PWM Carrier Displacement in Multi-N-Phase Drives: An Additional Degree of Freedom to Reduce the DC-Link Stress

The paper presents a particular Pulse Width Modulation (PWM) strategy to reduce the (Direct Current) DC-link capacitor stress for multi-n-phase drives. A multi-n-phase drive is composed of multiple independent systems of n inverter supplying a multi-n-phase electric machine. The paper focused on the investigation of the best phase shifting between carriers for a triple-3-phase drive compared to the 3-phase counterpart in order to reduce the capacitor bench design point. Simulation and experimental results show as the control technique proposed is able to reduce the value of the DC-link capacitor current in any operating condition including fault case. In this sense, the PWM carrier displacement appears like an additional degree of freedom that can be exploited in multi-n-phase drives but also in multi-motor application

Using the electron spin resonance to detect the functional centers in materials for sensor devices

AbstractThe paper reports and comments the results of several electron spin resonance investigations, performed on semiconductor oxides for gas sensing. The main aspects, related to the comparison between spectroscopic and electric data, are concerning on (i) the role of the oxide defects in interacting with the gas atmosphere; (ii) the origin of the sensing enhancement, which follows the doping of the oxide by transition metal ions; and (iii) the effects of different particle morphology and of the controlled particle shape on the sensing functionality. The electron spin resonance results have been associated, when possible, to those deriving from X-ray photoelectron spectroscopy, in order to investigate the electronic configuration of the transition metal centers. Special emphasis has been deserved to the oxide synthesis procedures, in several cases well related to the electrical response. The data have been drawn from several studies, performed in different time periods, and have been compared to suggest a possible common interpretation of the sensing mechanism, based on either electronic or morphological properties

Fast hardware protection for a series-series compensated inductive power transfer system for electric vehicles

The paper proposes a simple solution to a safety problem encountered during the development of a series-series compensated IPT system for electric vehicles. This problem is related to the equivalent current source behavior of the receiver side in presence of an unpredicted load disconnection. A pure analog hardware system able to manage this fault protecting the filtering elements of the system is proposed. The system is investigated by means of a circuit simulation then its physical implementation is presented. The effectiveness of the proposed solution is experimentally proven

Thermally Regenerable Redox Flow Battery for Exploiting Low-Temperature Heat Sources

Harvesting energy from low-temperature heat sources (<100°C) would enable the exploitation of currently untapped renewable sources. Recently proposed techniques fail to reach suitable efficiencies. We propose here a redox flow battery that can be recharged by a thermal process, distillation. The electrochemical cell produces electrical energy from the mixing free energy of two sodium iodide aqueous solutions at different concentrations. The electrochemical cell is based on the technology of sodium ion-conducting ceramics and is coupled with a liquid-liquid extraction process, performed by an unconventional device, the "through-liquid-exchanger." Our technique bypasses the bottleneck of other similar techniques by working with solutions at very high concentrations. Our initial experiments prove an unprecedented energy efficiency (ratio between the electrical work produced and the incoming heat necessary to restore the initial solutions concentrations) of 3% from a heat source <100°C and a power density of 10 W/m2, with the possibility of further improvements. © 2020 The Author(s) The flow battery described by Facchinetti et al. can be recharged by distillation with heat sources <100°C. It enables the efficient exploitation of currently untapped clean and renewable heat sources (e.g., low-concentration solar heat collectors). The design is based on a solid-state ion conductor and includes an unconventional device based on liquid-liquid exchange

Quaterpyridine Ligands for Panchromatic Ru(II) Dye Sensitizers

A new general synthetic access to carboxylated quaterpyridines (qpy), of interest as ligands for panchromatic dyesensitized solar cell organometallic sensitizers, is presented. The strategic step is a Suzuki−Miyaura cross-coupling reaction, which has allowed the preparation of a number of representative unsubstituted and alkyl and (hetero)aromatic substituted qpys. To bypass the poor inherent stability of 2-pyridylboronic acid derivatives, we successfully applied N-methyliminodiacetic acid (MIDA) boronates as key reagents, obtaining the qpy ligands in good yields up to (quasi)gram quantities. The structural, spectroscopic (NMR and UV−vis), electrochemical, and electronic characteristics of the qpy have been experimentally and computationally (DFT) investigated. The easy access to the bis-thiocyanato Ru(II) complex of the parent species of the qpy series, through an efficient route which bypasses the use of Sephadex column chromatography, is shown. The bis-thiocyanato Ru(II) complex has been spectroscopically (NMR and UV−vis), electrochemically, and computationally investigated, relating its properties to those of previously reported Ru(II)−qpy complexes.“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Organic Chemistry], copyright © American Chemical Society after peer review and technical editing by the publisher

Theoretical and experimental comparison of two interoperable dynamic wireless power transfer systems for electric vehicles

The paper discusses two wireless power transfer systems for the charge of electric vehicles during the motion. The systems are conceived to be interoperable with the same receiver structure. Both systems are supplied by means of the same power electronics architecture and are based on the series-series compensation of the coils. In one of the presented systems a high-frequency transformer is used at the transmitter side. The two solutions are analyzed and compared pointing out their advantages and drawbacks. Results of experimental tests are presented to demonstrate the operations of both systems

Effect of the alkali insertion ion on the electrochemical properties of nickel hexacyanoferrate electrodes

Nickel hexacyanoferrate (NiHCFe) is an attractive cathode material in both aqueous and organic electrolytes due to a low-cost synthesis using earth-abundant precursors and also due to its open framework, Prussian blue-like crystal structure that enables ultra-long cycle life, high energy efficiency, and high power capability. Herein, we explored the effect of different alkali ions on the insertion electrochemistry of NiHCFe in aqueous and propylene carbonate-based electrolytes. The large channel diameter of the structure offers fast solid-state diffusion of Li+, Na+, and K+ ions in aqueous electrolytes. However, all alkali ions in organic electrolytes and Rb+ and Cs+ in aqueous electrolytes show a quasi-reversible electrochemical behavior that results in poor galvanostatic cycling performance. Kinetic regimes in aqueous electrolyte were also determined, highlighting the effect of the size of the alkali ion on the electrochemical properties.open3

Sensorless control of the charging process of a dynamic inductive power transfer system with interleaved nine-phase boost converter

The paper proposes a technique for the control of the charging process in a dynamic inductive power transfer system for automotive applications. This technique is based on an impedance control loop on the receiver side. The proposed control allows to carry out the different phases of the charging process in absence of a communication link between ground and vehicle side. The charging process starts with a sensorless procedure for the identification of the actual presence of the vehicle over the receiver. The same control technique introduces several advantages in terms of interoperability between systems having different requirements in terms of power demand. A 11 kW prototype has been implemented based on a transmitter 1.5 meters long as compromise solution between the long track coil and the lumped one. The power management of the receiver side is provided by a nine-phase interleaved boost converter. The experimental results prove the effectiveness of the proposed control together with a good matching with the developed theoretical equations set for the system description

Comparative life cycle assessment of Fe2O3-based fibers as anode materials for sodium-ion batteries

AbstractSodium-ion batteries (SIBs) potentially represent a more sustainable, less expensive and environmentally friendly alternative to lithium-ion batteries. The development of new low-cost, non-toxic, highly performing electrode materials is the key point for the SIB technology advances. This study develops a basic life cycle assessment (LCA) model for the evaluation of the production by electrospinning of iron (III) oxide-based fibers to be used as anode materials in SIBs. Indeed, it has been recently demonstrated that electrospun silicon-doped iron (III) oxide (Fe2O3) fibers exhibit outstanding electrochemical properties and gravimetric capacities never achieved before for pure Fe2O3-based anodes. The LCA methodology is utilized in order to analyze the environmental burdens (from raw material extraction to manufacturing process) of these electrode materials. The simplified comparative LCA studies, conducted to assess the environmental impacts associated with the electrospun Fe2O3 and Fe2O3:Si fibers at the same cell performance, demonstrate that the Si-doped anode material, which exhibits better electrochemical performance with respect to the undoped one, has also lower impact for each category of damage, namely human health, ecosystem quality and resources