1,450 research outputs found
Noncircular Orifice Holes and Advanced Fabrication Techniques for Liquid Rocket Injectors (Phases 1, 2, 3, and 4)
A comprehensive summary of the results of a cold-flow and hot-fire experimental study of the mixing and atomization characteristics of injector elements incorporating noncircular orifices is presented. Both liquid/liquid and gas/liquid element types are discussed. Unlike doublet and triplet elements (circular orifices only) were investigated for the liquid/liquid case while concentric tube elements were investigated for the gas/liquid case. It is concluded that noncircular shape can be employed to significant advantage in injector design for liquid rocket engines
Noncircular orifice holes and advanced fabrication techniques for liquid rocket injectors. Phase 3: Analytical and cold-flow experimental evaluation of rectangular concentric tube injector elements for gas/liquid application. Phase 4: Analytical and experimental evaluation of noncircular injector elements for gas/liquid and liquid/liquid application
Results are presented of a cold-flow and hot-fire experimental study of the mixing and atomization characteristics of injector elements incorporating noncircular orifices. Both liquid/liquid and gas/liquid element types are discussed. Unlike doublet and triplet elements (circular orifices only) were investigated for the liquid/liquid case while concentric tube elements were investigated for the gas/liquid case. It is concluded that noncircular shape can be employed to significant advantage in injector design for liquid rocket engines
Surface roughness and interfacial slip boundary condition for quartz crystal microbalances
The response of a quartz crystal microbalance (QCM) is considered using a wave equation for the substrate and the Navier-Stokes equations for a finite liquid layer under a slip boundary condition. It is shown that when the slip length to shear wave penetration depth is small, the first order effect of slip is only present in the frequency response. Importantly, in this approximation the frequency response satisfies an additivity relation with a net response equal to a Kanazawa liquid term plus an additional Sauerbrey "rigid" liquid mass. For the slip length to result in an enhanced frequency decrease compared to a no-slip boundary condition, it is shown that the slip length must be negative so that the slip plane is located on the liquid side of the interface. It is argued that the physical application of such a negative slip length could be to the liquid phase response of a QCM with a completely wetted rough surface. Effectively, the model recovers the starting assumption of additivity used in the trapped mass model for the liquid phase response of a QCM having a rough surface. When applying the slip boundary condition to the rough surface problem, slip is not at a molecular level, but is a formal hydrodynamic boundary condition which relates the response of the QCM to that expected from a QCM with a smooth surface. Finally, possible interpretations of the results in terms of acoustic reflectivity are developed and the potential limitations of the additivity result should vapour trapping occur are discussed
Topography driven spreading
Roughening a hydrophobic surface enhances its nonwetting properties into superhydrophobicity. For liquids other than water, roughness can induce a complete rollup of a droplet. However, topographic effects can also enhance partial wetting by a given liquid into complete wetting to create superwetting. In this work, a model system of spreading droplets of a nonvolatile liquid on surfaces having lithographically produced pillars is used to show that superwetting also modifies the dynamics of spreading. The edge speed-dynamic contact angle relation is shown to obey a simple power law, and such power laws are shown to apply to naturally occurring surfaces
Terminal velocity and drag reduction measurements on superhydrophobic spheres
Super water-repellent surfaces occur naturally on plants and aquatic insects and are created in the laboratory by combining micro- or nanoscale surface topographic features with hydrophobic surface chemistry. When such types of water-repellent surfaces are submerged they can retain a film of air (a plastron). In this work, we report measurements of the terminal velocity of solid acrylic spheres with various surface treatments settling under the action of gravity in water. We observed increases in terminal velocity corresponding to drag reduction of between 5% and 15% for superhydrophobic surfaces that carry plastrons
Plastron induced drag reduction and increased slip on a superhydrophobic sphere
On low contact angle hysteresis superhydrophobic surfaces, droplets of water roll easily. It is intuitively appealing, but less obvious, that when such material is immersed in water, the liquid will flow more easily across its surface. In recent experiments it has been demonstrated that superhydrophobic surfaces with the same high contact angle and low contact angle hysteresis may not, in fact, have the same drag reducing properties. A key performance parameter is whether the surface is able to retain a layer of air (i.e. a plastron) when fully immersed. In this report, we consider an analytical model of Stokes flow (i.e. low Reynolds number, Re, creeping flow) across a surface retaining a continuous layer of air. The system is based on a compound droplet model consisting of a solid sphere encased in a sheathing layer of air and is the extreme limit of a solid sphere with a superhydrophobic surface. We demonstrate that an optimum thickness of air exists at which the drag on this compound object is minimized and that the level of drag reduction can approach 20 to 30%. Physically, drag reduction is caused by the ability of the external flow to transfer momentum across the water-air interface generating an internal circulation of air within the plastron
Leukemia-related chromosomal loss detected in hematopoietic progenitor cells of benzene-exposed workers.
Benzene exposure causes acute myeloid leukemia and hematotoxicity, shown as suppression of mature blood and myeloid progenitor cell numbers. As the leukemia-related aneuploidies monosomy 7 and trisomy 8 previously had been detected in the mature peripheral blood cells of exposed workers, we hypothesized that benzene could cause leukemia through the induction of these aneuploidies in hematopoietic stem and progenitor cells. We measured loss and gain of chromosomes 7 and 8 by fluorescence in situ hybridization in interphase colony-forming unit-granulocyte-macrophage (CFU-GM) cells cultured from otherwise healthy benzene-exposed (n=28) and unexposed (n=14) workers. CFU-GM monosomy 7 and 8 levels (but not trisomy) were significantly increased in subjects exposed to benzene overall, compared with levels in the control subjects (P=0.0055 and P=0.0034, respectively). Levels of monosomy 7 and 8 were significantly increased in subjects exposed to <10 p.p.m. (20%, P=0.0419 and 28%, P=0.0056, respectively) and ≥ 10 p.p.m. (48%, P=0.0045 and 32%, 0.0354) benzene, compared with controls, and significant exposure-response trends were detected (P(trend)=0.0033 and 0.0057). These data show that monosomies 7 and 8 are produced in a dose-dependent manner in the blood progenitor cells of workers exposed to benzene, and may be mechanistically relevant biomarkers of early effect for benzene and other leukemogens
Dielectrophoresis-Driven Spreading of Immersed Liquid Droplets
In recent years electrowetting-on-dielectric (EWOD) has become an effective tool to control partial wetting. EWOD uses the liquid−solid interface as part of a capacitive structure that allows capacitive and interfacial energies to adjust by changes in wetting when the liquid−solid interface is charged due to an applied voltage. An important aspect of EWOD has been its applications in micro fluidics in chemistry and biology and in optical devices and displays in physics and engineering. Many of these rely on the use of a liquid droplet immersed in a second liquid due to the need either for neutral buoyancy to overcome gravity and shield against impact shocks or to encapsulate the droplet for other reasons, such as in microfluidic-based DNA analyses. Recently, it has been shown that nonwetting oleophobic surfaces can be forcibly wetted by nonconducting oils using nonuniform electric fields and an interface-localized form of liquid dielectrophoresis (dielectrowetting). Here we show that this effect can be used to create films of oil immersed in a second immiscible fluid of lower permittivity. We predict that the square of the thickness of the film should obey a simple law dependent on the square of the applied voltage and with strength dependent on the ratio of difference in permittivity to the liquid-fluid interfacial tension, Δε/γLF. This relationship is experimentally confirmed for 11 liquid−air and liquid−liquid combinations with Δε/γLF having a span of more than two orders of magnitude. We therefore provide fundamental understanding of dielectrowetting for liquid-in-liquid systems and also open up a new method to determine liquid−liquid interfacial tensions
Time-dependent perturbation theory for vibrational energy relaxation and dephasing in peptides and proteins
Without invoking the Markov approximation, we derive formulas for vibrational
energy relaxation (VER) and dephasing for an anharmonic system oscillator using
a time-dependent perturbation theory. The system-bath Hamiltonian contains more
than the third order coupling terms since we take a normal mode picture as a
zeroth order approximation. When we invoke the Markov approximation, our theory
reduces to the Maradudin-Fein formula which is used to describe VER properties
of glass and proteins. When the system anharmonicity and the renormalization
effect due to the environment vanishes, our formulas reduce to those derived by
Mikami and Okazaki invoking the path-integral influence functional method [J.
Chem. Phys. 121 (2004) 10052]. We apply our formulas to VER of the amide I mode
of a small amino-acide like molecule, N-methylacetamide, in heavy water.Comment: 16 pages, 5 figures, 5 tables, submitted to J. Chem. Phy
Single-crossover dynamics: finite versus infinite populations
Populations evolving under the joint influence of recombination and
resampling (traditionally known as genetic drift) are investigated. First, we
summarise and adapt a deterministic approach, as valid for infinite
populations, which assumes continuous time and single crossover events. The
corresponding nonlinear system of differential equations permits a closed
solution, both in terms of the type frequencies and via linkage disequilibria
of all orders. To include stochastic effects, we then consider the
corresponding finite-population model, the Moran model with single crossovers,
and examine it both analytically and by means of simulations. Particular
emphasis is on the connection with the deterministic solution. If there is only
recombination and every pair of recombined offspring replaces their pair of
parents (i.e., there is no resampling), then the {\em expected} type
frequencies in the finite population, of arbitrary size, equal the type
frequencies in the infinite population. If resampling is included, the
stochastic process converges, in the infinite-population limit, to the
deterministic dynamics, which turns out to be a good approximation already for
populations of moderate size.Comment: 21 pages, 4 figure
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