OPO-laser system for atmospheric sounding in the MID-IR range

A laser system is designed that provides for tunable generation of nanosecond radiation pulses in the 3–4 μm range. Optical block-diagram and specifications of the system are presented. The laser system as a part of a differential absorption lidar designed can be used for remote control of pollutant concentrations along surface atmospheric path

Class preserving automorphisms of unitriangular groups

Let $\textrm{UT}_n (K)$ be a unitriangular group over a field $K$ and $\Gamma_{n,k} := \textrm{UT}_n (K)/ \gamma_k(\textrm{UT}_n (K))$, where $\gamma_k (\mathrm{UT}_n(K))$ denotes the $k$-th term of the lower central series of $\mathrm{UT}_n (K)$, $2 \le k \le n$. We prove that the group of all class preserving automorphisms of $\Gamma_{n,k}$ is equal to \Inn(\Gamma_{n,k}) if and only if $K$ is a prime field. Let $G_n^{(m)} := \mathrm{UT}_n (\mathbb{F}_{p^m}) / \gamma_3 (\mathrm{UT}_n(\mathbb{F}_{p^m}))$. We calculate the group of all class preserving automorphisms and class preserving outer automorphisms of $G_n^{(m)}$.Comment: 19 pages, accepted for publication in International Journal of Algebra and Computatio

Electron correlation effects in electron-hole recombination in organic light-emitting diodes

We develop a general theory of electron--hole recombination in organic light emitting diodes that leads to formation of emissive singlet excitons and nonemissive triplet excitons. We briefly review other existing theories and show how our approach is substantively different from these theories. Using an exact time-dependent approach to the interchain/intermolecular charge-transfer within a long-range interacting model we find that, (i) the relative yield of the singlet exciton in polymers is considerably larger than the 25% predicted from statistical considerations, (ii) the singlet exciton yield increases with chain length in oligomers, and, (iii) in small molecules containing nitrogen heteroatoms, the relative yield of the singlet exciton is considerably smaller and may be even close to 25%. The above results are independent of whether or not the bond-charge repulsion, X_perp, is included in the interchain part of the Hamiltonian for the two-chain system. The larger (smaller) yield of the singlet (triplet) exciton in carbon-based long-chain polymers is a consequence of both its ionic (covalent) nature and smaller (larger) binding energy. In nitrogen containing monomers, wavefunctions are closer to the noninteracting limit, and this decreases (increases) the relative yield of the singlet (triplet) exciton. Our results are in qualitative agreement with electroluminescence experiments involving both molecular and polymeric light emitters. The time-dependent approach developed here for describing intermolecular charge-transfer processes is completely general and may be applied to many other such processes.Comment: 19 pages, 11 figure

Freshwater Seepage Into Sediments of the Shelf, Shelf Edge, and Continental Slope of the Canadian Beaufort Sea

Long‐term warming of the continental shelf of the Canadian Beaufort Sea caused by the transgression associated with the last deglaciation may be causing decomposition of relict offshore subsea permafrost and gas hydrates. To evaluate this possibility, pore waters from 118 sediment cores up to 7.3‐m long were taken on the shelf and slope and analyzed for chloride concentrations and δ180 and δD composition. We observed downcore decreases in pore waters Cl− concentration in sediments from all sites from the inner shelf (<20‐m water depth), from the shelf edge, from the outer slope (down to 1,000‐m water depths), and from localized shelf features such as midshelf pingo‐like features and inner shelf pockmarks. In contrast, pore water freshening is absent from all investigated cores of the Mackenzie Trough. Downcore pore waters Cl− concentration decreases indicate regional widespread freshwater seepage. Extrapolations to zero Cl− of pore water Cl− versus δ180 regression lines indicate that freshwaters in these environments carry different isotope signatures and thus are sourced from different reservoirs. These isotopic signatures indicate that freshening of shelf sediments pore waters is a result of downward infiltration of Mackenzie River water, freshening of shelf edge sediments is due to relict submarine permafrost degradation or gas hydrate decomposition under the shelf, and freshening of slope sediments is consistent with regional groundwater flow and submarine groundwater discharge as far as 150 km from shore. These results confirm ongoing decomposition of offshore permafrost and suggest extensive current groundwater discharge far from the coast