7,693 research outputs found
New electrocatalysts for hydrogen-oxygen fuel cells
Platinum-silver, palladium-gold, and platinum-gold alloys serve as oxygen reduction catalysts in high-current-density cells. Catalysts were tested on polytetrafluoroethylene-bonded cathodes and a hydrogen anode at an operating cell temperature of 80 degrees C
Droplet shapes on structured substrates and conformal invariance
We consider the finite-size scaling of equilibrium droplet shapes for fluid
adsorption (at bulk two-phase co-existence) on heterogeneous substrates and
also in wedge geometries in which only a finite domain of the
substrate is completely wet. For three-dimensional systems with short-ranged
forces we use renormalization group ideas to establish that both the shape of
the droplet height and the height-height correlations can be understood from
the conformal invariance of an appropriate operator. This allows us to predict
the explicit scaling form of the droplet height for a number of different
domain shapes. For systems with long-ranged forces, conformal invariance is not
obeyed but the droplet shape is still shown to exhibit strong scaling
behaviour. We argue that droplet formation in heterogeneous wedge geometries
also shows a number of different scaling regimes depending on the range of the
forces. The conformal invariance of the wedge droplet shape for short-ranged
forces is shown explicitly.Comment: 20 pages, 7 figures. (Submitted to J.Phys.:Cond.Mat.
Correlation function algebra for inhomogeneous fluids
We consider variational (density functional) models of fluids confined in
parallel-plate geometries (with walls situated in the planes z=0 and z=L
respectively) and focus on the structure of the pair correlation function
G(r_1,r_2). We show that for local variational models there exist two
non-trivial identities relating both the transverse Fourier transform G(z_\mu,
z_\nu;q) and the zeroth moment G_0(z_\mu,z_\nu) at different positions z_1, z_2
and z_3. These relations form an algebra which severely restricts the possible
form of the function G_0(z_\mu,z_\nu). For the common situations in which the
equilibrium one-body (magnetization/number density) profile m_0(z) exhibits an
odd or even reflection symmetry in the z=L/2 plane the algebra simplifies
considerably and is used to relate the correlation function to the finite-size
excess free-energy \gamma(L). We rederive non-trivial scaling expressions for
the finite-size contribution to the free-energy at bulk criticality and for
systems where large scale interfacial fluctuations are present. Extensions to
non-planar geometries are also considered.Comment: 15 pages, RevTex, 4 eps figures. To appear in J.Phys.Condens.Matte
A microscopic approach to critical phenomena at interfaces: an application to complete wetting in the Ising model
We study how the formalism of the Hierarchical Reference Theory (HRT) can be
extended to inhomogeneous systems. HRT is a liquid state theory which
implements the basic ideas of Wilson momentum shell renormalization group (RG)
to microscopic Hamiltonians. In the case of homogeneous systems, HRT provides
accurate results even in the critical region, where it reproduces scaling and
non-classical critical exponents. We applied the HRT to study wetting critical
phenomena in a planar geometry. Our formalism avoids the explicit definition of
effective surface Hamiltonians but leads, close to the wetting transition, to
the same renormalization group equation already studied by RG techiques.
However, HRT also provides information on the non universal quantities because
it does not require any preliminary coarse graining procedure. A simple
approximation to the infinite HRT set of equations is discussed. The HRT
evolution equation for the surface free energy is numerically integrated in a
semi-infinite three-dimensional Ising model and the complete wetting phase
transition is analyzed. A renormalization of the adsorption critical amplitude
and of the wetting parameter is observed. Our results are compared to available
Monte Carlo simulations.Comment: To be published in Phy. Rev.
New bulk scalar field solutions in brane worlds
We use nonlinear perturbation theory to obtain new solutions for brane world
models that incorporate a massive bulk scalar field. We then consider tensor
perturbations and show that Newtonian gravity is recovered on the brane for
both a light scalar field and for a bulk field with large negative mass. This
latter result points to the viability of higher-derivative theories of gravity
in the context of bulk extra dimensions.Comment: 4+\epsilon pages, no figure
3D wedge filling and 2D random-bond wetting
Fluids adsorbed in 3D wedges are shown to exhibit two types of continuous
interfacial unbinding corresponding to critical and tricritical filling
respectively. Analytic solution of an effective interfacial model based on the
transfer-matrix formalism allows us to obtain the asymptotic probability
distribution functions for the interfacial height when criticality and
tricriticality are approached. Generalised random walk arguments show that, for
systems with short-ranged forces, the critical singularities at these
transitions are related to 2D complete and critical wetting with random bond
disorder respectively.Comment: 7 pages, 3 figures, accepted for publication in Europhysics Letter
Zenithal bistability in a nematic liquid crystal device with a monostable surface condition
The ground-state director configurations in a grating-aligned, zenithally bistable nematic device are calculated in two dimensions using a Q tensor approach. The director profiles generated are well described by a one-dimensional variation of the director across the width of the device, with the distorted region near the grating replaced by an effective surface anchoring energy. This work shows that device bistability can in fact be achieved by using a monostable surface term in the one-dimensional model. This implies that is should be possible to construct a device showing zenithal bistability without the need for a micropatterned surface
How do people with knee osteoarthritis perceive and manage flares? A qualitative study
Background
Acute flares in people with osteoarthritis (OA) are poorly understood. There is uncertainty around the nature of flares, their impact, and how these are managed.
Aim
To explore understandings and experiences of flares in people with knee OA, and to describe self-management and help-seeking strategies.
Design & setting
Qualitative interview study of people with knee OA in England.
Method
Semi-structured interviews were undertaken with 15 people with knee OA. Thematic analysis was applied using constant comparison methods.
Results
The following four main themes were identified: experiencing pain; consequences of acute pain; predicting and avoiding acute pain; and response to acute pain. People with OA described minor episodes that were frequent, fleeting, occurred during everyday activity, had minimal impact, and were generally predictable. This contrasted with severe episodes that were infrequent, had greater impact, and were less likely to be predictable. The latter generally led to feelings of low confidence, vulnerability, and of being a burden. The term ‘flare’ was often used to describe the severe events but this was applied inconsistently and some would describe a flare as any increase in pain. Participants used numerous self-management strategies but tended to seek help when these had been exhausted, their symptoms led to emotional distress, disturbed sleep, or pain experience worse than usual. Previous experiences shaped whether people sought help and who they sought help from.
Conclusion
Severe episodes of pain are likely to be synonymous with flares. Developing a common language about flares will allow a shared understanding of these events, early identification, and appropriate management
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