113 research outputs found
Highly cross-linked bifunctional magnesium porphyrin-imidazolium bromide polymer: Unveiling the key role of co-catalysts proximity for CO2 conversion into cyclic carbonates
Highly cross-linked materials containing an imidazolium salt and magnesium porphyrin, either in the absence
(TSP-Mg-imi) or in the presence (7a and 7b) of multi-walled carbon nanotubes (MWCNTs), were synthesized
and used as heterogeneous bifunctional catalysts for the conversion of CO2 into cyclic carbonates. The metalloporphyrin
moiety acts both as a âcovalent swelling agentâ, generating hybrids with high surface area, and as a
Lewis acid co-catalytic species. TSP-Mg-imi produced excellent conversion and TONMg values, under solvent-free
conditions, even at room temperature and with low catalytic loading (0.003 mol%). In terms of conversion and
TONMg, TSP-Mg-imi exhibited better catalytic performance compared to a reference homogeneous system,
demonstrating that the proximity between the metal centers and the nucleophilic site results in a synergistic
effect during the catalytic cycle. The results of the computational study confirmed both the cooperative function
and the significance of incorporating a co-catalytic species into the system
White light emitting silsesquioxane based materials: The importance of a ligand with rigid and directional arms
The synthesis of a novel polyhedral oligomeric silsesquioxane functionalized with eight rigid and directional terpyridine-based arms (Ter-POSS) was successfully achieved via a Sonogashira reaction. The POSS based ligand was extensively characterized using different techniques including 1H, 13C and 29Si NMR as well as UV-Vis and fluorescence spectroscopies. The assembly of these nano-caged units in the presence of different transition metal ions (Fe2+, Zn2+ and Cu2+) as well as of a cation from the lanthanides (Eu3+) was investigated using absorption and emission spectroscopies. The final materials display an evident emission in different regions of the visible spectrum as a function of the cation employed. Additional insights into the structural organization of Ter-POSS in the presence of metal cations were obtained via molecular mechanics and molecular dynamics simulations. The polymeric material resulting from the complexation with europium displays a white light emission ascribed to the presence of combined contributions from the blue, green and red regions. The final self-assembled organizations display an increased quantum yield with the highest value (29.6%) obtained in the presence of Zn2+. Moreover, the white-light emitting europium-based nanostructure exhibits one of the highest quantum yields reported in the literature for similar solids
Donor-acceptor stacking arrangements in bulk and thin-film high-mobility conjugated polymers characterized using molecular modelling and MAS and surface-enhanced solid-state NMR spectroscopy
Conjugated polymers show promising properties as cheap, sustainable and solution-processable semiconductors. A key challenge in the development of these materials is to determine the polymer chain structure, conformation and packing in both the bulk polymer and in thin films typically used in devices. However, many characterisation techniques are unable to provide atomic-level structural information owing to the presence of disorder. Here, we use molecular modelling, magic-angle spinning (MAS) and dynamic nuclear polarisation surface-enhanced NMR spectroscopy (DNP SENS) to characterise the polymer backbone group conformations and packing arrangement in the high-mobility donor-acceptor copolymer diketopyrrolo-pyrrole-dithienylthieno[3,2-b] thiophene (DPP-DTT). Using conventional H-1 and C-13 solid-state MAS NMR coupled with density functional theory calculations and molecular dynamics simulations, we find that the bulk polymer adopts a highly planar backbone conformation with a laterally-shifted donor-on-acceptor stacking arrangement. DNP SENS enables acquisition of C-13 NMR data for polymer films, where sensitivity is limiting owing to small sample volumes. The DNP signal enhancement enables a two-dimensional H-1-C-13 HETCOR spectrum to be recorded for a drop-cast polymer film, and a C-13 CPMAS NMR spectrum to be recorded for a spin-coated thin-film with a thickness of only 400 nm. The results show that the same planar backbone structure and intermolecular stacking arrangement is preserved in the films following solution processing and annealing, thereby rationalizing the favourable device properties of DPP-DTT, and providing a protocol for the study of other thin film materials
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Polaron spin dynamics in high-mobility polymeric semiconductors
Polymeric semiconductors exhibit exceptionally long spin lifetimes, and recently observed micrometre spin diffusion lengths in conjugated polymers demonstrate the potential for organic spintronics devices. Weak spinâorbit and hyperfine interactions lie at the origin of their long spin lifetimes, but the coupling mechanism of a spin to its environment remains elusive. Here, we present a systematic study of polaron spin lifetimes in field-effect transistors with high-mobility conjugated polymers as an active layer. We demonstrate how spin relaxation is governed by the chargesâ hopping motion at low temperatures, whereas an ElliottâYafet-like relaxation due to a transient localization of the carrier wavefunctions is responsible for spin relaxation at high temperatures. In this regime, charge, spin and structural dynamics are intimately related and depend sensitively on the local conformation of polymer backbones and the crystalline packing of the polymer chains.* ERC Synergy grant SC2 (no. 610115)
* Alexander von Humboldt Foundation
* Transregional Collaborative Research Center (SFB/TRR) 173 SPIN+X
* Winton Programme for the Physics of Sustainability
* Engineering and Physical Sciences Research Council (EPSRC)
* Excellence Initiative by the Graduate School Materials Science in Mainz (GSC 266)
* European Commission/RĂ©gion Wallonne (FEDERâBIORGEL project), the Consortium des Ăquipements de Calcul Intensif (CĂCI), funded by the Fonds National de la Recherche Scientifique (FRS-FNRS) under grant no. 2.5020.11 * Tier-1 supercomputer of the FĂ©dĂ©ration Wallonie-Bruxelles, infrastructure funded by the Walloon Region under grant agreement n111754
Side chain engineering in indacenodithiophene- co -benzothiadiazole and its impact on mixed ionicâelectronic transport properties
Organic semiconductors are increasingly being decorated with hydrophilic solubilising chains to create materials that can function as mixed ionicâelectronic conductors, which are promising candidates for interfacing biological systems with organic electronics. While numerous organic semiconductors, including p- and n-type materials, small molecules and polymers, have been successfully tailored to encompass mixed conduction properties, common to all these systems is that they have been semicrystalline materials. Here, we explore how side chain engineering in the nano-crystalline indacenodithiophene-co-benzothiadiazole (IDTBT) polymer can be used to instil ionic transport properties and how this in turn influences the electronic transport properties. This allows us to ultimately assess the mixed ionicâelectronic transport properties of these new IDTBT polymers using the organic electrochemical transistor as the testing platform. Using a complementary experimental and computational approach, we find that polar IDTBT derivatives can be infiltrated by water and solvated ions, they can be electrochemically doped efficiently in aqueous electrolyte with fast doping kinetics, and upon aqueous swelling there is no deterioration of the close interchain contacts that are vital for efficient charge transport in the IDTBT system. Despite these promising attributes, mixed ionicâelectronic charge transport properties are surprisingly poor in all the polar IDTBT derivatives. Albeit a âânegativeââ result, this finding clearly contradicts established side chain engineering rules for mixed ionicâelectronic conductors, which motivated our continued investigation of this system. We eventually find this anomalous behaviour to be caused by increasing energetic disorder in the polymers with increasing polar side chain content. We have investigated computationally how the polar side chain motifs contribute to this detrimental energetic inhomogeneity and ultimately use the learnings to propose new molecular design criteria for side chains that can facilitate ion transport without impeding electronic transport
Oxacycle fused [1]benzothieno[3,2-b][1]benzothiophene derivatives: synthesis, electronic structure, electrochemical properties, ionisation potential, and crystal structure
The molecular properties of [1]benzothieno[3,2-b][1]benzothiophene (BTBT) are vulnerable to the structural modifications which in turn are decided by the functionalization of the backbone. Hence versatile synthetic strategies are needed to discover the properties of this molecule. To address this, we have attempted heteroatom (oxygen) functionalization of BTBT by a concise and easily scalable synthesis. Four-fold hydroxy substituted BTBT is the key intermediate, from which the compounds 2,3,7,8- bis(ethylenedioxy)-[1]benzothieno[3,2-b][1]benzothiophene and 2,3,7,8- bis(methylenedioxy)-[1]benzothieno[3,2-b][1]benzothiophene are synthesized. The difference in ether functionalities on the BTBT scaffold influences the ionisation potential values substantially. The crystal structure reveals the transformation of the herringbone motif in bare BTBT towards Ï stacked columns in the newly synthesized derivatives. The results are further elaborated with the aid of quantum chemical calculations
Unraveling unprecedented charge carrier mobility through structure property relationship of four isomers of didodecyl[1]benzothieno[3,2-b][1]benzothiophene
Since the dawn of organic electronics in the 1970âs, academic and industrial research efforts have led to dramatic improvements of the solubility, stability, and electronic properties of organic semiconductors (OSCs).[1, 2] The common benchmark to characterize the electrical performances of OSCs is their charge carrier mobility ÎŒ (cm2 Vâ1 sâ1), defined as the drift velocity of the charge carrier (cm sâ1) per unit of applied electric field (V cmâ1). Reaching high mobilities in OSCs is highly desirable as it allows faster operation of transistors and energy savings by reduced calculation times.[2, 3] However, OSCs performances (conventional values usually range from 1 to 10 cm2 Vâ1 sâ1, with highest values obtained with single-crystal devices mostly exempt of structural defects) are still not comparable to that of state-of-the-art inorganic semiconductors (e.g. metal oxides with ” = 20-50 cm2 Vâ1 sâ1 and polycrystalline silicon with ” > 100 cm2 Vâ1 sâ1) thereby hampering important potential technological applications such as flexible organic light-emitting diode (OLED) displays and wearable electronics.[3, 4
Core charge distribution and self assembly of columnar phases: the case of triphenylenes and azatriphenylenes
<p>Abstract</p> <p>Background</p> <p>The relation betweeen the structure of discotic molecules and columnar properties, a crucial point for the realization of new advanced materials, is still largely unknown. A paradigmatic case is that hexa-alkyl-thio substituted triphenylenes present mesogenic behavior while the corresponding azatriphenylenes, similar in shape and chemical structure, but with a different core charge distribution, do not form any liquid crystalline mesophase. This study is aimed at investigating, with the help of computer simulations techniques, the effects on phase behaviour of changes of the charge distribution in the discotic core.</p> <p>Results</p> <p>We described the shape and the pair, dispersive and electrostatic, interactions of hexa alkyl triphenylenes by uniaxial Gay-Berne discs with embedded point charges. Gay-Berne parameters were deduced by fitting the dispersive energies obtained from an atomistic molecular dynamics simulation of a small sample of hexa-octyl-thio triphenylene molecules in columnar phase, while a genetic algorithm was used to get a minimal set of point charges that properly reproduces the ab anitio electrostatic potential. We performed Monte Carlo simulations of three molecular models: the pure Gay-Berne disc, used as a reference, the Gay-Berne disc with hexa-thio triphenylene point charges, the Gay-Berne disc with hexa-thio azatriphenylene point charges. The phase diagram of the pure model evidences a rich polymorphism, with isotropic, columnar and crystalline phases at low pressure, and the appearance of nematic phase at higher pressure.</p> <p>Conclusion</p> <p>We found that the intermolecular electrostatic potential among the cores is fundamental in sta-bilizing/destabilizing columnar phases; in particular the triphenylene charge distribution stabilizes the columnar structure, while the azatriphenylene distribution suppresses its formation in favor of the nematic phase. We believe the present model could be successfully employed as the basis for coarse-grained level simulations of a wider class of triphenylene derivatives.</p
Dinaphthotetrathienoacenes : synthesis, characterization, and applications in organic field-effect transistors
The charge transport properties of organic semiconductors are limited by dynamic disorder that tends to localize charges in organic crystals. It is the main hurdle to overcome in order to significantly increase charge carrier mobility. We propose an innovative design that combines a chemical structure based on sulfur-rich thienoacene with a solid-state herringbone packing and present the synthesis, physicochemical characterization and charge transport properties of two new thienoacenes bearing a central tetrathienyl core fused with two external naphthyl rings: DN4T and isoDN4T. Both compounds crystallize with a herringbone pattern structure and present transfer integrals ranging from 33 to 99 meV (for the former) within the herringbone plane of charge transport. Molecular dynamics simulations point towards an efficient resilience of the transfer integrals to the intermolecular sliding motion commonly responsible for strong variations of the electronic coupling in the crystal. Best device performances were reached with DN4T with hole mobility up to ÎŒ = 2.1 cmÂČ V-1 s-1 in polycrystalline OFETs, showing the effectiveness of the electronic coupling enabled by the new aromatic core. These promising results pave the way to the design of high-performing materials based on this new thienoacene, notably through the introduction of alkyl side-chains
HighâEfficiency IonâExchange Doping of Conducting Polymers
Abstract: Molecular dopingâthe use of redoxâactive small molecules as dopants for organic semiconductorsâhas seen a surge in research interest driven by emerging applications in sensing, bioelectronics, and thermoelectrics. However, molecular doping carries with it several intrinsic problems stemming directly from the redoxâactive character of these materials. A recent breakthrough was a doping technique based on ionâexchange, which separates the redox and charge compensation steps of the doping process. Here, the equilibrium and kinetics of ion exchange doping in a model system, poly(2,5âbis(3âalkylthiophenâ2âyl)thieno(3,2âb)thiophene) (PBTTT) doped with FeCl3 and an ionic liquid, is studied, reaching conductivities in excess of 1000 S cmâ1 and ion exchange efficiencies above 99%. Several factors that enable such high performance, including the choice of acetonitrile as the doping solvent, which largely eliminates electrolyte association effects and dramatically increases the doping strength of FeCl3, are demonstrated. In this high ion exchange efficiency regime, a simple connection between electrochemical doping and ion exchange is illustrated, and it is shown that the performance and stability of highly doped PBTTT is ultimately limited by intrinsically poor stability at high redox potential
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