Evidence of Freezing Pressure in Sea Ice Discrete Brine Inclusions and Its Impact on Aqueous-Gaseous Equilibrium

Sea ice in part controls surface water properties and the ocean-atmosphere exchange of greenhouse gases at high latitudes. In sea ice, gas exists dissolved in brine and as air bubbles contained in liquid brine inclusions or as bubbles trapped directly within the ice matrix. Current research on gas dynamics within the ocean-sea ice-atmosphere interface has been based on the premise that brine with dissolved air becomes supersaturated with respect to the atmosphere during ice growth. Based on Henry's law, gas bubbles within brine should grow when brine reaches saturation during cooling, given that the total partial pressure of atmospheric gases is above the implicit pressure in brine of 1 atm. Using high-resolution light microscopy time series imagery of gas bubble evolution inside discrete brine pockets, we observed bubbles shrinking during cooling events in response to the development of freezing pressure above 3 atm. During warming of discrete brine pockets, existing bubbles expand and new bubbles nucleate in response to depressurization. Pressure variation within these inclusions has direct impacts on aqueous-gaseous equilibrium, indicating that Henry's law at a constant pressure of 1 atm is inadequate to assess the partitioning between dissolved and gaseous fractions of gas in sea ice. This new evidence of pressure build-up in discrete brine inclusions controlling the solubility of gas and nucleation of bubbles in these inclusions has the potential to affect the transport pathways of air bubbles and dissolved gases within sea ice-ocean-atmosphere interface and modifies brine biochemical properties

Performance, Politics and Media: How the 2010 British General Election leadership debates generated ‘talk’ amongst the electorate.

During the British General Election 2010 a major innovation was introduced in part to improve engagement: a series of three live televised leadership debates took place where the leader of each of the three main parties, Labour, Liberal Democrat and Conservative, answered questions posed by members of the public and subsequently debated issues pertinent to the questions. In this study we consider these potentially ground breaking debates as the kind of event that was likely to generate discussion. We investigate various aspects of the ‘talk’ that emerged as a result of watching the debates. As an exploratory study concerned with situated accounts of the participants experiences we take an interpretive perspective. In this paper we outline the meta-narratives (of talk) associated with the viewing of the leadership debates that were identified, concluding our analysis by suggesting that putting a live debate on television and promoting and positioning it as a major innovation is likely to mean that is how the audience will make sense of it – as a media event

Surfactant-free purification of membrane protein complexes from bacteria: application to the staphylococcal penicillin-binding protein complex PBP2/PBP2a

Surfactant-mediated removal of proteins from biomembranes invariably results in partial or complete loss of function and disassembly of multi-protein complexes. We determined the capacity of styrene-co-maleic acid (SMA) co-polymer to remove components of the cell division machinery from the membrane of drug-resistant staphylococcal cells. SMA-lipid nanoparticles solubilized FtsZ-PBP2-PBP2a complexes from intact cells, demonstrating the close physical proximity of these proteins within the lipid bilayer. Exposure of bacteria to (-)-epicatechin gallate, a polyphenolic agent that abolishes β-lactam resistance in staphylococci, disrupted the association between PBP2 and PBP2a. Thus, SMA purification provides a means to remove native integral membrane protein assemblages with minimal physical disruption and shows promise as a tool for the interrogation of molecular aspects of bacterial membrane protein structure and function

Inorganic carbon dynamics of melt-pond-covered first-year sea ice in the Canadian Arctic

Melt pond formation is a common feature of spring and summer Arctic sea ice, but the role and impact of sea ice melt and pond formation on both the direction and size of CO2 fluxes between air and sea is still unknown. Here we report on the CO2-carbonate chemistry of melting sea ice, melt ponds and the underlying seawater as well as CO2 fluxes at the surface of first-year landfast sea ice in the Resolute Passage, Nunavut, in June 2012. Early in the melt season, the increase in ice temperature and the subsequent decrease in bulk ice salinity promote a strong decrease of the total alkalinity (TA), total dissolved inorganic carbon (T CO2) and partial pressure of CO2 (pCO2) within the bulk sea ice and the brine. As sea ice melt progresses, melt ponds form, mainly from melted snow, leading to a low in situ melt pond pCO2 (36 μatm). The percolation of this low salinity and low pCO2 meltwater into the sea ice matrix decreased the brine salinity, TA and T CO2, and lowered the in situ brine pCO2 (to 20 μatm). This initial low in situ pCO2 observed in brine and melt ponds results in air-ice CO2 fluxes ranging between -0.04 and -5.4 mmolm-2 day-1 (negative sign for fluxes from the atmosphere into the ocean). As melt ponds strive to reach pCO2 equilibrium with the atmosphere, their in situ pCO2 increases (up to 380 μatm) with time and the percolation of this relatively high concentration pCO2 meltwater increases the in situ brine pCO2 within the sea ice matrix as the melt season progresses. As the melt pond pCO2 increases, the uptake of atmospheric CO2 becomes less significant. However, since melt ponds are continuously supplied by meltwater, their in situ pCO2 remains undersaturated with respect to the atmosphere, promoting a continuous but moderate uptake of CO2 (∼-1 mmolm-2 day-1) into the ocean. Considering the Arctic seasonal sea ice extent during the melt period (90 days), we estimate an uptake of atmospheric CO2 of -10.4 Tg of Cyr-1. This represents an additional uptake of CO2 associated with Arctic sea ice that needs to be further explored and considered in the estimation of the Arctic Ocean's overall CO2 budget

A nonlinear scalar model of extreme mass ratio inspirals in effective field theory I. Self force through third order

The motion of a small compact object in a background spacetime is investigated in the context of a model nonlinear scalar field theory. This model is constructed to have a perturbative structure analogous to the General Relativistic description of extreme mass ratio inspirals (EMRIs). We apply the effective field theory approach to this model and calculate the finite part of the self force on the small compact object through third order in the ratio of the size of the compact object to the curvature scale of the background (e.g., black hole) spacetime. We use well-known renormalization methods and demonstrate the consistency of the formalism in rendering the self force finite at higher orders within a point particle prescription for the small compact object. This nonlinear scalar model should be useful for studying various aspects of higher-order self force effects in EMRIs but within a comparatively simpler context than the full gravitational case. These aspects include developing practical schemes for higher order self force numerical computations, quantifying the effects of transient resonances on EMRI waveforms and accurately modeling the small compact object's motion for precise determinations of the parameters of detected EMRI sources.Comment: 30 pages, 8 figure

Finite size corrections to the radiation reaction force in classical electrodynamics

We introduce an effective field theory approach that describes the motion of finite size objects under the influence of electromagnetic fields. We prove that leading order effects due to the finite radius $R$ of a spherically symmetric charge is order $R^2$ rather than order $R$ in any physical model, as widely claimed in the literature. This scaling arises as a consequence of Poincar\'e and gauge symmetries, which can be shown to exclude linear corrections. We use the formalism to calculate the leading order finite size correction to the Abraham-Lorentz-Dirac force.Comment: 4 pages, 2 figure

Properties of the ferrimagnetic double-perovskite A_{2}FeReO_{6} (A=Ba and Ca)

Ceramics of A_{2}FeReO_{6} double-perovskite have been prepared and studied for A=Ba and Ca. Ba_{2}FeReO_{6} has a cubic structure (Fm3m) with $a\approx$8.0854(1) \AA whereas Ca_{2}FeReO_{6} has a distorted monoclinic symmetry with $a\approx 5.396(1) \AA, b\approx 5.522(1) \AA, c\approx 7.688(2) \AA$ and $\beta =90.4^{\circ} (P21/n)$. The barium compound is metallic from 5 K to 385 K, i.e. no metal-insulator transition has been seen up to 385 K, and the calcium compound is semiconducting from 5 K to 385 K. Magnetization measurements show a ferrimagnetic behavior for both materials, with T_{c}=315 K for Ba_{2}FeReO_{6} and above 385 K for Ca_{2}FeReO_{6}. A specific heat measurement on the barium compound gave an electron density of states at the Fermi level, N(E_{F}) equal to 6.1$\times 10^{24} eV^{-1}mole^{-1}$. At 5 K, we observed a negative magnetoresistance of 10 % in a magnetic field of 5 T, but only for Ba_{2}FeReO_{6}. Electrical, thermal and magnetic properties are discussed and compared to the analogous compounds Sr_{2}Fe(Mo,Re)O_{6}.Comment: 5 pages REVTeX, 7 figures included, submitted to PR

Theory of optomechanics: Oscillator-field model of moving mirrors

In this paper we present a model for the kinematics and dynamics of optomechanics which describe the coupling between an optical field, here modeled by a massless scalar field, and the internal (e.g., determining its reflectivity) and mechanical (e.g., displacement) degrees of freedom of a moveable mirror. As opposed to implementing boundary conditions on the field we highlight the internal dynamics of the mirror which provides added flexibility to describe a variety of setups relevant to current experiments. The inclusion of the internal degrees of freedom in this model allows for a variety of optical activities of mirrors from those exhibiting broadband reflective properties to the cases where reflection is suppressed except for a narrow band centered around the characteristic frequency associated with the mirror's internal dynamics. After establishing the model and the reflective properties of the mirror we show how appropriate parameter choices lead to useful optomechanical models such as the well known Barton-Calogeracos model [G. Barton and A. Calogeracos, Ann. Phys. 238, 227 (1995)] and the important yet lesser explored nonlinear models (e.g., $Nx$ coupling) for small photon numbers $N$, which present models based on side-band approximations [H. Kimble et al., Phys. Rev. D 65, 022002 (2001)] cannot cope with. As a simple illustrative application we consider classical radiation pressure cooling with this model. To expound its theoretical structure and physical meanings we connect our model to field-theoretical models using auxiliary fields and the ubiquitous Brownian motion model of quantum open systems. Finally we describe the range of applications of this model, from a full quantum mechanical treatment of radiation pressure cooling, quantum entanglement between macroscopic mirrors, to the backreaction of Hawking radiation on black hole evaporation in a moving mirror analog.Comment: 27 pages, 3 figure