13,877 research outputs found

    Activity of alumina supported fe catalysts for N2O decomposition: Effects of the iron content and thermal treatment

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    Indexación: Scopus.The activity of Fe2O3/Al2O3 catalysts prepared by impregnation of Al2O3 with different amounts of Fe and calcination temperatures (650 and 900 °C) in the direct N2O decomposition reaction was studied. High calcination temperature was introduced to study the effect of "aging", which are the conditions prevailing in the process-gas option for N2O abatement. The catalysts were characterized by BET, XRD, UV-DRS, and H2-TPR. The incorporation of Fe promotes the alumina phase transition (g-Al2O3 to a-Al2O3) when the catalysts are calcined at 900 °C, which is accompanied by a decrease in the specifc area. The activity of the catalysts and the specifc surface area depend on Fe loading and calcination temperature. It was found that highly dispersed Fe species are more active than bulk type Fe2O3 particles. We conclude that Fe2O3/Al2O3 catalysts prepared by impregnation method are active in the decomposition of N2O, to be used at low or high reaction temperatures (tail-gas or process-gas treatments, respectively), as part of nitric acid production plant. © 2018 Sociedad Chilena de Quimica. All rights reserved.https://scielo.conicyt.cl/pdf/jcchems/v62n4/0717-9324-jcchems-62-04-3752.pd

    Constraints on the mass and mixing of Z' bosons

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    We tested several models in which the Standard Model (SM) gauge group is extended by an additional U(1) gauge symmetry, against available electroweak precision data to impose limits on the mass of the neutral Z' boson, M_Z', predicted in all such models, and on the Z-Z' mixing angle, theta_ZZ', at 95% C.L. We found lower limits on M_Z' of order 1 TeV in most cases, while theta_ZZ' was found to be constrained to very small values.Comment: Format fixed, 5 pages, 2 figures, Talk given at the 17th International Conference on Supersymmetry and the Unification of Fundamental Interactions (SUSY09), Boston, MA, USA, 5-10 June 2009, to be published in the conference proceedings (AIP

    Z' Searches: From Tevatron to LHC

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    The CDF collaboration has set lower limits on the masses of the Z' bosons occurring in a range of E_6 GUT based models. We revisit their analysis and extend it to certain other E_6 scenarios as well as to some general classes of models satisfying the anomaly cancellation conditions, which are not included in the CDF analysis. We also suggest a Bayesian statistical method for finding exclusion limits on the Z' mass, which allows one to explore a wide range of the U(1)' gauge coupling parameter. This method also takes into account the effects of interference between the Z' and the SM gauge bosons.Comment: 5 pages. Talk given at the XXIInd Rencontres de Blois, Loire, France, 16-20 July 201
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