Environmental and geochemical characteristics of heavy metals in soils around the former mining area of zeïda (High Moulouya, Morocco)

The Zeïda mining center, closed in the mid-1980s, was once intensively exploited for lead concentrates. Throughout its activity, more than 12 Mt of tailings were generated and, to this day, they are still abandoned in the open air, exposed to weathering conditions without any rehabilitation. The purpose of the present study is to evaluate the environmental and geochemical characteristics of the soils, combining physicochemical, mineralogical, sequential, and kinetic extraction analyses, as well as the metallic spatial distribution and pollution indices of heavy metals (Pb, Cd, Cu, As, and Zn), levels, and risks. The results showed that the abandoned tailings had the highest concentrations of heavy metals, far exceeding their equivalents in the international and local guidelines. The soils spatial distribution maps showed that the levels of heavy metals decreased with distance from the tailings. Based on the pollution indices results, the soils located on and near the tailings are highly contaminated mainly by Pb. While downstream of the tailings, this contamination intensity decreased until becoming null. The sequential extraction results indicated that Pb, Zn, and Cd were primarily associated with the exchangeable fraction in tailings and soils. Therefore, they were more mobile and environmentally hazardous in the study area. The As was mainly associated with the residual fraction, and was thus immobile. Cu was more mobile in tailings as long as it was associated with the reducible fraction while it became immobile in the downstream soils. The kinetic extractions using EDTA and H2O revealed that the labile and less labile fractions were very significant in tailing for the majority of heavy metals. The methodology applied in this study may constitute a valuable tool to develop appropriate mine reclamation solution

Human demography changes in Morocco and environmental imprint during the Holocene

The aim of this work is to reconstruct the periods of growth and decline of human populations in Morocco and their potential impacts on the landscape over the past 10,000 years. In order to estimate the trends in the human population size between 10,000 and 3000 years ago, we used a summed probability distribution (SPD) of radiocarbon dates from a wide range of archaeological sites throughout Morocco. Landscape changes were identified and quantified from a dataset of fossil pollen records. Different anthropogenic pollen markers, as well as natural vegetation groups and taxonomic richness were used to analyse the relationship between long-term trends in human population expansion or regression and type of impact on the landscape. The sub-regions of Morocco have different topographies and climates, which have either favoured or prevented the establishment and/or spread of human populations. In order to identify the areas most significantly impacted by humans and the timing of such impacts, we have reconstructed and compared the same past anthropogenic and landscape proxies along with the population trends within the lowlands and mountainous areas. The lowlands were more strongly impacted earlier in the Holocene than the mountainous areas. Anthropogenic markers indicate that farming expanded in the lowlands during the first major expansion of human populations between ca. 7200 and 6700 cal. yr BP at the start of the Neolithic period. In the Atlas and Rif Mountains, anthropogenic impact is not clearly detectable in any of these areas before 4000 cal. BP. </jats:p

The age and origin of groundwater in the Great Western Erg sub-basin of the North-Western Sahara aquifer system: insights from Krechba, central Algeria

Abstract: The North-Western Sahara aquifer system (NWSAS) forms an important transboundary groundwater resource whose properties remain to be fully understood across its whole extent. For example, groundwater flow in the Cretaceous Continental Intercalaire (CI) unit of the NWSAS is well-characterised in the northern part of its range around the Algeria/Tunisia/Libya borders and in the Great Eastern Erg sub-basin immediately to the south. To the southwest, however, the CI of the Great Western Erg sub-basin has been much less studied. The present paper reports hydrogeochemical data from a wellfield in central Algeria which will contribute to a better understanding of this sector of the NWSAS in terms of the age and origin of groundwater within it. Groundwater pumped from five deep boreholes in the CI aquifer overlying the Krechba gas field has been studied using a variety of environmental tracers including hydrochemistry, environmental isotopes, and reactive and noble gases (the latter being reported for the first time for this sub-basin). All the waters were dilute (SEC 460–600 µS/cm), contained detectable O2 (6.3–7.5 mg/L), showed evidence of evaporation (relative enrichment in δ18O), gave late-Pleistocene 14C model ages (13.5–19.3 ka), and yielded lower than present-day noble gas recharge temperatures (14.3–17.6°C). Various lines of evidence suggest that these waters are the product of mixing between water recharged direct to the CI and leakage from the Neogene–Quaternary Erg aquifer. The results support the long-held concept of regional flow from a palaeo-recharge area to the northwest. Finally, while the Krechba gas field (Carboniferous) has been since 2004 the site of a pilot carbon capture and storage (CCS) project, the data revealed no evidence for leakage of fluids (gas or brines) into the overlying CI aquifer at the time of sampling (October 2014)

Snowpack and groundwater recharge in the Atlas mountains: New evidence and key drivers

Study region: The Atlas Mountains of Morocco, specifically the High Oum Er-rbiaa (HOER) and Ourika catchments. Study focus: to identify the recharge processes within the semi-arid watersheds, in the Atlas Mountains, through monthly monitoring of snow, rainfall, surface water, and groundwater isotope signal, but also the usage of remote sensing data. New hydrological insights for the region: The spatial-temporal analysis of groundwater and precipitation isotopes reveals significant spatial heterogeneity, primarily influenced by the geological variations in each aquifer. Temporal variations indicate that direct recharge occurs in response to winter precipitation, whereas a delayed response is observed during the summer when snow replenishes groundwater towards the end of the melting season. The findings are further supported by the ''Gravity Recovery and Climate Experiment'' (GRACE) dataset, which demonstrates that high values of Total Water Storage (TWS) align with groundwater isotopes. This highlights the substantial groundwater abstraction rate between March and June to compensate for the lack of precipitation during this period. The analysis of isotope data indicates that 50% of groundwater recharge in the upstream Jurassic aquifer and 80% in the downstream Triassic-Paleozoic aquifers in the HOER catchment is sourced from snowmelt. Similarly, in the Ourika catchment, snowmelt contributes 30% and 50% of groundwater recharge in the upstream and downstream portions of the catchments respectively. This disparity is due to different melting rates across altitudinal ranges and variations in the lithology of each catchment

Use of bathymetry and clay mineralogy of reservoir sediment to reconstruct the recent changes in sediment yields from a mountain catchment in the Western High Atlas region, Morocco

The dam of Takerkoust, located at the outlet side of N'fis Basin (Western High Atlas of Morocco), is one of the strategic reservoirs in Morocco facing a serious problem of siltation due to soil erosion. A paleo-hydrology approach combining chronological and sedimentological analyses is conducted to understand the evolution of the depositional sediment history of the Takerkoust reservoir between 1988 and 2016. First, a series of 8 bathymetric surveys in the Takerkoust reservoir was used to determine the chronology of flood event deposits. Second, grain size distribution, clay mineralogy (XRD) and organic matter content were analyzed in 2 cores drilled in the Takerkoust reservoir and the newly build Ouirgane reservoir in upstream (from which 46 samples were taken). Third, Soils samples collected from the uppermost soil horizons (First 5 cm) of different localities of the N'fis watershed were also analyzed to identify sediments origins. Eleven couplets with different textures and thickness are identified in the Takerkoust reservoir corresponding to the period 1988–2016. The highest correlation is observed between instantaneous maximum flow and thickness of the sandy component of the couplets. The variation of the siltation rate allows highlighting two distinct periods: the oldest period (1988–1999) characterized by a high sediment yield SY (908.6 t·km−2·yr−1) and a youngest one (1999–2016) characterized by a low SY (203.9 t·km−2·yr−1). The newly built Ouirgane dam, seems to be responsible for the decreasing siltation rate and change of the clay assemblages of the sedimentary series in Takerkoust reservoir

Environmental changes in the moroccan western rif mountains over the last 9,000 years

The aim of this study is to reconstruct the impact of past environmental changes in the Moroccan Rif mountainous ecosystems. We collected an 8.5 m sedimentary core in the western part of the Rif and analyzed its palynological content, micro-remains of fossil charcoal, particle size, and content of several chemical elements. The chronology of the record is based on ten 14C datings that indicate a continuous time span of 9,000 years. This multidisciplinary approach allowed us to reconstruct both the environmental evolution of the catchment area and the vegetation dynamics in the surrounding landscape. Besides the fossil record, we collected a series of surface samples along a transect running from Talassemtane National Park, where fir populations are currently protected, to the study site in order to determine the dispersal capacity of different plant taxa. Based on the modern observations, the fossil pollen data show that despite its closer range today to the study site than Cedrus atlantica (closest populations at ca. 20 km), Abies maroccana (populations at ca. 10 km) did not reach the studied site during the Holocene. At the same time, Cedrus atlantica was present and even dominated the landscape between 8,000 and 6,000 BP. After 6,000 BP, other species more tolerant to annual drought, such as evergreen oaks, expanded gradually. The early Holocene period was wet enough to promote a maximum expansion of cedar forest. The Atlas cedar disappears from the fossil record after 2,000 BP due to an increased human pressure. Particle size analysis and chemical elements are particularly relevant for reconstructing the landscape changes and for depicting the human impact. Their changes after 2,000 BP are well correlated with the forest cover decline

Contamination impact and human health risk in surface soils surrounding the abandoned mine of Zeïda, High Moulouya, Northeastern Morocco

International audienceThe study assesses the levels of 16 heavy metals (HMs) in soils around the Zeida mine to provide information on the extent of contamination, the ecological risk of these HMs in soils, and the health risk to the residents of the Zeida village. Total metal concentrations were determined by inductively coupled plasma-mass spectrometry (ICP-MS) for 20 sampling stations around the mining area. The average concentrations of HMs (mg/kg) in the study area were as follows: Ag (2.3), As (90.4), Ba (1605.1), Be (3.1), Co (11.2), Cr (57.6), Cu (33.9), Mn (499.6), Mo (6.1), Ni (23.4), Pb (1338.7), Sb (7.4), Se (1.3), Sn (11.3), Sr (596.5), and Zn (87.9). They were higher than those at the control sites. Twelve single and integrated ecological risk indices, namely Nemerow Pollution Index (PINemerow), Contamination degree (Cd), and Potential Ecological Risk (RI), were used and suggested that tailings and their nearby soils had a moderate to high contamination potential. Based on the US Environmental Protection Agency (USEPA), the carcinogenic risk, non-carcinogenic, hazard quotient (HQ), and hazard index (HI) were calculated with three routes: ingestion, inhalation, and dermal for children and adults. For both children and adults, HI for HMs was in the order: Mn > As > Co > Pb > 1 > other HMs. Mn, As, and Co were hazardous at 90% of soil sampling stations, while Pb was hazardous in tailings samples. The inhalation and dermal carcinogenic risks presented negligible to acceptable levels. The ingestion carcinogenic risk posed a significant issue for As, which tended to be serious for children at the majority of sampling sites