A depositional model for spherulitic carbonates associated with alkaline, volcanic lakes

The South Atlantic Aptian ‘Pre-salt’ reservoirs are formed by a combination of spherulitic carbonates and Mg-rich clays accumulated in volcanic alkaline lake settings with exotic chemistries. So far, outcrop analogues characterised by metre-thick successions deposited in lacustrine scenarios are elusive so disentangling the genesis of spherulitic carbonates represents a major scientific challenge with business impact. In particular the controls on spatial distribution and the environment of spherulitic facies formation remain poorly constrained, little studied, and hotly debated. To shed light on this conundrum, a spherulitic carbonate-rich, alkaline volcanic lacustrine succession has been analysed at outcrop scale: the Carboniferous East Kirkton Limestone (Scotland). Despite clays being very scarce and limited to layers of amorphous Mg-Si minerals, a diverse array of spherulitic calcitic components were formed, including coated grains, crusts, and build-ups. This setting enables the mechanisms of spherulitic calcite development and the patterns of sediment accumulation to be explored in a geobiological and hydrochemical scenario similar to the ‘Pre-Salt’ subsurface occurrences but divorced from clay influence. The integration of logs, borehole data, outcrop photomosaics and petrographic observations collectively allowed the reconstruction of a depositional model for the East Kirkton lacustrine succession. In this model, calcite spherule nucleation took place at the sediment-water interface in the littoral zone, driven by the co-occurrence of 1) high alkalinity, 2) Ca-Mg rich hydrochemistry, and 3) microbial-derived colloidal exopolymeric substances. These environmental conditions permitted the coeval development of spherulitic cementstone build-ups and spherulitic grainstone-packstone within the wave-agitated zone, and the accumulation of floatstones and laminites of spherulitic grains in deeper lake regions by means of downslope reworking. This model is consistent with the previously documented microbial bloom occurrences and highlights the need to better understand the complex ‘microbe-solution’ interactions before any reliable facies model is envisaged

The geomorphological distribution of subaqueous tufa columns within a hypersaline lake : Mono Lake, USA

Acknowledgments This work was supported by funding from BP Group. We thank the Mono Lake Committee for supporting fieldwork and for helping our vessel onto and most of all off the lake, and the State of California for permitting access to the lake and its environs. Dave Marquart is thanked for his support and knowledge of the lake environment. Cody and Phillip are thanked for their help on the lake, and Vern for vital logistical support. Ian Billing is thanked for his instrumental involvement in this project, and his role in shaping our thoughts. We hope he would be pleased with this paper. Dr. Chelsea Pederson, Dr. W. Fischer are heartily thanked for their excellent efforts as reviewers improving this manuscript, and Dr. Juan Carlos Laya is thanked for his careful handling of the manuscript as Associate Editor.Peer reviewedPostprin

Are spherulitic lacustrine carbonates an expression of large-scale mineral carbonation? : A case study from the East Kirkton Limestone, Scotland

BP Exploration Co. is thanked for funding, and particularly the Carbonate Team for supporting this research and for fruitful discussions. West Lothian Council and Scottish Natural Heritage are thanked for allowing access and permission for sampling the site. The Core Store Team at BGS Keyworth is particularly acknowledged for their assistance. Mark Anderson, Tony Sinclair (University of Hull), and Bouk Lacet (VU University Amsterdam) are thanked for technical support. Anne Kelly (SUERC) for carrying out the Strontium Isotope analyses. Mark Tyrer is thanked for his advice on PHREEQC modelling.Peer reviewedPostprin

A test of the biogenicity criteria established for microfossils and stromatolites on quaternary tufa and speleothem materials formed in the “Twilight zone” at Caerwys, UK

© 2015, Mary Ann Liebert, Inc. The ability to distinguish the features of a chemical sedimentary rock that can only be attributed to biology is a challenge relevant to both geobiology and astrobiology. This study aimed to test criteria for recognizing petrographically the biogenicity of microbially influenced fabrics and fossil microbes in complex Quaternary stalactitic carbonate rocks from Caerwys, UK. We found that the presence of carbonaceous microfossils, fabrics produced by the calcification of microbial filaments, and the asymmetrical development of tufa fabrics due to the more rapid growth of microbially influenced laminations could be recognized as biogenic features. Petrographic evidence also indicates that the development of "speleothem-like" laminae was related to episodes of growth interrupted by intervals of nondeposition and erosion. The lack of any biogenic characteristics in these laminae is consistent with their development as a result of variation in the physicochemical parameters that drive calcite precipitation from meteoric waters in such environmental settings

Including debris cover effects in a distributed model of glacier ablation

Distributed glacier melt models generally assume that the glacier surface consists of bare exposed ice and snow. In reality, many glaciers are wholly or partially covered in layers of debris that tend to suppress ablation rates. In this paper, an existing physically based point model for the ablation of debris-covered ice is incorporated in a distributed melt model and applied to Haut Glacier d’Arolla, Switzerland, which has three large patches of debris cover on its surface. The model is based on a 10 m resolution digital elevation model (DEM) of the area; each glacier pixel in the DEM is defined as either bare or debris-covered ice, and may be covered in snow that must be melted off before ice ablation is assumed to occur. Each debris-covered pixel is assigned a debris thickness value using probability distributions based on over 1000 manual thickness measurements. Locally observed meteorological data are used to run energy balance calculations in every pixel, using an approach suitable for snow, bare ice or debris-covered ice as appropriate. The use of the debris model significantly reduces the total ablation in the debris-covered areas, however the precise reduction is sensitive to the temperature extrapolation used in the model distribution because air near the debris surface tends to be slightly warmer than over bare ice. Overall results suggest that the debris patches, which cover 10% of the glacierized area, reduce total runoff from the glacierized part of the basin by up to 7%

The modelled surface mass balance of the Antarctic Peninsula at 5.5 km horizontal resolution

This study presents a high-resolution (~ 5.5 km) estimate of Surface Mass Balance (SMB) over the period 1979–2014 for the Antarctic Peninsula (AP), generated by the regional atmospheric climate model RACMO2.3 and a Firn Densification Model (FDM). RACMO2.3 is used to force the FDM, which calculates processes in the snowpack, such as meltwater percolation, refreezing and runoff. We evaluate model output with 132 in-situ SMB observations and discharge rates from 6 glacier drainage basins, and find that the model realistically simulates the strong spatial variability in precipitation, but that significant biases remain as a result of the highly complex topography of the AP. It is also clear that the observations significantly underrepresent the high-accumulation regimes. The SMB map reveals large accumulation gradients, with precipitation values above 3000 mm we yr−1 over the western AP (WAP) and below 500 mm we yr−1 on the eastern AP (EAP), not resolved by coarser data-sets such as ERA-Interim. The other SMB components are one order of magnitude smaller, with drifting snow sublimation the largest ablation term removing up to 100 mm we yr−1 of mass. Snowmelt is widespread over the AP, reaching 500 mm we yr−1 towards the northern ice shelves, but the meltwater mostly refreezes. As a result runoff fluxes are low, but still considerable (200 mm we yr−1) over the Larsen (B/C), Wilkins and George VI ice shelves. The average AP ice sheet integrated SMB, including ice shelves (an area of 4.1 × 105 km2), is estimated at 351 Gt yr−1 with an interannual variability of 58 Gt yr−1, which is dominated by precipitation (PR) (365 ± 57 Gt yr−1). The WAP (2.4 × 105 km2) SMB (276 ± 47 Gt yr−1), where PR is large (276 ± 47 Gt yr−1), dominates over the EAP (1.7 × 105 km2) SMB (75 ± 11 Gt yr−1) and PR (84 ± 11 Gt yr−1). Total sublimation is 11 ± 2 Gt yr−1 and meltwater runoff into the ocean is 4 ± 4 Gt yr−1. There are no significant trends in any of the AP SMB components, except for snowmelt that shows a significant decrease over the last 36 years (−0.36 Gt yr−2)

Особливості урбаністичного хронотопу в поезіях літугруповання “Бу-Ба-Бу”

Стаття присвячена дослідженню особливостей урбаністичного хронотопу в поезіях Ю. Андруховича, О. Ірванця, В. Неборака. Встановлено, що характерними модифікаціями урбаністичного хронотопу у творчості Ю. Андруховича є топографічний хронотоп із домінантами Львова й Станіслава та карнавалізоване Місто; у поезіях В. Неборака варіації урбаністичного хронотопу створюються за допомогою використання традиційних атрибутів міста, а також власне міських прошарків населення; урбаністичний хронотоп у поезіях О. Ірванця є найменше матеріалізованим і тяжіє до психологічно-метафізичного. Ключові слова: часопростір, хронотоп, топос, урбанізм, карнавалізація.Статья посвящена изучению особенностей урбанистического хронотопа в поэзиях Ю. Андруховича, А. Ирванца, В. Неборака. Так, в творчестве Ю. Андруховича были выявлены такие модификации урбанистического хронотопа, как топографический с доминантами Львова и Станислава и карнавальный Город; в поэзиях В. Неборака вариации урбанистического хронотопа осуществляются при помощи использования традиционных атрибутов города, а также собственно городских слоев населения; урбанистический хронотоп поэзий А. Ирванца наименее материализован и тяготеет к психологически-метафизическому. Ключевые слова: пространственно-временное единство, хронотоп, топос, урбанистичность, карнавальность.The article is dedicated to the study of the urbanism chronotope’s particularities in Yu. Andruhovicha, A. Irvanca, V. Neboraka poetry. So in Yu. Andruhovich’s work. Such modification urbanism chronotope as topographical one with the Livov and Stanislav’s dominant and the carnival one. In V. Neboraka’s variations of urbanism chronotope are realized using the traditional city attributes and town population layers as well. A. Irvanc’s poetry urbanism chronotope is less materialired and strongly attracted by psychological-metaphysical one. Keywords: space-time unity, chronotope, urbanism, carnivalization

The abrupt onset of the modern South Asian Monsoon winds

The South Asian Monson (SAM) is one of the most intense climatic elements yet its initiation and variations are not well established. Dating the deposits of SAM wind-driven currents in IODP cores from the Maldives yields an age of 12. 9 Ma indicating an abrupt SAM onset, over a short period of 300 kyrs. This coincided with the Indian Ocean Oxygen Minimum Zone expansion as revealed by geochemical tracers and the onset of upwelling reflected by the sediment's content of particulate organic matter. A weaker 'proto-monsoon' existed between 12.9 and 25 Ma, as mirrored by the sedimentary signature of dust influx. Abrupt SAM initiation favors a strong influence of climate in addition to the tectonic control, and we propose that the post Miocene Climate Optimum cooling, together with increased continentalization and establishment of the bipolar ocean circulation, i.e. the beginning of the modern world, shifted the monsoon over a threshold towards the modern system

A new albedo parameterization for use in climate models over the Antarctic ice sheet

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/95255/1/jgrd16889.pd

Corrigendum to “Carbonate delta drift: A new sediment drift type” [Mar. Geol. 401 (2018) 98–111]

The authors regret the mistake in the drawing of the delta drift architecture in figure 11. The authors would like to apologise for any inconvenience caused. [Figure presented