Improved pulse shape discriminator for fast neutron-gamma ray detection system

Discriminator in nuclear particle detection system distinguishes nuclear particle type and energy among many different nuclear particles. Discriminator incorporates passive, linear circuit elements so that it will operate over a wide dynamic range

Reprogramming Pittsburgh's post-industrial riverfront: an open space vision for the south side

As Pittsburgh strives to revive its image as a river city it must contend with its dilapidated urban riverfronts along the Monongahela, Allegheny, and Ohio Rivers. In the late 19th and 20th centuries, the river was considered solely as an economic engine that fueled the growth of America. Once the world’s largest producer of glass and steel, Pittsburgh’s popular South Side district has become disconnected from the river, despite its close proximity. The purpose of this thesis is to generate a new vision plan for the South Side by reprogramming the neglected margin with the intention of providing public access and activating the life-less boundary between the community and the riverfront. In response to the inadequacies of some recent projects completed within the city, this project suggests a new model for the South Side that aims to integrate the riverfront with the urban fabric. The process focuses on the neglected riverfront by extending programs from the surrounding context to pollinate the marginal spaces. An exploratory method is developed to create an open space framework that is capable of supporting the diverse social and cultural demands of Pittsburgh’s South Side. It demonstrates that strategic urban design can effectively create new viable connections with the river by creating spaces that are flexible enough to facilitate the changing demands on the urban riverfront

Nicholas Reactions of Alkynyl- and Alkenyltrifluoroborates

The Lewis acid mediated Nicholas reaction of potassium alkynyltrifluoroborates and propargyl acetate- hexacarbonyldicobalt complexes affords 1,4-diyne dicobalt hexacarbonyl complexes in good yields. The analogous Nicholas reactions of potassium alkenyltrifluoroborates give 1,3-enyne dicobalt hexacarbonyl complexes in most cases, although the initial site of reaction can vary. Potassium vinyltrifluoroborate itself affords alkynylcyclopropane complexes

Preliminary geophysical interpretation of the McKeand River area, southern Baffin Island, Nunavut: insights from gravity, magnetic and geological data

The recently completed McKeand River and Amittok Lake aeromagnetic surveys on southern Baffin Island, Nunavut pro- vide a new high-resolution magnetic dataset over an area with no previous coverage. Complemented by regional gravity data, newly acquired rock-property information and geological-mapping products, the aeromagnetic dataset yields qualita- tive and quantitative information on the structure and geology of the underlying bedrock. This paper presents a preliminary interpretation of these datasets that delineates three gravimetric and five magnetic domains. The gravity data outline a broad negative anomaly associated with a plutonic-intrusive suite, as well as several isolated gravity highs associated with metasedimentary strata. Magnetic domains are defined on the basis of anomaly amplitude, wavelength and texture, and are correlated to the mapped geology and magnetic properties. Associations between potential-field anomalies, physical prop- erties and mineral occurrences help define the regional distribution of economically significant horizons

Basement-cover relations and internal structure of the Cape Smith klippe: A 1.9 Ga greenstone belt in northern Quebec, Canada

The Cape Smith Belt is a 380x60 km tectonic klippe composed of greenschistto amphibolite-grade mafic and komatiitic lava flows and fine-grained quartzose sediment, intruded by minor syn- to post-tectonic granitoids. Previously studied transects in areas of relatively high structural level show that the belt is constructed of seven or more north-dipping thrust sheets which verge toward the Superior Province (Archean) foreland in the south and away from an Archean basement massif (Kovik Antiform) external to the Trans-Hudson Orogen (Early Proterozoic) in the north. A field project (mapping and structural-stratigraphic-metamorphic studies) directed by MRS was begun in 1985 aimed at the structurally deeper levels of the belt and underlying basement, which are superby exposed in oblique cross-section (12 km minimum structural relief) at the west-plunging eastern end of the belt. Mapping now complete of the eastern end of the belt confirms that all of the metavolcanic and most of the metasedimentary rocks are allochthonous with respect to the Archean basement, and that the thrusts must have been rooted north of Kovik Antiform. The main findings follow

The roles of transportation and transportation hubs in the propagation of influenza and coronaviruses: a systematic review

BACKGROUND: Respiratory viruses spread in humans across wide geographical areas in short periods of time, resulting in high levels of morbidity and mortality. We undertook a systematic review to assess the evidence that air, ground and sea mass transportation systems or hubs are associated with propagating influenza and coronaviruses. METHODS: Healthcare databases and sources of grey literature were searched using pre-defined criteria between April and June 2014. Two reviewers screened all identified records against the protocol, undertook risk of bias assessments and extracted data using a piloted form. Results were analysed using a narrative synthesis. RESULTS: Forty-one studies met the eligibility criteria. Risk of bias was high in the observational studies, moderate to high in the reviews and moderate to low in the modelling studies. In-flight influenza transmission was identified substantively on five flights with up to four confirmed and six suspected secondary cases per affected flight. Five studies highlighted the role of air travel in accelerating influenza spread to new areas. Influenza outbreaks aboard cruise ships affect 2-7% of passengers. Influenza transmission events have been observed aboard ground transport vehicles. High heterogeneity between studies and the inability to exclude other sources of infection means that the risk of influenza transmission from an index case to other passengers cannot be accurately quantified. A paucity of evidence was identified describing severe acute respiratory syndrome coronavirus and Middle East respiratory syndrome coronavirus transmission events associated with transportation systems or hubs. CONCLUSION: Air transportation appears important in accelerating and amplifying influenza propagation. Transmission occurs aboard aeroplanes, at the destination and possibly at airports. Control measures to prevent influenza transmission on cruise ships are needed to reduce morbidity and mortality. There is no recent evidence of sea transport accelerating influenza or coronavirus spread to new areas. Further investigation is required regarding the roles of ground transportation systems and transport hubs in pandemic situations

Record of modern-style plate tectonics in the Palaeoproterozoic Trans-Hudson orogen

The Trans-Hudson orogen of North America is a circa 1,800 million year old, middle Palaeoproterozoic continental collisional belt. The orogen may represent an ancient analogue to the Himalayan orogen, which began forming 50 million years ago and remains active today. Both mountain belts exhibit similar length scales of deformation and timescales of magmatism and metamorphism. A notable divergence in this correlation has been the absence of high-pressure, low-temperature metamorphic rocks in the Trans-Hudson compared with the Himalaya. It has been debated whether this absence reflects a secular tectonic change, with the requisite cool thermal gradients precluded by warmer ambient mantle temperatures during the Palaeoproterozoic, or a lack of preservation. Here we identify eclogite rocks within the Trans-Hudson orogen. These rocks, which typically form at high pressures and cool temperatures during subduction, fill the gap in the comparative geologic record between the Trans-Hudson and Himalayan orogens. Through the application of phase equilibria modelling and in situ U–Pb monazite dating we show that the pressure–temperature conditions and relative timing of eclogite-facies metamorphism are comparable in both orogenies. The results imply that modern-day plate tectonic processes featuring deep continental subduction occurred at least 1,830 million years ago. This study highlights that the global metamorphic rock record (particularly in older terrains) is skewed by overprinting and erosion

Electronic band gap reduction and intense luminescence in Co and Mn ion-implanted SiO2_2

Cobalt and manganese ions are implanted into SiO$_2$ over a wide range of concentrations. For low concentrations, the Co atoms occupy interstitial locations, coordinated with oxygen, while metallic Co clusters form at higher implantation concentrations. For all concentrations studied here, Mn ions remain in interstitial locations and do not cluster. Using resonant x-ray emission spectroscopy and Anderson impurity model calculations, we determine the strength of the covalent interaction between the interstitial ions and the SiO$_2$ valence band, finding it comparable to Mn and Co monoxides. Further, we find an increasing reduction in the SiO$_2$ electronic band gap for increasing implantation concentration, due primarily to the introduction of Mn- and Co-derived conduction band states. We also observe a strong increase in a band of x-ray stimulated luminescence at 2.75 eV after implantation, attributed to oxygen deficient centers formed during implantation.Comment: 8 pages, 6 figure

Reaction of Alkynyl- And Alkenyltrifluoroborates with Propargyldicobalt Cations: Alkynylation, Alkenylation, and Cyclopropanation Product Pathways

The Lewis acid-mediated Nicholas reactions of propargyl acetate–Co2(CO)6 complexes with a series of potassium alkynyltrifluoroborates and potassium alkenyltrifluoroborates are described. Alkynyltrifluoroborates directly alkynylate the intermediate propargyldicobalt cations. In contrast, alkenyltrifluoroborates proceed through one of the three modes of dominant reactivity: C-2-substituted alkenyltrifluorobrates directly alkenylate, predominantly with the retention of stereochemistry. C-1-substituted alkenyltrifluoroborates alkenylate at C-2. Potassium vinyltrifluoroborate incorporates a cyclopropane at the site propargyl to alkynedicobalt. Computational analysis of these systems explains the differential modes of reactivity of alkenyltrifluoroborates and outlines the probable mechanisms for the formation of each product

Completing the bedrock mapping of southern Baffin Island, Nunavut; plutonic suites and regional stratigraphy

This paper summarizes the field observations and initial interpretations following eight weeks of regional and targeted bed- rock mapping on south-central Baffin Island, Nunavut. The 2015 field campaign completes a two-decade mission to update the geoscience knowledge for the whole of Baffin Island south of latitude 70°N. The bedrock in the area is dominated by a Paleoproterozoic metaplutonic suite, ranging in composition from gabbro to syenogranite, with crosscutting relations indi- cating a progression from mafic to silicic magmatism. Phase-equilibria modelling reveals that the prevailing upper-amphi- bolite– to lower-granulite–facies metamorphic conditions overlap the stability limits of magnetite and orthopyroxene for a typical granitoid bulk composition, which is consistent with field observations of the discontinuous presence of both phases throughout the map area. This result is also consistent with regional aeromagnetic data that show complex structures within relatively homogeneous map units, which are primarily attributed to variations in the abundance of magnetite. The granitoid rocks are interpreted as part of the middle Paleoproterozoic Cumberland Batholith. Metasedimentary rocks, including quartzite, pelite, marble and metagreywacke, are present as enclaves and screens within and between plutonic bodies. An examination of the ‘ghost’stratigraphy suggests that the metasedimentary rocks through- out most of the map area can be correlated with the middle Paleoproterozoic Lake Harbour Group, except in the northeast, where the unique presence of greywacke suggests a middle Paleoproterozoic Piling Group affinity. This transition in strata is consistent with the proposal that a middle Paleoproterozoic tectonic suture (the Baffin suture) associated with the Trans- Hudson Orogen runs through Cumberland Sound. Completion of the bedrock mapping in southern Baffin Island indicates that the region offers a world-class exposure of a reworked Paleoproterozoic convergent margin, which affords valuable in- sight into a variety of magmatic and tectonic processes that can be applied to younger collisional belt