Point defects on graphene on metals

Understanding the coupling of graphene with its local environment is critical to be able to integrate it in tomorrow's electronic devices. Here we show how the presence of a metallic substrate affects the properties of an atomically tailored graphene layer. We have deliberately introduced single carbon vacancies on a graphene monolayer grown on a Pt(111) surface and investigated its impact in the electronic, structural and magnetic properties of the graphene layer. Our low temperature scanning tunneling microscopy studies, complemented by density functional theory, show the existence of a broad electronic resonance above the Fermi energy associated with the vacancies. Vacancy sites become reactive leading to an increase of the coupling between the graphene layer and the metal substrate at these points; this gives rise to a rapid decay of the localized state and the quenching of the magnetic moment associated with carbon vacancies in free-standing graphene layers

Determining the physical conditions of extremely young Class 0 circumbinary disk around VLA1623A

We present detailed analysis of high-resolution C18O (2-1), SO (88-77), CO (3-2) and DCO+ (3-2) data obtained by the Atacama Large Millimeter/sub-millimeter Array (ALMA) towards a Class 0 Keplerian circumbinary disk around VLA1623A, which represents one of the most complete analysis towards a Class 0 source. From the dendrogram analysis, we identified several accretion flows feeding the circumbinary disk in a highly anisotropic manner. Stream-like SO emission around the circumbinary disk reveals the complicated shocks caused by the interactions between the disk, accretion flows and outflows. A wall-like structure is discovered south of VLA1623B. The discovery of two outflow cavity walls at the same position traveling at different velocities suggests the two outflows from both VLA1623A and VLA1623B overlays on top of each other in the plane of sky. Our detailed flat and flared disk modeling shows that Cycle 2 C18O J = 2-1 data is inconsistent with the combined binary mass of 0.2 Msun as suggested by early Cycle 0 studies. The combined binary mass for VLA1623A should be modified to 0.3 ~ 0.5 Msun.Comment: 26 pages, 20 figures, accepted by ApJ 2020.2.2

Metallic properties of magnesium point contacts

We present an experimental and theoretical study of the conductance and stability of Mg atomic-sized contacts. Using Mechanically Controllable Break Junctions (MCBJ), we have observed that the room temperature conductance histograms exhibit a series of peaks, which suggests the existence of a shell effect. Its periodicity, however, cannot be simply explained in terms of either an atomic or electronic shell effect. We have also found that at room temperature, contacts of the diameter of a single atom are absent. A possible interpretation could be the occurrence of a metal-to-insulator transition as the contact radius is reduced, in analogy with what it is known in the context of Mg clusters. However, our first principle calculations show that while an infinite linear chain can be insulating, Mg wires with larger atomic coordinations, as in realistic atomic contacts, are alwaysmetallic. Finally, at liquid helium temperature our measurements show that the conductance histogram is dominated by a pronounced peak at the quantum of conductance. This is in good agreement with our calculations based on a tight-binding model that indicate that the conductance of a Mg one-atom contact is dominated by a single fully open conduction channel.Comment: 14 pages, 5 figure

La ictiofauna

La composició específica de la fauna ictiològica de l'Arxipèlag de Cabrera no presenta diferències significatives respecte a la de la resta de les Balears. Aquest treball es composa d'una llista exhaustiva dels peixos coneguts fins al moment a Cabrera, amb 218 espècies litorals o de plataforma, i d'un capítol de comentaris a les espècies més interessants, destacant la confirmació de la presència de Serranus atricauda a Balears i primera referencia a Mallorca, la primera cita de Gobius vittatus a aigües ibèriques, la primera cita a Balears de Pomadasys incisus i la primera referència a Mallorca de Diplodus cervinus. A l'annex s'inclou una llista dels peixos ordenats pel tipus d'hàbitat.The specific composition of the icthyologic fauna of Cabrera Archipelago does not appear to be significantly different from that of the rest of the Balearic Islands. The present study gives an exhaustive list of the fishes know to live in Cabrera, with 128 coastal or platform species and includes a section commenting on the most interesting ones. The presence of Serranus atricauda in the Balearic Islands and its first citation in Mallorca is confirmed. Gobius vittatus is first cited for Iberian waters. Pomadasys incisus is first cited for Mallorca. A list of fishes ranked by that type is also given

Voltage balancing scheme for the multilevel flying capacitor converter using phase-shifted PWM

In flying capacitor (FC) converters, phase-shifted pulse-width modulation (PS-PWM) provides natural voltage balancing. However, for a practical application, a more robust balancing mechanism of maintaining the FC voltages at the desired values is required. This paper proposes a new closed-loop voltage balancing method for multilevel FC converters using PS-PWM. The proposed method balances the voltages of the FCs by modifying the duty cycle of each switch of the FC converter using a proportional (P) controller. The crossed effect between FC currents and duty cycles is considered and is used for FC voltage balancing. The Simulation results verify that the proposed voltage balancing method is very robust to different operating conditions, such as load transients and non-linear loads.Postprint (author’s final draft

Voltage balancing strategy for a five-level flying capacitor converter using phase disposition PWM with sawtooth-shaped arriers

The flying capacitor (FC) multilevel converter has attracted a great deal of interest in the recent years because of its easier extension to a higher number of levels (n>;3), as compared to its counterpart, the diode-clamped converter (DCC). The main focus of this paper is to develop a voltage balancing scheme of FCs for a five-level FC converter based on phase disposition pulse-width modulation (PD-PWM). Since there are multiple states that produce the same output voltage at the leg of the converter, such a redundancy is used to regulate the FC voltages at their desired levels. The selection of the optimal states is performed by minimizing a cost function. A drawback observed when using standard symmetrical triangular carriers for the PD-PWM, is the additional switching events that are produced due to transitions within the same voltage level. Nevertheless, this fact can be avoided by using sawtooth carrier waveforms instead. Simulation results verify the robustness of the proposed voltage balancing scheme against static and dynamic load conditions. Moreover, using sawtooth carriers a significant reduction of the switching frequency is achieved as compared to the use of standard triangle carriers while maintaining the FC voltage balanced.Peer ReviewedPostprint (author’s final draft

Fabrication and deposition of copper and copper oxide nanoparticles by laser ablation in open air

The proximity of the “post-antibiotic era”, where infections and minor injuries could be a cause of death, there are urges to seek an alternative for the cure of infectious diseases. Copper nanoparticles and their huge potential as a bactericidal agent could be a solution. In this work, Cu and Cu oxide nanoparticles were synthesized by laser ablation in open air and in argon atmosphere using 532 and 1064 nm radiation generated by nanosecond and picosecond Nd:YVO4 lasers, respectively, to be directly deposited onto Ti substrates. Size, morphology, composition and the crystalline structure of the produced nanoparticles have been studied by the means of field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), the energy dispersive spectroscopy of X-rays (EDS), selected area electron diffraction (SAED) and X-ray diffraction (XRD). The UV-VIS absorbance of the thin layer of nanoparticles was also measured, and the antibacterial capacity of the obtained deposits tested against Staphylococcus aureus. The obtained deposits consisted of porous coatings composed of copper and copper oxide nanoparticles interconnected to form chain-like aggregates. The use of the argon atmosphere contributed to reduce significantly the formation of Cu oxide species. The synthesized and deposited nanoparticles exhibited an inhibitory effect upon S. aureus.Peer ReviewedPostprint (published version