Quantifying the relative contributions of substorm injections and chorus waves to the rapid outward extension of electron radiation belt

Abstract We study the rapid outward extension of the electron radiation belt on a timescale of several hours during three events observed by Radiation Belt Storm Probes and Time History of Events and Macroscale Interactions during Substorms satellites and particularly quantify the contributions of substorm injections and chorus waves to the electron flux enhancement near the outer boundary of radiation belt. A comprehensive analysis including both observations and simulations is performed for the first event on 26 May 2013. The outer boundary of electron radiation belt moved from L = 5.5 to L \u3e 6.07 over about 6 h, with up to 4 orders of magnitude enhancement in the 30 keV to 5 MeV electron fluxes at L = 6. The observations show that the substorm injection can cause 100% and 20% of the total subrelativistic (∼0.1 MeV) and relativistic (2-5 MeV) electron flux enhancements within a few minutes. The data-driven simulation supports that the strong chorus waves can yield 60%-80% of the total energetic (0.2-5.0 MeV) electron flux enhancement within about 6 h. Some simple analyses are further given for the other two events on 2 and 29 June 2013, in which the contributions of substorm injections and chorus waves are shown to be qualitatively comparable to those for the first event. These results clearly illustrate the respective importance of substorm injections and chorus waves for the evolution of radiation belt electrons at different energies on a relatively short timescale. Key Points Rapid outward extension of electron radiation belt observed by RBSP and THEMIS A two-step scenario to explain the rapid flux enchantment Differentiating between contributions of substorm injections and chorus waves

Regional Differences in South American Monsoon Precipitation Inferred from the Growth and Isotopic Composition of Tropical Trees

The authors present results on the relationship between tree-ring proxies and regional precipitation for several sites in tropical South America. The responsiveness of oxygen isotopes (δ18O) and seasonal growth as precipitation proxies was first validated by high-resolution sampling of a Tachigali myrmecophila from Manaus, Brazil (3.1°S, 60.0°W). Monthly growth of Tachigali spp. was significantly correlated with monthly precipitation. Intra-annual measurements of cellulose δ18O in Tachigali spp. were also significantly correlated with monthly precipitation at a lag of approximately one month. The annual ring widths of two tropical tree taxa, Cedrela odorata growing in the Amazon (12.6°S, 69.2°W) and Polylepis tarapacana growing in the Altiplano (22.0°S, 66.0°W), were validated using bomb-derived radiocarbon 14C. Estimated dates were within two to three years of bomb-inferred 14C dates, indicating that these species exhibit annual rings but uncertainties in our chronologies remain. A multiproxy record spanning 180 years from Cedrela spp. showed a significant negative relationship between cellulose δ18O and January precipitation. A 150-yr record obtained from Polylepis spp. also showed a significant negative relationship between δ18O and March precipitation, whereas annual ring width showed a significant positive correlation with December precipitation. These proxies were combined in a multivariate framework to reconstruct past precipitation, revealing a significant increase in monsoon precipitation at the Amazon site since 1890 and a significant decrease in monsoon precipitation at the Altiplano since 1880. Proxy time series also showed spatial and temporal coherence with precipitation variability due to El Niño forcing, suggesting that oxygen isotopes and ring widths in tropical trees may be important diagnostics for identifying regional differences in the response of the tropical hydrologic cycle to anthropogenic warming

A Doubly Nudged Elastic Band Method for Finding Transition States

A modification of the nudged elastic band (NEB) method is presented that enables stable optimisations to be run using both the limited-memory quasi-Newton (L-BFGS) and slow-response quenched velocity Verlet (SQVV) minimisers. The performance of this new `doubly nudged' DNEB method is analysed in conjunction with both minimisers and compared with previous NEB formulations. We find that the fastest DNEB approach (DNEB/L-BFGS) can be quicker by up to two orders of magnitude. Applications to permutational rearrangements of the seven-atom Lennard-Jones cluster (LJ7) and highly cooperative rearrangements of LJ38 and LJ75 are presented. We also outline an updated algorithm for constructing complicated multi-step pathways using successive DNEB runs.Comment: 13 pages, 8 figures, 2 table

Identification of optimal epitopes for Plasmodium falciparum rapid diagnostic tests that target histidine-rich proteins 2 and 3

Rapid diagnostic tests (RDTs) represent important tools to diagnose malaria infection. To improve understanding of the variable performance of RDTs that detect the major target in Plasmodium falciparum, namely, histidine-rich protein 2 (HRP2), and to inform the design of better tests, we undertook detailed mapping of the epitopes recognized by eight HRP-specific monoclonal antibodies (MAbs). To investigate the geographic skewing of this polymorphic protein, we analyzed the distribution of these epitopes in parasites from geographically diverse areas. To identify an ideal amino acid motif for a MAb to target in HRP2 and in the related protein HRP3, we used a purpose-designed script to perform bioinformatic analysis of 448 distinct gene sequences from pfhrp2 and from 99 sequences from the closely related gene pfhrp3. The frequency and distribution of these motifs were also compared to the MAb epitopes. Heat stability testing of MAbs immobilized on nitrocellulose membranes was also performed. Results of these experiments enabled the identification of MAbs with the most desirable characteristics for inclusion in RDTs, including copy number and coverage of target epitopes, geographic skewing, heat stability, and match with the most abundant amino acid motifs identified. This study therefore informs the selection of MAbs to include in malaria RDTs as well as in the generation of improved MAbs that should improve the performance of HRP-detecting malaria RDTs. Copyright © 2012, American Society for Microbiology

Modeling inward diffusion and slow decay of energetic electrons in the Earth\u27s outer radiation belt

Abstract A new 3-D diffusion code is used to investigate the inward intrusion and slow decay of energetic radiation belt electrons (\u3e0.5 MeV) observed by the Van Allen Probes during a 10 day quiet period on March 2013. During the inward transport, the peak differential electron fluxes decreased by approximately an order of magnitude at various energies. Our 3-D radiation belt simulation including radial diffusion and pitch angle and energy diffusion by plasmaspheric hiss and electromagnetic ion cyclotron (EMIC) waves reproduces the essential features of the observed electron flux evolution. The decay time scales and the pitch angle distributions in our simulation are consistent with the Van Allen Probe observations over multiple energy channels. Our study suggests that the quiet time energetic electron dynamics are effectively controlled by inward radial diffusion and pitch angle scattering due to a combination of plasmaspheric hiss and EMIC waves in the Earth\u27s radiation belts

Fine-time energetic electron behavior observed by Cluster/RAPID in the magnetotail associated with X-line formation and subsequent current disruption

Energetic electrons with 90deg pitch angle have been observed in the magnetotail at ~19 <i>R<sub>E</sub></i> near local midnight during the recovery phase of a substorm event on 27 August 2001 (Baker et al., 2002). Based on auroral images Baker et al. (2002) placed the substorm expansion phase between ~04:06:16 and ~04:08:19 UT. The electron enhancements perpendicular to the ambient magnetic field occurred while the Cluster spacecraft were on closed field lines in the central plasma sheet approaching the neutral sheet. Magnetic field and energetic particle measurements have been employed from a number of satellites, in order to determine the source and the subsequent appearance of these electrons at the Cluster location. It is found that ~7.5 min after an X-line formation observed by Cluster (Baker et al., 2002) a current disruption event took place inside geosynchronous orbit and subsequently expanded both in local time and tailward, giving rise to field-aligned currents and the formation of a current wedge. A synthesis of tail reconnection and the cross-tail current disruption scenario is proposed for the substorm global initiation process: When a fast flow with northward magnetic field, produced by magnetic reconnection in the midtail, abruptly decelerates at the inner edge of the plasma sheet, it compresses the plasma populations earthward of the front, altering dynamically the B<sub>z</sub> magnetic component in the current sheet. This provides the necessary and sufficient conditions for the kinetic cross-field streaming/current (KCSI/CFCI) instability (Lui et al., 1990, 1991) to initiate. As soon as the ionospheric conductance increases over a threshold level, the auroral electrojet is greatly intensified (see Fig. 2 in Baker et al., 2002), which leads to the formation of the substorm current wedge and dipolarization of the magnetic field. This substorm scenario combines the near-Earth neutral line and the current disruption for the initiation of substorms, at least during steady southward IMF. One can conclude the following: The observations suggest that the anisotropic electron increases observed by Cluster are not related to an acceleration mechanism associated with the X-line formation in the midtail, but rather these particles are generated in the dusk magnetospheric sector due to the longitudinal and tailward expansion of a current disruption region and subsequently observed at the Cluster location with no apparent energy dispersion.<br><br> <b>Keywords.</b> Magnetospheric physics (Magnetotail; Plasma convection; Storms and substorms

Radiation belt electron acceleration by chorus waves during the 17 March 2013 storm

Abstract Local acceleration driven by whistler-mode chorus waves is fundamentally important for accelerating seed electron populations to highly relativistic energies in the outer radiation belt. In this study, we quantitatively evaluate chorus-driven electron acceleration during the 17 March 2013 storm, when the Van Allen Probes observed very rapid electron acceleration up to several MeV within ~12 hours. A clear radial peak in electron phase space density (PSD) observed near L* ~4 indicates that an internal local acceleration process was operating. We construct the global distribution of chorus wave intensity from the low-altitude electron measurements made by multiple Polar Orbiting Environmental Satellites (POES) satellites over a broad region, which is ultimately used to simulate the radiation belt electron dynamics driven by chorus waves. Our simulation results show remarkable agreement in magnitude, timing, energy dependence, and pitch angle distribution with the observed electron PSD near its peak location. However, radial diffusion and other loss processes may be required to explain the differences between the observation and simulation at other locations away from the PSD peak. Our simulation results, together with previous studies, suggest that local acceleration by chorus waves is a robust and ubiquitous process and plays a critical role in accelerating injected seed electrons with convective energies (~100 keV) to highly relativistic energies (several MeV)

Silver(I) and mercury(II) complexes of meta- and para-xylyl linked bis(imidazol-2-ylidenes)

Mononuclear silver and mercury complexes bearing bis-N-heterocyclic carbene (NHC) ligands withlinear coordination modes have been prepared and structurally characterised. The complexes form metallocyclic structures that display rigid solution behaviour. A larger metallocycle of the form [L2Ag2]2+ [where L = parabis(N-methylimidazolylidene)xylylene] has been isolated from the reaction of para-xylylene-bis(N-methylimidazolium) chloride and Ag2O. Reaction of silver- and mercury-NHC complexes with Pd(NCCH3)2Cl2 affords palladium-NHC complexes via NHC-transfer reactions, the mercury case being only the second example of a NHC-transfer reaction using a mercury-NHC complex