Особливості змісту права громадян на екологічну безпеку

В статье сделан анализ содержания права граждан на экологическую безопасность, определяется момент, с которого право на экологическую безопасность считается нарушенным

Particle detection experiment for Applications Technology Satellite 1 /ATS-1/ Final report

Applications technology satellite particle detection experiment for measuring energy spectra of earth magnetic fiel

Supertransferred hyperfine interactions in layer LaSrGa0.995Cu0.005O4

The EPR allowing a direct observation of supertransferred hyperfine fields on the nuclei of the next-nearest cations to copper ion in the structure of LaSrGa0.995Cu0.005O4 isomorphous to the superconducting cuprates prove the far delocalisation of the spin density. The theoretical analysis of the value and mechanisms of this process by the method of configurational interaction leads to a good agreement with the experiment. It is shown that the cascade processes involving simultaneous electron transfers from the oxygen to the copper atom and from the neighbouring cation to the same oxygen, in the fragment considered bring a substantial contribution into polarisation of 3s-shell of gallium ion. A comparison of the supertransferred hyperfine fields and g-tensor values in the studied, diluted LaSrGa0.995Cu0.005O4 crystal and in the La2CuO4 cuprate confirms the validity of the local centre approach in the analysis of cuprate properties. © 2002 Elsevier Science B.V. All rights reserved

Photochemical properties of the cyclopentadienyliron complex of phenothiazine

Publisher's version/PDFPhotolysis of [([eta superscript 6]-phenothiazine)([eta superscript 5]-cyclopentadienyl)]iron(II) hexafluorophosphate (1) has been examined in various solvents such as MeOH, DMSO, THF, MeCN, furan, CH[subscript 2]Cl[subscript 2], CF[subscript 3]CH[subscript 2]OH and (CF[subscript 3])[subscript 2]CHOH. Photoreactions are induced by excitation at [lambda] = 254, 313, 337, 366, 514.5 and 647.5 nm. The major reaction leads to the photorelease of phenothiazine (2) which does not react further under the reaction conditions. Quantum yields of photolysis of 1, [phi](1), and photorelease of 2, [phi]([subscript 2]), are independent of concentration in the range of 1 × 10[superscript –4]–1 × 10[superscript–2] mol dm[superscript–3], wavelength of excitation and light intensity and in MeOH, MeCN, furan and THF, [phi]([subscript 1]) = [phi]([subscript 2]) = ca. 1. The quantum yields are lower in solvents of lower nucleophilicity and in CH[subscript 2]Cl[subscript 2], CF[subscript 3]CH[subscript 2]OH and (CF[subscript 3])[subscript 2]CHOH the [phi]([subscript 1]) values are 0.45, 0.26 and 0.03, respectively. In some solvents ferrocene formation is also observed. Applying oxygen as a quencher it is found that photochemical decay of 1 takes place from the excited state [superscript 3]E[subscript 1], with a lifetime of [tau][subscript 3][Epsilon][subscript 1] < 10[superscript –8]s and leads to formation of 2

Examination of the production of an isotensor dibaryon in the pp → ppπ+π− reaction

Exclusive measurements of the quasi-free $pp o pppi^+pi^-$ reaction have been performed by means of $pd$ collisions at $T_p$ = 1.2 GeV using the WASA detector setup at COSY. Total and differential cross sections have been obtained covering the energy region $T_p = 1.08 - 1.36$ GeV ($sqrt s$ = 2.35 - 2.46 GeV), which includes the regions of $N^*(1440)$ and $Delta(1232)Delta(1232)$ resonance excitations. Calculations describing these excitations by $t$-channel meson exchange are at variance with experimental differential cross sections and underpredict substantially the measured total cross section. An isotensor $Delta N$ dibaryon resonance with $I(J^P) = 2(1^+)$ produced associatedly with a pion is able to overcome these deficiencies. Such a dibaryon was predicted by Dyson and Xuong and more recently calculated by Gal and Garcilazo

Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents

UiO-66, MOF-808 and NU-1000 metal-organic frameworks exhibit a differentiated reactivity toward [Mg(OMe)2(MeOH)2]4 related to their pore accessibility. Microporous UiO-66 remains unchanged while mesoporous MOF-808 and hierarchical micro/mesoporous NU-1000 materials yield doped systems containing exposed MgZr5O2(OH)6 clusters in the mesoporous cavities. This modification is responsible for a remarkable enhancement of the catalytic activity toward the hydrolytic degradation of P-F and P-S bonds of toxic nerve agents, at room temperature, in unbuffered aqueous solutions

Measurement of the ω→π+π−π0 Dalitz plot distribution

Using the production reactions and , the Dalitz plot distribution for the decay is studied with the WASA detector at COSY, based on a combined data sample of events. The Dalitz plot density is parametrised by a product of the P-wave phase space and a polynomial expansion in the normalised polar Dalitz plot variables Z and ϕ. For the first time, a deviation from pure P-wave phase space is observed with a significance of 4.1σ. The deviation is parametrised by a linear term , with α determined to be, consistent with the expectations of ρ-meson-type final-state interactions of the P-wave pion pairs

Combinatorial nuclear level density by a Monte Carlo method

We present a new combinatorial method for the calculation of the nuclear level density. It is based on a Monte Carlo technique, in order to avoid a direct counting procedure which is generally impracticable for high-A nuclei. The Monte Carlo simulation, making use of the Metropolis sampling scheme, allows a computationally fast estimate of the level density for many fermion systems in large shell model spaces. We emphasize the advantages of this Monte Carlo approach, particularly concerning the prediction of the spin and parity distributions of the excited states, and compare our results with those derived from a traditional combinatorial or a statistical method. Such a Monte Carlo technique seems very promising to determine accurate level densities in a large energy range for nuclear reaction calculations.Comment: 30 pages, LaTex, 7 figures (6 Postscript figures included). Fig. 6 upon request to the autho

Phase Measurement for Driven Spin Oscillations in a Storage Ring

This paper reports the first simultaneous measurement of the horizontal and vertical components of the polarization vector in a storage ring under the influence of a radio frequency (rf) solenoid. The experiments were performed at the Cooler Synchrotron COSY in J\"ulich using a vector polarized, bunched $0.97\,\textrm{GeV/c}$ deuteron beam. Using the new spin feedback system, we set the initial phase difference between the solenoid field and the precession of the polarization vector to a predefined value. The feedback system was then switched off, allowing the phase difference to change over time, and the solenoid was switched on to rotate the polarization vector. We observed an oscillation of the vertical polarization component and the phase difference. The oscillations can be described using an analytical model. The results of this experiment also apply to other rf devices with horizontal magnetic fields, such as Wien filters. The precise manipulation of particle spins in storage rings is a prerequisite for measuring the electric dipole moment (EDM) of charged particles