Étude des propriétés d'adhésion à l'interface entre deux films de polytétrafluoroéthylène (PTFE)

National audienceCette étude vise à déterminer la fenêtre de paramètres optimum (pression, temps, température) pour réaliser le soudage entre deux surfaces de PTFE et comprendre les mécanismes d'adhésion entrant en jeu. Les principaux mécanismes responsables de l'adhésion à l'interface polymère/polymère sont présentés puis leur caractérisation expérimentale est exposée. Abstract This study aims to determine the optimum parameters (pressure, time, temperature) to achieve welding between two PTFE surfaces and to understand the adhesion mechanisms involved. The main mechanisms responsible for adhesion of polymer-to-polymer interface are presented and then their experimental characterization is exposed

Large Eddy Simulation of combustion instabilities in a lean partially premixed swirled flame

This paper investigates one issue related to Large Eddy Simulations (LES) of self- excited combustion instabilities in gas-fueled swirled burners: the effects of incom- plete mixing between the gas injection and the combustion chamber. For simplicity reasons, many LES assume perfect premixing of the gases entering the combustion chamber. In practice this is rarely the case and this study addresses the question by comparing LES assuming perfect premixing and LES where the fuel jets are resolved and fuel/air mixing is explicitely computed. This is done for the Preccin- sta swirled burner which has been carefully studied experimentally at DLR. All previous LES studies of Preccinsta have assumed perfect premixing and this work demonstrates that this assumption is reasonable for stable flows but is not accept- able to predict self-excited unstable cases. This is shown by comparing LES and experimental fields in terms of mean and RMS fields of temperature, species and velocities as well as mixture fraction pdfs and unsteady activity for two regimes: a stable one at equivalence ratio 0.83 and an unstable one at 0.7

Explicit predictability and dispersion scaling exponents in fully developed turbulence

We apply a simple method to provide explicit expressions for different scaling exponents in intermittent fully developed turbulence, that before were only given through a Legendre transform. This includes predictability exponents for infinitesimal and non infinitesimal perturbations, Lagrangian velocity exponents, and dispersion exponents. We obtain also new results concerning inverse statistics corresponding to exit-time moments.Comment: Physics Letters A (in press

Crystalline orientation assessment in transversely isotropic semicrystalline polymer: Application to oedometric compaction of PTFE

The Hermans orientation factor is a scalar giving a simple assessment of molecular or crystal orientation in a polymer. It is usually determined from X-ray diffraction measurements. The evaluation of the Hermans orientation factor is proposed from the diffraction analysis of only a single diffracting plane. The estimation relies on (a) the assumption that the polymer crystals possess a cylindrical symmetry with respect to the chain direction and (b) that the processing conditions induce a transverse isotropy of the polymer chains. A practical consequence of the proposed analysis is that the Hermans orientation factor can be computed from a single 1D diffractogram. This enables fast evaluations since even low signal-to-noise ratio signals can be processed with optimal noise reduction. An illustration of this method for uniaxially compacted polytetrafluoroethylene (PTFE) powder is presented. The crystalline orientation is followed during in situ crystallization experiments with a fine time resolution.The authors would like to thank Saint-Gobain for sponsoring this work and especially Xavier Brajer, Monika Brodesser, François Creuzet, René Gy, Ansgar Haeger, and Georges Moineau for their implication in the project. The support of the ANRT through the CIFRE PhD grant of Gabriel Guenoun is gratefully acknowledged. The X-ray diffraction experiments were performed on beamline D2AM BM02 at the European Synchrotron Radiation Facility (ESRF), Grenoble, France. We are grateful to Nathalie Boudet and Nils Blanc at the ESRF for providing assistance in using beamline D2AM BM02

Velocity profiles in shear-banding wormlike micelles

Using Dynamic Light Scattering in heterodyne mode, we measure velocity profiles in a much studied system of wormlike micelles (CPCl/NaSal) known to exhibit both shear-banding and stress plateau behavior. Our data provide evidence for the simplest shear-banding scenario, according to which the effective viscosity drop in the system is due to the nucleation and growth of a highly sheared band in the gap, whose thickness linearly increases with the imposed shear rate. We discuss various details of the velocity profiles in all the regions of the flow curve and emphasize on the complex, non-Newtonian nature of the flow in the highly sheared band.Comment: 4 pages, 5 figures, submitted to Phys. Rev. Let

Using LES to Study Reacting Flows and Instabilities in Annular Combustion Chambers

Great prominence is put on the design of aeronautical gas turbines due to increasingly stringent regulations and the need to tackle rising fuel prices. This drive towards innovation has resulted sometimes in new concepts being prone to combustion instabilities. In the particular field of annular combustion chambers, these instabilities often take the form of azimuthal modes. To predict these modes, one must compute the full combustion chamber, which remained out of reach until very recently and the development of massively parallel computers. Since one of the most limiting factors in performing Large Eddy Simulation (LES) of real combustors is estimating the adequate grid, the effects of mesh resolution are investigated by computing full annular LES of a realistic helicopter combustion chamber on three grids, respectively made of 38, 93 and 336 million elements. Results are compared in terms of mean and fluctuating fields. LES captures self-established azimuthal modes. The presence and structure of the modes is discussed. This study therefore highlights the potential of LES for studying combustion instabilities in annular gas turbine combustors

PTFE crystallization mechanisms: Insight from calorimetric and dilatometric experiments

PTFE presents an original secondary crystallization that appears to be independent of the primary one.The conjunction of differential scanning calorimetry and dilatometry experiments has offered complementarydata to study both crystallization melted compacted powder and of recrystallized samples. The primarycrystallization is responsible for the crystallinity content variation with the cooling rate. It preserves theanisotropy induced by previous compaction that can be observed by dilatometry. Conversely, the secondarycrystallization appears to be instantaneous, reversible, kinetic-free and isotropic. It occurs over a widetemperature range between 250◦C and 310◦C

Thermal cycling of cold-pressed PTFE compacts: Reversible and irreversible behavior

Cold uniaxial pressed PTFE compacts were subjected to thermal cycles of increasing maximum temperature below melting temperature, and thermal expansion was followed in both the compaction and transverse directions. The measurements reveal that thermal expansion consists of two distinct contributions: i) an irreversible part that is controlled only by the maximum temperature experienced by the sample, and ii) a reversible, or thermo-elastic, part that is observed while cycling below the maximum temperature. Moreover, both of these thermal strains exhibit marked anisotropy, resulting from the cold oedometric compaction of the sample. A quantitative analysis of these eigenstrains is proposed, following a formal analogy with elasto-plasticity. Finally, it is shown that such behavior is specific to cold-pressed compacts as sintered samples exhibit isotropic and purely reversible thermo-elastic behavior

Multifractal stationary random measures and multifractal random walks with log-infinitely divisible scaling laws

We define a large class of continuous time multifractal random measures and processes with arbitrary log-infinitely divisible exact or asymptotic scaling law. These processes generalize within a unified framework both the recently defined log-normal Multifractal Random Walk (MRW) [Bacry-Delour-Muzy] and the log-Poisson "product of cynlindrical pulses" [Barral-Mandelbrot]. Our construction is based on some ``continuous stochastic multiplication'' from coarse to fine scales that can be seen as a continuous interpolation of discrete multiplicative cascades. We prove the stochastic convergence of the defined processes and study their main statistical properties. The question of genericity (universality) of limit multifractal processes is addressed within this new framework. We finally provide some methods for numerical simulations and discuss some specific examples.Comment: 24 pages, 4 figure

Boron isotope ratio determination in carbonates /via/ LA-MC-ICP-MS using soda-lime glass standards as reference material

A new in situ method using LA-MC-ICP-MS (193 nm excimer laser) for the determination of stable boron isotope ratios (δ11B) in carbonates was developed. Data were acquired via a standard sample standard bracketing procedure typically providing a reproducibility of 0.5‰ (SD) for samples containing 35 ppm of boron. A single ablation interval consumed about 5 µg of sample corresponding to about 0.2 ng of boron. The major finding was the similar instrumental fractionation behaviour of carbonates, soda-lime glass and sea salt with respect to boron isotopes. As no matrix induced offset was detectable between these distinct materials we propose the use of NIST glasses as internal standards for boron isotope ratio measurements via LA-MC-ICP-MS. This finding overcomes the problem of a missing matrix matched carbonate standard for in situ boron isotope studies. As a first application a set of coral samples from a culturing experiment was analysed. δ11B values range from 19.5 to 25‰ depending on the pH of the water used in the particular treatment. This is in good agreement with the results of earlier studies