826 research outputs found
A Simple, Quick, and Precise Procedure for the Determination of Water in Organic Solvents
A procedure for the UV/VIS-spectroscopic determination of water by the use of a solvatochromic pyridiniumphenolate betaine is given. The water content of organic solvents is calculated by a two parameter equation from λmax of the dye. A typical, detection limit is of the order of 1 mg in 1 ml solvent for routine spectrometers. The parameters for the determination of water are given for a number of commonly used solvents
Infrared identification of hard X-ray sources in the Galaxy
The nature of the low- to intermediate-luminosity (LX ∼ 1032–34 erg s−1) source population revealed in hard band (2–10 keV) X-ray surveys of the Galactic plane is poorly understood. To overcome such problem, we cross-correlated the XMM–Newton 3XMM-DR4 survey with the infrared Two Micron All Sky Survey and Galactic Legacy Infrared Mid-Plane Survey Extraordinaire catalogues. We identified reliable X-ray–infrared associations for 690 sources. We selected 173 sources having hard X-ray spectra, typical of hard X-ray high-mass stars (kT > 5 keV), and 517 sources having soft X-ray spectra, typical of active coronae. About 18 per cent of the soft sources are classified in the literature: ∼91 per cent as stars, with a minor fraction of Wolf–Rayet (WR) stars. Roughly 15 per cent of the hard sources are classified in the literature: ∼68 per cent as high-mass X-ray stars single or in binary systems (WR, Be and high-mass X-ray binaries – HMXBs), with a small fraction of G and B stars. We carried out infrared spectroscopic pilot observations at the William Herschel Telescope for five hard X-ray sources. Three of them are high-mass stars with spectral types WN7-8h, Ofpe/WN9 and Be, and LX ∼ 1032–1033erg s−1. One source is a colliding-wind binary, while another source is a colliding-wind binary or a supergiant fast X-ray transient in quiescence. The Be star is a likely γ-Cas system. The nature of the other two X-ray sources is uncertain. The distribution of hard X-ray sources in the parameter space made of X-ray hardness ratio, infrared colours and X-ray-to-infrared flux ratio suggests that many of the unidentified sources are new γ-Cas analogues, WRs and low LX HMXBs. However, the nature of the X-ray population with Ks ≥ 11 and average X-ray-to-infrared flux ratio remains unconstrained.We acknowledge financial support from the ARCHES project (7th Framework of the
European Union, no. 313146). FJC acknowledges financial support from the Spanish Ministerio de EconomÃa y Competitividad under project AYA2012-31447.Peer Reviewe
An optical spectroscopic H-R diagram for low-mass stars and brown dwarfs in Orion
The masses and temperatures of young low mass stars and brown dwarfs in star-
forming regions are not yet well established because of uncertainties in the
age of individual objects and the spectral type vs. temperature scale
appropriate for objects with ages of only a few Myr. Using multi-object optical
spectroscopy, 45 low-mass stars and brown dwarfs in the Trapezium Cluster in
Orion have been classified and 44 of these confirmed as bona fide cluster
members. The spectral types obtained have been converted to effective
temperatures using a temperature scale intermediate between those of dwarfs and
giants, which is suitable for young pre-main sequence objects. The objects have
been placed on an H-R diagram overlaid with theoretical isochrones. The low
mass stars and the higher mass substellar objects are found to be clustered
around the 1 Myr isochrone, while many of the lower mass substellar objects are
located well above this isochrone. An average age of 1 Myr is found for the
majority of the objects. Assuming coevality of the sources and an average age
of 1 Myr, the masses of the objects have been estimated and range from 0.018 to
0.44Msun. The spectra also allow an investigation of the surface gravity of the
objects by measurement of the sodium doublet equivalent width. With one
possible exception, all objects have low gravities, in line with young ages,
and the Na indices for the Trapezium objects lie systematically below those of
young stars and brown dwarfs in Chamaeleon, suggesting that the 820 nm Na index
may provide a sensitive means of estimating ages in young clusters.Comment: 19 pages, accepted by MNRA
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Accretion-ejection connection in the young brown dwarf candidate ISO-Cha1 217
As the number of observed brown dwarf outflows is growing it is important to
investigate how these outflows compare to the well studied jets from young
stellar objects. A key point of comparison is the relationship between outflow
and accretion activity and in particular the ratio between the mass outflow and
accretion rates (/). The brown dwarf candidate
ISO-ChaI 217 was discovered by our group, as part of a spectro-astrometric
study of brown dwarfs, to be driving an asymmetric outflow with the
blue-shifted lobe having a position angle of 20. The aim here
is to further investigate the properties of ISO-ChaI 217, the morphology and
kinematics of its outflow, and to better constrain
(/). The outflow is spatially resolved in the
lines and is detected out to 1\farcs6
in the blue-shifted lobe and ~ 1" in the red-shifted lobe. The asymmetry
between the two lobes is confirmed although the velocity asymmetry is less
pronounced with respect to our previous study. Using thirteen different
accretion tracers we measure log() [M/yr]= -10.6
0.4. As it was not possible to measure the effect of extinction on the ISO-ChaI
217 outflow was derived for a range of values of A, up to
a value of A = 2.5 mag estimated for the source extinction. The logarithm
of the mass outflow () was estimated in the range -11.7 to -11.1
for both jets combined. Thus / [\Msun/yr] lies
below the maximum value predicted by magneto-centrifugal jet launching models.
Finally, both model fitting of the Balmer decrements and spectro-astrometric
analysis of the H line show that the bulk of the H I emission comes
from the accretion flow.Comment: accepted by Astronomy & Astrophysic
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