The Hydraulic Mission and the Mexican Hydrocracy: Regulating and Reforming the Flows of Water and Power

In Mexico, the hydraulic mission, the centralisation of water control, and the growth of the federal hydraulic bureaucracy (hydrocracy) recursively shaped and reinforced each other during the 20th century. The hydraulic mission entails that the state, embodied in an autonomous hydrocracy, takes the lead in water resources development to capture as much water as possible for human uses. The hydraulic mission was central to the formation of Mexico’s hydrocracy, which highly prized its autonomy. Bureaucratic rivals, political transitions, and economic developments recurrently challenged the hydrocracy’s degree of autonomy. However, driven by the argument that a single water authority should regulate and control the nation’s waters, the hydrocracy consistently managed to renew its, always precarious, autonomy at different political moments in the country’s history. The legacy of the hydraulic mission continues to inform water reforms in Mexico, and largely explains the strong resilience of the Mexican hydrocracy to "deep" institutional change and political transitions. While the emphasis on infrastructure construction has lessened, the hydrocracy has actively renewed its control over water decisions and budgets and has played a remarkably constant, hegemonic role in defining and shaping Mexico’s water laws, policies and institutions

The leidenfrost phenomenon on structured surfaces

This paper was presented at the 4th Micro and Nano Flows Conference (MNF2014), which was held at University College, London, UK. The conference was organised by Brunel University and supported by the Italian Union of Thermofluiddynamics, IPEM, the Process Intensification Network, the Institution of Mechanical Engineers, the Heat Transfer Society, HEXAG - the Heat Exchange Action Group, and the Energy Institute, ASME Press, LCN London Centre for Nanotechnology, UCL University College London, UCL Engineering, the International NanoScience Community, www.nanopaprika.eu.The lifetime of a droplet released on a hot plate decreases when the temperature of the plate increases. But above some critical value of the temperature, the lifetime suddenly increases. This is due to the formation of a thin layer of vapour between the droplet and the substrate. This layer plays a double role: first it thermally isolates the droplet from the plate and second it allows the droplet to “levitate.” This effect was discovered by Leidenfrost in 1756, but remains an active field of research nowadays, motivated by a wide range of applications. The Leidenfrost point is affected by the roughness or microstructure of the surface. In this work, a silicon surface with different micro-structured regions of square-pillars was prepared such that there is a sharp transition (boundary) between areas of different pillar spacing. The Leidenfrost point was identified in experiments using water drops ranging in average size from 8 μL to 24 μL and the behaviour of the droplets was recorded using a high-speed digital camera. We show that the Leidenfrost point can vary by up to 120 °C for pillar spacings varying from 10 microns to 100 microns. If the drop is placed on the boundary between structured sections, the drop becomes asymmetric. Drop motion may also be observed and some occurrences of drop spinning have been seen. In this paper we present experimental data on Leidenfrost behaviour of drops placed structured surfaces and on the boundary between surfaces with different micro-structures

Importance of tropospheric volcanic aerosol for indirect radiative forcing of climate

Observations and models have shown that continuously degassing volcanoes have a potentially large effect on the natural background aerosol loading and the radiative state of the atmosphere. We use a global aerosol microphysics model to quantify the impact of these volcanic emissions on the cloud albedo radiative forcing under pre-industrial (PI) and present-day (PD) conditions. We find that volcanic degassing increases global annual mean cloud droplet number concentrations by 40% under PI conditions, but by only 10% under PD conditions. Consequently, volcanic degassing causes a global annual mean cloud albedo effect of −1.06 W m−2 in the PI era but only −0.56 W m−2 in the PD era. This non-equal effect is explained partly by the lower background aerosol concentrations in the PI era, but also because more aerosol particles are produced per unit of volcanic sulphur emission in the PI atmosphere. The higher sensitivity of the PI atmosphere to volcanic emissions has an important consequence for the anthropogenic cloud radiative forcing because the large uncertainty in volcanic emissions translates into an uncertainty in the PI baseline cloud radiative state. Assuming a −50/+100% uncertainty range in the volcanic sulphur flux, we estimate the annual mean anthropogenic cloud albedo forcing to lie between −1.16 W m−2 and −0.86 W m−2. Therefore, the volcanically induced uncertainty in the PI baseline cloud radiative state substantially adds to the already large uncertainty in the magnitude of the indirect radiative forcing of climate

The radiative effect of ion-induced inorganic nucleation in the free troposphere

To determine the effect of cosmic rays on the Earth's climate via ion-induced nucleation, a parametrisation of inorganic nucleation was formulated based on experiments at the CERN CLOUD experiment. The parametrisation was implemented in the GLOMAP aerosol microphysics model and used to estimate the radiative effect of the change in ionisation experienced over an 11-year solar cycle

Sensitivity of mid-19th century tropospheric ozone to atmospheric chemistry-vegetation interactions

We use an Earth-System model (HadGEM2-ES) to investigate the sensitivity of mid-19th century tropospheric ozone to vegetation distribution and atmospheric chemistry-vegetation interaction processes. We conduct model experiments to isolate the response of mid-19th century tropospheric ozone to vegetation cover changes between the 1860s and present-day and to CO2 induced changes in isoprene emissions and dry deposition over the same period. Changes in vegetation distribution and CO2 suppression of isoprene emissions between mid-19th century and present-day, lead to decreases in global isoprene emissions of 19% and 21% respectively. This results in increases in surface ozone over the continents of up to 2 ppbv and of 2-6 ppbv in the tropical upper troposphere. The effects of CO2 increases on suppression of isoprene emissions and suppression of dry deposition to vegetation are small compared with the effects of vegetation cover change. Assuming present-day climate in addition to present-day vegetation cover and atmospheric CO2 concentrations, leads to increases in surface ozone concentrations of up to 5 ppbv over the entire northern hemisphere (NH), and of up to 8 ppbv in the NH free troposphere, compared with a mid-19th century simulation. Ozone changes are dominated by: 1) the role of isoprene as an ozone sink in the low NOx mid-19th century at30 mosphere, and 2) the redistribution of NOx to remote regions and the free troposphere via PAN (peroxyacetyl nitrate) formed from isoprene oxidation. We estimate a tropospheric ozone radiative forcing of 0.264W m−2 and a sensitivity in ozone radiative forcing to mid-19th century to present-day vegetation cover change of -0.012W m−2

Influence of enhanced Asian NOx emissions on ozone in the upper troposphere and lower stratosphere in chemistry–climate model simulations

The Asian summer monsoon (ASM) anticyclone is the most pronounced circulation pattern in the upper troposphere and lower stratosphere (UTLS) during northern hemispheric summer. ASM convection plays an important role in efficient vertical transport from the surface to the upper-level anticyclone. In this paper we investigate the potential impact of enhanced anthropogenic nitrogen oxide (NOx) emissions on the distribution of ozone in the UTLS using the fully coupled aerosol–chemistry–climate model, ECHAM5-HAMMOZ. Ozone in the UTLS is influenced both by the convective uplift of ozone precursors and by the uplift of enhanced-NOx-induced tropospheric ozone anomalies. We performed anthropogenic NOx emission sensitivity experiments over India and China. In these simulations, covering the years 2000–2010, anthropogenic NOx emissions have been increased by 38 % over India and by 73 % over China with respect to the emission base year 2000. These emission increases are comparable to the observed linear trends of 3.8 % per year over India and 7.3 % per year over China during the period 2000 to 2010. Enhanced NOx emissions over India by 38 % and China by 73 % increase the ozone radiative forcing in the ASM anticyclone (15–40° N, 60–120° E) by 16.3 and 78.5 mW m−2 respectively. These elevated NOx emissions produce significant warming over the Tibetan Plateau and increase precipitation over India due to a strengthening of the monsoon Hadley circulation. However, increase in NOx emissions over India by 73 % (similar to the observed increase over China) results in large ozone production over the Indo-Gangetic Plain and Tibetan Plateau. The higher ozone concentrations, in turn, induce a reversed monsoon Hadley circulation and negative precipitation anomalies over India. The associated subsidence suppresses vertical transport of NOx and ozone into the ASM anticyclone