Parent population of flat-spectrum radio-loud narrow-line Seyfert 1 galaxies

Flat-spectrum radio-loud Narrow-Line Seyfert 1 galaxies (NLS1s) are a recently discovered class of $\gamma$-ray emitting Active Galactic Nuclei (AGN), that exhibit some blazar-like properties which are explained with the presence of a relativistic jet viewed at small angles. When blazars are observed at larger angles they appear as radio-galaxies, and we expect to observe an analogue parent population for beamed NLS1s. However, the number of known NLS1s with the jet viewed at large angles is not enough. Therefore, we tried to understand the origin of this deficit. Current hypotheses about the nature of parent sources are steep-spectrum radio-loud NLS1s, radio-quiet NLS1s and disk-hosted radio-galaxies. To test these hypotheses we built three samples of candidate sources plus a control sample, and calculated their black hole mass and Eddington ratio using their optical spectra. We then performed a Kolmogorov-Smirnov statistical test to investigate the compatibility of our different samples with a beamed population. Our results indicate that, when the inclination angle increases, a beamed source appears as a steep-spectrum radio-loud NLS1, or possibly even as a disk-hosted radio-galaxy with low black hole mass and high Eddington ratio. Further investigations, involving larger complete samples and observations at radio frequency, are needed to understand the incidence of disk-hosted radio-galaxies in the parent population, and to assess whether radio-quiet NLS1s can play a role, as well.Comment: 12 pages, 6 figures, accepted for publication by Astronomy and Astrophysic

Balmer Emission Line Profiles and the Complex Properties of Broad Line Regions in Active Galactic Nuclei

In this work we analyze a sample of AGN spectra, selected from the 6th Data Release of the Sloan Digital Sky Survey, exploiting a generalized technique of line profile analysis, designed to take into account the whole profiles of their broad emission lines. We find that the line profile broadening functions result from a complex structure, but we may be able to infer some constraints about the role of the geometrical factor, thus improving our ability to estimate AGN properties and their relation with the host galaxy. Our results suggest that flattening and inclination within the structure of the Broad Line Region (BLR) must be taken into account. We detect low inclinations of the BLR motion plane with respect to our line of sight, typically i < 20 degrees, with a geometrical effect which generally decreases as the line profile becomes broader.Comment: 13 pages, 11 figures, updated reference list. ApJ accepte

Structure, Atomistic Simulations, and Phase Transition of Stoichiometric Yeelimite

ABSTRACT: Yeelimite, Ca4[Al6O12]SO4, is outstanding as an aluminate sodalite, being the framework of these type of materials flexible and dependent on ion sizes and anion ordering/disordering. On the other hand, yeelimite is also important from an applied perspective as it is the most important phase in calcium sulfoaluminate cements. However, its crystal structure is not well studied. Here, we characterize the room temperature crystal structure of stoichiometric yeelimite through joint Rietveld refinement using neutron and Xray powder diffraction data coupled with chemical soft-constraints. Our structural study shows that yeelimite has a lower symmetry than that of the previously reported tetragonal system, which we establish to likely be the acentric orthorhombic space group Pcc2, with a √2a × √2a × a superstructure based on the cubic sodalite structure. Final unit cell values were a = 13.0356(7) Å, b = 13.0350(7) Å, and c = 9.1677(2) Å. We determine several structures using density functional theory calculations, with the lowest energy structure being Pcc2 in agreement with our experimental result. Yeelimite undergoes a reversible phase transition to a higher-symmetry phase which has been characterized to occur at 470 °C by thermodiffractometry. The higher-symmetry phase is likely cubic or pseudocubic possessing an incommensurate superstructure, as suggested by our theoretical calculations which show a phase transition from an orthorhombic to a tetragonal structure. Our theoretical study also predicts a pressure-induced phase transition to a cubic structure of space group I43m. Finally, we show that our reported crystal structure of yeelimite enables better mineralogical phase analysis of commercial calcium sulfoaluminate cements, as shown by RF values for this phase, 6.9% and 4.8% for the previously published orthorhombic structure and for the one reported in this study, respectively.Universidad de Málaga. Campus de Excelencia Internacional. Andalucía Tech

Sympathy for the environment predicts green consumerism but not more important environmental behaviours related to domestic energy use

SUMMARY Household consumption is a major contributor to global greenhouse gas emissions. Some behaviours (for example energy use and vehicle use) may have far larger impacts than others (for example green consumerism of household products). Here, the driving forces of green consumerism and two domestic energy uses (electricity consumption and vehicle fuel use) are compared. This study found that environmental attitudes predicted green consumerism, but not electricity consumption or vehicle fuel use. Furthermore, green consumerism was correlated with income and individual level demographic factors, while energy consumption was primarily predicted by household size and structural constraints. Because household energy consumption has greater environmental impacts than green consumerism, policies that aim to improve pro-environmental attitudes may not be effective in mitigating greenhouse gas emissions. Policies should rather aim to change structural constraints influencing transportation and household energy decisions and improve the conspicuousness of household energy consumption

Elastic lever arm model for myosin V

We present a mechanochemical model for myosin V, a two-headed processive motor protein. We derive the properties of a dimer from those of an individual head, which we model both with a 4-state cycle (detached, attached with ADP.Pi, attached with ADP and attached without nucleotide) and alternatively with a 5-state cycle (where the power stroke is not tightly coupled to the phosphate release). In each state the lever arm leaves the head at a different, but fixed, angle. The lever arm itself is described as an elastic rod. The chemical cycles of both heads are coordinated exclusively by the mechanical connection between the two lever arms. The model explains head coordination by showing that the lead head only binds to actin after the power stroke in the trail head and that it only undergoes its power stroke after the trail head unbinds from actin. Both models (4- and 5-state) reproduce the observed hand-over-hand motion and fit the measured force-velocity relations. The main difference between the two models concerns the load dependence of the run length, which is much weaker in the 5-state model. We show how systematic processivity measurement under varying conditions could be used to distinguish between both models and to determine the kinetic parameters.Comment: 15 pages, 15 figures, to appear in Biophys.

Exploring the parent population of beamed NLS1s: from the black hole to the jet

The aim of this work is to understand the nature of the parent population of beamed narrow-line Seyfert 1 galaxies (NLS1s), by studying the physical properties of three parent candidates samples: steep-spectrum radio-loud NLS1s, radio-quiet NLS1s and disk-hosted radio-galaxies. In particular, we focused on the black hole mass and Eddington ratio distribution and on the interactions between the jet and the narrow-line region.Comment: 6 pages, 2 figures, to appear in Proceedings of High Energy Phenomena in Relativistic Outflows (HEPRO) V, Workshop Series of the Argentinian Astronomical Societ

Chemical Recycling of a Textile Blend from Polyester and Viscose, Part II: Mechanism and Reactivity during Alkaline Hydrolysis of Textile Polyester

Chemical recycling of textiles holds the potential to yield materials of equal quality and value as products from virgin feedstock. Selective depolymerization of textile polyester (PET) from regenerated cellulose/PET blends, by means of alkaline hydrolysis, renders the monomers of PET while cellulose remains in fiber form. Here, we present the mechanism and reactivity of textile PET during alkaline hydrolysis. Part I of this article series focuses on the cellulose part and a possible industrialization of such a process. The kinetics and reaction mechanism for alkaline hydrolysis of polyester packaging materials or virgin bulk polyester are well described in the scientific literature; however, information on depolymerization of PET from textiles is sparse. We find that the reaction rate of hydrolysis is not affected by disintegrating the fabric to increase its surface area. We ascribe this to the yarn structure, where texturing and a low density assures a high accessibility even without disintegration. The reaction, similar to bulk polyester, is shown to be surface specific and proceeds via endwise peeling. Finally, we show that the reaction product terephthalic acid is pure and obtained in high yields

How children talk about events:Implications for eliciting and analyzing eyewitness reports

Legal and social service professionals often question whether various features of young witnesses’ responses during interviews are characteristic of children’s event reports or whether these features are concerning findings that reflect degraded memory, outside influence, or other phenomena. To assist helping professionals and researchers who collect data through interviews, we aggregated findings from child eyewitness studies and revisited transcript sets to construct fifteen principles that capture how children talk about events. These principles address children’s earliest event narratives, how children report information as interviews unfold and typical features of their narratives, threats to the accuracy of answers, the influence of interviewers’ language on children’s styles of reporting, how testimonies compare across multiple interviews and multiple witnesses to the same event, and the structure of accurate and inaccurate reports. A summary table highlights the implications of these principles for interviewers and the decision-makers who analyze children’s reports

Spectral optical monitoring of 3C390.3 in 1995-2007: I. Light curves and flux variation of the continuum and broad lines

Here we present the results of the long-term (1995-2007) spectral monitoring of the broad line radio galaxy \object{3C~390.3}, a well known AGN with the double peaked broad emission lines, usually assumed to be emitted from an accretion disk. To explore dimensions and structure of the BLR, we analyze the light curves of the broad H$\alpha$ and H$\beta$ line fluxes and the continuum flux. In order to find changes in the BLR, we analyze the H$\alpha$ and H$\beta$ line profiles, as well as the change in the line profiles during the monitoring period. First we try to find a periodicity in the continuum and H$\beta$ light curves, finding that there is a good chance for quasi-periodical oscillations. Using the line shapes and their characteristics (as e.g. peaks separation and their intensity ratio, or FWHM) of broad H$\beta$ and H$\alpha$ lines, we discuss the structure of the BLR. Also, we cross-correlate the continuum flux with H$\beta$ and H$\alpha$ lines to find dimensions of the BLR. We found that during the monitoring period the broad emission component of the H$\alpha$ and H$\beta$ lines, and the continuum flux varied by a factor of $\approx$4-5. Also, we detected different structure in the line profiles of H$\alpha$ and H$\beta$. It seems that an additional central component is present and superposed to the disk emission. In the period of high activity (after 2002), H$\beta$ became broader than H$\alpha$ and red wing of H$\beta$ was higher than the one of H$\alpha$. We found time lags of $\sim$95 days between the continuum and H$\beta$ flux, and about 120 days between the continuum and H$\alpha$ flux. Variation in the line profiles, as well as correlation between the line and continuum flux during the monitoring period is in the favor of the disk origin of the broad lines with the possible contribution of some additional region and/or some kind of perturbation in the disk.Comment: 32 pages, accepted to A&A, typos correcte