Sectoral and regional impacts of the European Carbon Market in Portugal

Across Europe, CO(2) emission allowances represent one of the main policy instruments to comply with the goals of the Kyoto Protocol. In this paper we use microdata to address two issues regarding the impact of the European Carbon Market (EU ETS). First, we analyze the sectoral effects of the EU ETS in Portugal. The goal is to study the distributive consequences of imbalances, with the novelty of taking into account firm financial data to put values into context. We show that a large majority of installations in most sectors had surpluses and the opportunity to raise remarkable revenues in some cases. We also look at the regional impact, since the pre-existing specialization of different regions in the production of different goods and services might lead to an uneven economic impact of the allowance market. In particular, Portuguese data indicate a distribution of revenue from low income to high income regions, or rather, between installations located in those regions. We focus on the first phase of the EU ETS, using data for each one of the 244 Portuguese installations in the market as well as financial data for 80% of these installations, although we also present data for 2008 and 2009.info:eu-repo/semantics/acceptedVersio

Nominal address and rapport management in informal interactions among university students in Quito (Ecuador), Santiago (Chile) and Seville (Spain)

Nominal and pronominal address forms, which play a central role in the construction of interpersonal relations (cf. Bargiela et al. 2002; Clyne, Norrby and Warren 2009), have been the focus of attention in different linguistics subfields for several decades now. Less attention, however, has been paid to these forms from a variational pragmatics (Schneider and Barron 2008) perspective, particularly in Spanish. Using a corpus of role play interactions, we examine the impact of region and gender on nominal address usage among male and female university students from Quito (Ecuador), Santiago (Chile) and Seville (Spain). We look at how these forms are employed in rapport management (Spencer-Oatey 2008 [2000]) in two situations: giving advice and making a direct complaint (Boxer 1993). Building on work on nominal forms (cf. Leech 1999; McCarthy and O’Keefe 2003), we examine similarities and differences in their use across the three varieties of Spanish. Among the findings recorded was a larger repertoire of nominal forms in the Santiago and Quito data sets relative to the Seville corpus, with the highest frequency of use in Santiago. We suggest that address usage in the dyadic contexts examined is connected to the expression of affect and involvement, with Chileans (Santiago) and Ecuadorians (Quito) displaying more affect than Spaniards (Seville). Contrary to early research suggesting that women employ more affiliative language than men (cf. Lakoff 1995), overall, males in the present study were found to use address forms more frequently than females across the three locations

Editorial:Subcellular compartmentalization of plant antioxidants and ROS generating systems, volume II

JP, MR-R and FC were financed by ERDF-co-financed grants from the Junta de Andalucía (P18-FR-1359) and the Ministry of Science and Innovation (PID2019-103924GB-I00), Spain. CF was financed by BBSRC/GCRF Grant (BB/T008865/1), UK

Biomimetic hierarchical micro/nano texturing of TiAlV alloys by femtosecond laser processing for the control of cell adhesion and migration

The control of the interaction between materials and biological tissues is a key factor to optimize the overall performance of implants and prostheses integrated into the body. With this objective in mind, biomimetic hierarchical one- and two-dimensional surface patterns textured at the micro and nano scales were fabricated on titanium alloys using femtosecond laser processing. The experimental results show that laser irradiation promotes surface oxidation together with a polarization-dependent nano-ripple formation. Human mesenchymal stem cells were subsequently cultured on different surface patterns aiming at determining their response to the underlying micro and nano structures. The ripple topography was demonstrated to induce a nonfouling behavior, which could be exploited in the fabrication of biomimetic hierarchical surface patterns to develop cell-trapping modulesThe authors are grateful for funding provided by Ministerio de Economía y Competitividad (Spain), under project reference numbers MAT2014-54826-C2-1-R and MAT2014-54826-C2-2-R and NanoNeuroDev (Grant No. 2017/EEUU/11) from Santander-Universida

Constructing a Global and Integral Model of Business Management Using a CBR System

Knowledge has become the most strategic resource in the new business environment. A case-based reasoning system, which incorporates a novel clustering and retrieval method, has been developed for identifying critical situations in business processes. The proposed method is based on a Cooperative Maximum Likelihood Hebbian Learning model, which can be used to categorize the necessities for the Acquisition, Transfer and Updating of Knowledge of the different departments of a firm. This technique is used as a tool to develop a part of a Global and Integral Model of business Management, which brings about a global improvement in the firm, adding value, flexibility and competitiveness. From this perspective, the model tries to generalise the hypothesis of organizational survival and competitiveness, so that the organisation that is able to identify, strengthen, and use key knowledge will reach a pole position

Plant catalases as NO and H2S targets

Catalase is a powerful antioxidant metalloenzyme located in peroxisomes which also plays a central role in signaling processes under physiological and adverse situations. Whereas animals contain a single catalase gene, in plants this enzyme is encoded by a multigene family providing multiple isoenzymes whose number varies depending on the species, and their expression is regulated according to their tissue/organ distribution and the environmental conditions. This enzyme can be modulated by reactive oxygen and nitrogen species (ROS/RNS) as well as by hydrogen sulfide (H2S). Catalase is the major protein undergoing Tyr-nitration [post-translational modification (PTM) promoted by RNS] during fruit ripening, but the enzyme from diverse sources is also susceptible to undergo other activity-modifying PTMs. Data on S-nitrosation and persulfidation of catalase from different plant origins are given and compared here with results from obese children where S-nitrosation of catalase occurs. The cysteine residues prone to be S-nitrosated in catalase from plants and from bovine liver have been identified. These evidences assign to peroxisomes a crucial statement in the signaling crossroads among relevant molecules (NO and H2S), since catalase is allocated in these organelles. This review depicts a scenario where the regulation of catalase through PTMs, especially S-nitrosation and persulfidation, is highlighted

Hacia productos saludables elaborados con arroces ricos en melatonina.

El arroz (Oryza sativa) es un cereal fundamental para más de la mitad de la población mundial. Como alimento básico es un aporte calórico en la dieta, adicionalmente contiene melatonina, compuesto beneficioso para la salud. En resultados previos, los arroces; integral, negro y rojo poseen mayor nivel de melatonina comparándolos con otras muestras analizadas, por lo que estos fueron seleccionados para iniciar un estudio de desarrollo de nuevos productos con arroces ricos en melatonina. En esta etapa, se analizó el efecto de la cocción sobre el contenido en melatonina, manteniéndose ésta en niveles aun elevados: 138 µg/kg-1 en el arroz rojo, 95 µg/kg-1 en el arroz negro y 22 µg/Kg-1 en el arroz integral; en el arroz blanco apenas alcanzó 6 µg/kg-1. La evaluación sensorial mediante prueba de calificación hedónica de los atributos globales aspecto, olor, sabor y textura mostró que no hay diferencia en la aceptación entre las 4 variedades de arroz. Mediante encuestas se analizaron otros factores que a priori podrían influir en la aceptabilidad del producto por los consumidores, tales como, la información en el etiquetado del contenido de melatonina y su origen, los mensajes sobre su efecto beneficioso en el metabolismo, y la familiaridad con la marca

A compact dosimetric system for MOSFETs based on passive NFC tag and smartphone

The authors acknowledge the Servicio de Radiofísica (Radio-physics Service) of the Hospital Universitario San Cecilio (Granada, Spain) for permitting us to use their installations. This work was funded by the Spanish Government under project FPA2015-67694-P (Spanish Ministry of Economy, Industry and Competitiveness) and a R&D predoctoral grant (FPU13/05032, Spanish Ministry of Education, Culture and Sport). This project is partially supported by European Regional Development Funds (ERDF).In this work we describe and evaluate a dosimetric system based on an NFC (Near Field Communication) tag and a smartphone that uses commercial MOSFETs as radiation sensors. The tag is designed with commercial integrated circuits and the smartphone is the power source of the tag configured as a readout unit, user interface and storage unit. The NFC tag is supplied wirelessly by the smartphone via NFC, using a home-made structure to align the tag coil and smartphone coil in order to achieve a good inductive coupling. In this case, the commercial DMOS transistor ZVP3306 is used as dosimeter in unbiased mode, connected to the tag before and after each irradiation session to perform the sensor reading. An evaluation of the dosimetric system has been carried out irradiating three transistors with photon beam of 6 MV up to 20 Gy. The average sensitivity found is (4.75 ± 0.15) mV/Gy, which is in good agreement with the results found with our previously developed dosimetric system. Therefore, this miniaturised dosimetric system can be considered as a promising and low cost electronic architecture to be used for dosimetry control in radio-therapy treatments.Servicio de Radiofísica (Radio-physics Service) of the Hospital Universitario San Cecilio (Granada, Spain)Spanish Government under project FPA2015-67694-P (Spanish Ministry of Economy, Industry and Competitiveness) and a R&D predoctoral grant (FPU13/05032, Spanish Ministry of Education, Culture and Sport)European Regional Development Funds (ERDF

Effect of Mixed Oxide-Based TiO2 on the Physicochemical Properties of Chitosan Films

The physicochemical, mechanical, and structural properties of chitosan-based films (CS) alone or CS-films with mixed oxide nanoparticles (TiO2-ZnO-MgO, TZM; CSTZM) at different concentrations (125, 250, and 500 μg mL−1) were investigated. The addition of nano-TZM promoted a color change (from colorless to white) in the film-forming solution, which increased its turbidity and it decreased viscosity. CSTZM were semitransparent (transmittance, T% decreased up to 49%) compared to CS-based films (T% = 95.5). CSTZM (particularly at a concentration of 500 μg mL−1) exhibited an improvement in the moisture content (decreased from 12.6 to 9.67%), water solubility (decreased from 14.94 to 10.22%), degree of swelling (increased from 19.79 to 36.28%), water vapor barrier (decreased from 6.62 x 10−16 to 4.33 x 10−16 g m−1 h−1 Pa−1), thermal stability (the endotherm peak increased from 99.5 to 157.7 °C), and mechanical properties (tensile strength and elongation at break increased from 4.15 to 4.98 kPa and 6.96 to 56.18%, respectively, while the modulus of elasticity decreased from 144 kPa to 4.11 kPa), without toxicity effects on Artemia salina (93.33% survival). X-ray diffraction and Fourier transform infrared studies demonstrated an interaction between CS-based films and nano-TZM. Overall, this film exhibited great potential for diverse industrial applications

Multifaceted roles of nitric oxide in tomato fruit ripening: NO-induced metabolic rewiring and consequences for fruit quality traits

Nitric oxide (NO) has been implicated as part of the ripening regulatory network in fleshy fruits. However, very little is known about the simultaneous action of NO on the network of regulatory events and metabolic reactions behind ripening-related changes in fruit color, taste, aroma and nutritional value. Here, we performed an in-depth characterization of the concomitant changes in tomato (Solanum lycopersicum) fruit transcriptome and metabolome associated with the delayed-ripening phenotype caused by NO supplementation at the pre-climacteric stage. Approximately one-third of the fruit transcriptome was altered in response to NO, including a multilevel down-regulation of ripening regulatory genes, which in turn restricted the production and tissue sensitivity to ethylene. NO also repressed hydrogen peroxide-scavenging enzymes, intensifying nitro-oxidative stress and S-nitrosation and nitration events throughout ripening. Carotenoid, tocopherol, flavonoid and ascorbate biosynthesis were differentially affected by NO, resulting in overaccumulation of ascorbate (25%) and flavonoids (60%), and impaired lycopene production. In contrast, the biosynthesis of compounds related to tomato taste (sugars, organic acids, amino acids) and aroma (volatiles) was slightly affected by NO. Our findings indicate that NO triggers extensive transcriptional and metabolic rewiring at the early ripening stage, modifying tomato antioxidant composition with minimal impact on fruit taste and aroma.This work was supported by the São Paulo Research Foundation (FAPESP) (grants 2018/16389-8, 2016/04924-0, 2017/17935-3 and 2016/01128-9), Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) (grants 422287/2018-0, 305012/2018-5, 303332/2019-0 and 300986/2018-1), and Coordenação de Aperfeiçoamento de Pessoal de Nível Superior – Brasil (CAPES) – Finance Code 001. The research work of FJC and JMP is supported by a European Regional Development Fund cofinanced grant from the Ministry of Economy and Competitiveness (AGL2015-65104-P and PID2019-103924GB-I00), Spain