model consisting of two parties, A and
B, and a group I, of undecided agents. We assume that the supporters of parties
A and B do not interact among them, but only interact through the group I, and
that there is a nonzero probability of a spontaneous change of opinion (A->I,
B->I). From the master equation, and via van Kampen's Omega-expansion approach,
we have obtained the "macroscopic" evolution equation, as well as the
Fokker-Planck equation governing the fluctuations around the deterministic
behavior. Within the same approach, we have also obtained information about the
typical relaxation behavior of small perturbations.Comment: 17 pages, 6 figures, submited to Europ.Phys.J.
Nanobeam photonic crystal cavity quantum dot laser
The lasing behavior of one dimensional GaAs nanobeam cavities with embedded
InAs quantum dots is studied at room temperature. Lasing is observed throughout
the quantum dot PL spectrum, and the wavelength dependence of the threshold is
calculated. We study the cavity lasers under both 780 nm and 980 nm pump,
finding thresholds as low as 0.3 uW and 19 uW for the two pump wavelengths,
respectively. Finally, the nanobeam cavity laser wavelengths are tuned by up to
7 nm by employing a fiber taper in near proximity to the cavities. The fiber
taper is used both to efficiently pump the cavity and collect the cavity
emission.Comment: 8 pages; 6 figure
CRADA Final Report for NFE-08-01826: Development and application of processing and processcontrol for nano-composite materials for lithium ion batteries
Oak Ridge National Laboratory and A123 Systems, Inc. collaborated on this project to develop a better understanding, quality control procedures, and safety testing for A123 System’s nanocomposite separator (NCS) technology which is a cell based patented technology and separator. NCS demonstrated excellent performance. x3450 prismatic cells were shown to survive >8000 cycles (1C/2C rate) at room temperature with greater than 80% capacity retention with only NCS present as an alternative to conventional polyolefin. However, for a successful commercialization, the coating conditions required to provide consistent and reliable product had not been optimized and QC techniques for being able to remove defective material before incorporation into a cell had not been developed. The work outlined in this report addresses these latter two points. First, experiments were conducted to understand temperature profiles during the different drying stages of the NCS coating when applied to both anode and cathode. One of the more interesting discoveries of this study was the observation of the large temperature decrease experienced by the wet coating between the end of the infrared (IR) drying stage and the beginning of the exposure to the convection drying oven. This is not a desirable situation as the temperature gradient could have a deleterious effect on coating quality. Based on this and other experimental data a radiative transfer model was developed for IR heating that also included a mass transfer module for drying. This will prove invaluable for battery coating optimization especially where IR drying is being employed. A stress model was also developed that predicts that under certain drying conditions tensile stresses are formed in the coating which could lead to cracking that is sometimes observed after drying is complete. Prediction of under what conditions these stresses form is vital to improving coating quality. In addition to understanding the drying process other parameters such as slurry quality and equipment optimization were examined. Removal of particles and gels by filtering, control of viscosity by %solids and mixing adjustments, removal of trapped gas in the slurry and modification of coater speed and slot die gap were all found to be important for producing uniform and flaw-free coatings. Second, an in-line Hi-Pot testing method has been developed specifically for NCS that will enable detection of coating flaws that could lead to soft or hard electrical shorts within the cell. In this way flawed material can be rejected before incorporation into the cell thus greatly reducing the amount of scrap that is generated. Improved battery safety is an extremely important benefit of NCS. Evaluation of battery safety is usually accomplished by conducting a variety of tests including nail penetration, hot box, over charge, etc. For these tests entire batteries must be built but the resultant temperature and voltage responses reveal little about the breakdown mechanism. In this report is described a pinch test which is used to evaluate NCS quality at various stages including coated anode and cathode as well as assembled cell. Coupled with post-microscopic examination of the damaged ‘pinch point’ test data can assist in the coating optimization from an improved end-use standpoint. As a result of this work two invention disclosures, one for optimizing drying methodology and the other for an in-line system for flaw detection, have been filed. In addition, 2 papers are being written for submission to peer-reviewed journals
Bright single-photon sources in bottom-up tailored nanowires
The ability to achieve near-unity light extraction efficiency is necessary
for a truly deterministic single photon source. The most promising method to
reach such high efficiencies is based on embedding single photon emitters in
tapered photonic waveguides defined by top-down etching techniques. However,
light extraction efficiencies in current top-down approaches are limited by
fabrication imperfections and etching induced defects. The efficiency is
further tempered by randomly positioned off-axis quantum emitters. Here, we
present perfectly positioned single quantum dots on the axis of a tailored
nanowire waveguide using bottom-up growth. In comparison to quantum dots in
nanowires without waveguide, we demonstrate a 24-fold enhancement in the single
photon flux, corresponding to a light extraction efficiency of 42 %. Such high
efficiencies in one-dimensional nanowires are promising to transfer quantum
information over large distances between remote stationary qubits using flying
qubits within the same nanowire p-n junction.Comment: 19 pages, 6 figure
Improving the performance of bright quantum dot single photon sources using amplitude modulation
Single epitaxially-grown semiconductor quantum dots have great potential as
single photon sources for photonic quantum technologies, though in practice
devices often exhibit non-ideal behavior. Here, we demonstrate that amplitude
modulation can improve the performance of quantum-dot-based sources. Starting
with a bright source consisting of a single quantum dot in a fiber-coupled
microdisk cavity, we use synchronized amplitude modulation to temporally filter
the emitted light. We observe that the single photon purity, temporal overlap
between successive emission events, and indistinguishability can be greatly
improved with this technique. As this method can be applied to any triggered
single photon source, independent of geometry and after device fabrication, it
is a flexible approach to improve the performance of solid-state systems, which
often suffer from excess dephasing and multi-photon background emission
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Single-Color Centers Implanted in Diamond Nanostructures
The development of material-processing techniques that can be used to generate optical diamond nanostructures containing a single-color center is an important problem in quantum science and technology. In this work, we present the combination of ion implantation and top-down diamond nanofabrication in two scenarios: diamond nanopillars and diamond nanowires. The first device consists of a 'shallow' implant (similar to 20 nm) to generate nitrogen-vacancy (NV) color centers near the top surface of the diamond crystal prior to device fabrication. Individual NV centers are then mechanically isolated by etching a regular array of nanopillars in the diamond surface. Photon anti-bunching measurements indicate that a high yield (> 10%) of the devices contain a single NV center. The second device demonstrates 'deep' (similar to ) implantation of individual NV centers into diamond nanowires as a post-processing step. The high single-photon flux of the nanowire geometry, combined with the low background fluorescence of the ultrapure diamond, allowed us to observe sustained photon anti-bunching even at high pump powers.Engineering and Applied SciencesPhysic
Coherent, mechanical control of a single electronic spin
The ability to control and manipulate spins via electrical, magnetic and
optical means has generated numerous applications in metrology and quantum
information science in recent years. A promising alternative method for spin
manipulation is the use of mechanical motion, where the oscillation of a
mechanical resonator can be magnetically coupled to a spins magnetic dipole,
which could enable scalable quantum information architectures9 and sensitive
nanoscale magnetometry. To date, however, only population control of spins has
been realized via classical motion of a mechanical resonator. Here, we
demonstrate coherent mechanical control of an individual spin under ambient
conditions using the driven motion of a mechanical resonator that is
magnetically coupled to the electronic spin of a single nitrogen-vacancy (NV)
color center in diamond. Coherent control of this hybrid mechanical/spin system
is achieved by synchronizing pulsed spin-addressing protocols (involving
optical and radiofrequency fields) to the motion of the driven oscillator,
which allows coherent mechanical manipulation of both the population and phase
of the spin via motion-induced Zeeman shifts of the NV spins energy. We
demonstrate applications of this coherent mechanical spin-control technique to
sensitive nanoscale scanning magnetometry.Comment: 6 pages, 4 figure
A robust, scanning quantum system for nanoscale sensing and imaging
Controllable atomic-scale quantum systems hold great potential as sensitive
tools for nanoscale imaging and metrology. Possible applications range from
nanoscale electric and magnetic field sensing to single photon microscopy,
quantum information processing, and bioimaging. At the heart of such schemes is
the ability to scan and accurately position a robust sensor within a few
nanometers of a sample of interest, while preserving the sensor's quantum
coherence and readout fidelity. These combined requirements remain a challenge
for all existing approaches that rely on direct grafting of individual solid
state quantum systems or single molecules onto scanning-probe tips. Here, we
demonstrate the fabrication and room temperature operation of a robust and
isolated atomic-scale quantum sensor for scanning probe microscopy.
Specifically, we employ a high-purity, single-crystalline diamond nanopillar
probe containing a single Nitrogen-Vacancy (NV) color center. We illustrate the
versatility and performance of our scanning NV sensor by conducting
quantitative nanoscale magnetic field imaging and near-field single-photon
fluorescence quenching microscopy. In both cases, we obtain imaging resolution
in the range of 20 nm and sensitivity unprecedented in scanning quantum probe
microscopy
Composite-pulse magnetometry with a solid-state quantum sensor
The sensitivity of quantum magnetometers is challenged by control errors and,
especially in the solid-state, by their short coherence times. Refocusing
techniques can overcome these limitations and improve the sensitivity to
periodic fields, but they come at the cost of reduced bandwidth and cannot be
applied to sense static (DC) or aperiodic fields. Here we experimentally
demonstrate that continuous driving of the sensor spin by a composite pulse
known as rotary-echo (RE) yields a flexible magnetometry scheme, mitigating
both driving power imperfections and decoherence. A suitable choice of RE
parameters compensates for different scenarios of noise strength and origin.
The method can be applied to nanoscale sensing in variable environments or to
realize noise spectroscopy. In a room-temperature implementation based on a
single electronic spin in diamond, composite-pulse magnetometry provides a
tunable trade-off between sensitivities in the microT/sqrt(Hz) range,
comparable to those obtained with Ramsey spectroscopy, and coherence times
approaching T1
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