20 research outputs found
Electronic structure and morphology of dark oxides on zinc generated by electrochemical treatment
European Union; state of North Rhine-Westphalia in the frame of the HighTech.NRW program; Salzgitter Mannesmann Forschung GmbH in the frame of the International Max Planck Research School for Surface and Interface Engineering in Advanced Materials (IMPRS-SurMat)Oxides formed by electrochemical treatment of metals frequently have properties and structures very different from the respective bulk oxides. Here, electronic structure and chemical composition were investigated for the oxide formed on polycrystalline zinc after electrochemical oxidation, and after subsequent reduction, in a Na2CO3 electrolyte. Photoluminescence and spectroscopic ellipsometry show the presence of states deep in the ZnO band gap in the oxidized sample, which consists of a highly disordered oxide. These states determine the absorption of light in the visible spectral range. After reduction, the characteristics of the ZnO electronic structure have disappeared, leaving a defect-dominated material with a band gap of similar to 1.8 eV. Complementary detailed analysis of the morphology of the resulting surfaces shows hexagon-shaped metallic Zn-"nanoplates" to be formed in the reduction step. The optical appearance of the surfaces is dark, because of their efficient extinction of light over a large part of the visible spectrum. The optical appearance is a result of changed surface morphology and electronic structure of the oxide film. Such materials may possess interesting applications in photocatalysis or photoelectrochemistry
Space-borne Bose-Einstein condensation for precision interferometry
Space offers virtually unlimited free-fall in gravity. Bose-Einstein
condensation (BEC) enables ineffable low kinetic energies corresponding to
pico- or even femtokelvins. The combination of both features makes atom
interferometers with unprecedented sensitivity for inertial forces possible and
opens a new era for quantum gas experiments. On January 23, 2017, we created
Bose-Einstein condensates in space on the sounding rocket mission MAIUS-1 and
conducted 110 experiments central to matter-wave interferometry. In particular,
we have explored laser cooling and trapping in the presence of large
accelerations as experienced during launch, and have studied the evolution,
manipulation and interferometry employing Bragg scattering of BECs during the
six-minute space flight. In this letter, we focus on the phase transition and
the collective dynamics of BECs, whose impact is magnified by the extended
free-fall time. Our experiments demonstrate a high reproducibility of the
manipulation of BECs on the atom chip reflecting the exquisite control features
and the robustness of our experiment. These properties are crucial to novel
protocols for creating quantum matter with designed collective excitations at
the lowest kinetic energy scales close to femtokelvins.Comment: 6 pages, 4 figure
Electronic structure and morphology of dark oxide on zinc generated by electrochemical treatment
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Electronic structure and morphology of dark oxides on zinc generated by electrochemical treatment
Oxides formed by electrochemical treatment of metals frequently have properties and structures very different from the respective bulk oxides. Here, electronic structure and chemical composition were investigated for the oxide formed on polycrystalline zinc after electrochemical oxidation, and after subsequent reduction, in a Na2CO3 electrolyte. Photoluminescence and spectroscopic ellipsometry show the presence of states deep in the ZnO band gap in the oxidized sample, which consists of a highly disordered oxide. These states determine the absorption of light in the visible spectral range. After reduction, the characteristics of the ZnO electronic structure have disappeared, leaving a defect-dominated material with a band gap of ∼1.8 eV. Complementary detailed analysis of the morphology of the resulting surfaces shows hexagon-shaped metallic Zn-"nanoplates" to be formed in the reduction step. The optical appearance of the surfaces is dark, because of their efficient extinction of light over a large part of the visible spectrum. The optical appearance is a result of changed surface morphology and electronic structure of the oxide film. Such materials may possess interesting applications in photocatalysis or photoelectrochemistry