857 research outputs found

    Emitter-site selective photoelectron circular dichroism of trifluoromethyloxirane

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    The angle-resolved inner-shell photoionization of R-trifluoromethyloxirane, C3H3F3O, is studied experimentally and theoretically. Thereby, we investigate the photoelectron circular dichroism (PECD) for nearly-symmetric O 1s and F 1s electronic orbitals, which are localized on different molecular sites. The respective dichroic β1\beta_{1} and angular distribution β2\beta_{2} parameters are measured at the photoelectron kinetic energies from 1 to 16 eV by using variably polarized synchrotron radiation and velocity map imaging spectroscopy. The present experimental results are in good agreement with the outcome of ab initio electronic structure calculations. We report a sizable chiral asymmetry β1\beta_{1} of up to about 9% for the K-shell photoionization of oxygen atom. For the individual fluorine atoms, the present calculations predict asymmetries of similar size. However, being averaged over all fluorine atoms, it drops down to about 2%, as also observed in the present experiment. Our study demonstrates a strong emitter- and site-sensitivity of PECD in the one-photon inner-shell ionization of this chiral molecule

    Making FORS2 fit for exoplanet observations (again)

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    For about three years, it was known that precision spectrophotometry with FORS2 suffered from systematic errors that made quantitative observations of planetary transits impossible. We identified the Longitudinal Atmospheric Dispersion Compensator (LADC) as the most likely culprit, and therefore engaged in a project to exchange the LADC prisms with the uncoated ones from FORS1. This led to a significant improvement in the depth of FORS2 zero points, a reduction in the systematic noise, and should make FORS2 again competitive for transmission spectroscopy of exoplanets.Comment: To appear in the March issue of the ESO Messenge

    FLICK: developing and running application-specific network services

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    Data centre networks are increasingly programmable, with application-specific network services proliferating, from custom load-balancers to middleboxes providing caching and aggregation. Developers must currently implement these services using traditional low-level APIs, which neither support natural operations on application data nor provide efficient performance isolation. We describe FLICK, a framework for the programming and execution of application-specific network services on multi-core CPUs. Developers write network services in the FLICK language, which offers high-level processing constructs and application-relevant data types. FLICK programs are translated automatically to efficient, parallel task graphs, implemented in C++ on top of a user-space TCP stack. Task graphs have bounded resource usage at runtime, which means that the graphs of multiple services can execute concurrently without interference using cooperative scheduling. We evaluate FLICK with several services (an HTTP load-balancer, a Memcached router and a Hadoop data aggregator), showing that it achieves good performance while reducing development effort

    The HARPS search for southern extra-solar planets I. HD330075 b: a new 'hot Jupiter'

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    We report on the first extra-solar planet discovered with the brand new HARPS instrument. The planet is a typical 'hot Jupiter' with m2sini = 0.62 MJup and an orbital period of 3.39 days, but from the photometric follow-up of its parent star HD330075 we can exclude the presence of a transit. The induced radial-velocity variations exceed 100 m/s in semi-amplitude and are easily detected by state-of-the-art spectro-velocimeters. Nevertheless, the faint magnitude of the parent star (V = 9.36) benefits from the efficient instrument: With HARPS less than 10 observing nights and 3 hours of total integration time were needed to discover the planet and characterize its orbit. The orbital parameters determined from the observations made during the first HARPS run in July 2003 have been confirmed by 7 additional observations carried out in February 2004. The bisector analysis and a photometric follow-up give no hint for activity-induced radial-velocity variations, indicating that the velocity curve is best explained by the presence of a low-mass companion to the star. In this paper we present a set of 21 measurements of excellent quality with weighted rms as low as 2.0 m/s. These measurements lead to a well defined orbit and consequently to the precise orbital parameters determination of the extra-solar planet HD330075b.Comment: 5 pages, 2 figures, accepted for publication by Astronomy and Astrophysics, see also http://obswww.unige.ch/~udry/planet/planet.htm

    A Case of Relapsing-Remitting Neuroborreliosis? Challenges in the Differential Diagnosis of Recurrent Myelitis

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    We report the case of a 31-year-old woman with 4 episodes of myelitis with pleocytosis, a positive Borrelia burgdorferi serology with positive antibody indices, and full recovery each time after antibiotic and steroid treatment, suggesting neuroborreliosis. We nevertheless believe that recurrent neuroborreliosis is improbable based on the levels of the chemokine CXCL13 in cerebrospinal fluid and favor the diagnosis of post-infectious autoimmune-mediated transverse myelitis possibly triggered by an initial neuroborreliosis as the cause of the relapses observed in our patient. We demonstrate the diagnostic steps and procedures which were important in the differential diagnosis of this unusual and challenging case

    Localisation and interactions of the Vipp1 protein in cyanobacteria

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    Biotechnology and Biological Sciences Research Council. Grant Number: BB/G021856. Deutsche Forschungsgemeinschaft. Grant Number: FOR 929, SCHN 690/3-1. European Commission. Grant Number: FP7-PEOPLE-2009-IEF 254575. NFR. Grant Numbers: 192436, 197119. OCISB. Royal Society and Engineering and Physical Sciences Research Council. Grant Number: EP/G0061009/

    Experimental study of pedestrian flow through a bottleneck

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    In this work the results of a bottleneck experiment with pedestrians are presented in the form of total times, fluxes, specific fluxes, and time gaps. A main aim was to find the dependence of these values from the bottleneck width. The results show a linear decline of the specific flux with increasing width as long as only one person at a time can pass, and a constant value for larger bottleneck widths. Differences between small (one person at a time) and wide bottlenecks (two persons at a time) were also found in the distribution of time gaps.Comment: accepted for publication in J. Stat. Mec
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