717 research outputs found
Openflow switching: data plane performance
Abstract—OpenFlow is an open standard that can be implemented in Ethernet switches, routers and wireless access points (AP). In the OpenFlow framework, packet forwarding (data plane) and routing decisions (control plane) run on different devices. OpenFlow switches are in charge of packet forwarding, whereas a controller sets up switch forwarding tables on a perflow basis, to enable flow isolation and resource slicing. We focus on the data path and analyze the OpenFlow implementation in Linux based PCs. We compare OpenFlow switching, layer-2 Ethernet switching and layer-3 IP routing performance. Forwarding throughput and packet latency in underloaded and overloaded conditions are analyzed, with different traffic patterns. System scalability is analyzed using different forwarding table size, and fairness in resource distribution is measured. I
Electron transport through a metal-molecule-metal junction
Molecules of bisthiolterthiophene have been adsorbed on the two facing gold
electrodes of a mechanically controllable break junction in order to form
metal-molecule(s)-metal junctions. Current-voltage (I-V) characteristics have
been recorded at room temperature. Zero bias conductances were measured in the
10-100 nS range and different kinds of non-linear I-V curves with step-like
features were reproducibly obtained. Switching between different kinds of I-V
curves could be induced by varying the distance between the two metallic
electrodes. The experimental results are discussed within the framework of
tunneling transport models explicitly taking into account the discrete nature
of the electronic spectrum of the molecule.Comment: 12 pages, 12 figures to appear in Phys. Rev. B 59(19) 199
Achievements, Challenges, and Prospects of Calcium Batteries
This Review flows from past attempts to develop a (rechargeable) battery technology based on Ca via crucial breakthroughs to arrive at a comprehensive discussion of the current challenges at hand. The realization of a rechargeable Ca battery technology primarily requires identification and development of suitable electrodes and electrolytes, which is why we here cover the progress starting from the fundamental electrode/electrolyte requirements, concepts, materials, and compositions employed and finally a critical analysis of the state-of-the-art, allowing us to conclude with the particular roadblocks still existing. As for crucial breakthroughs, reversible plating and stripping of calcium at the metal-anode interface was achieved only recently and for very specific electrolyte formulations. Therefore, while much of the current research aims at finding suitable cathodes to achieve proof-of-concept for a full Ca battery, the spectrum of electrolytes researched is also expanded. Compatibility of cell components is essential, and to ensure this, proper characterization is needed, which requires design of a multitude of reliable experimental setups and sometimes methodology development beyond that of other next generation battery technologies. Finally, we conclude with recommendations for future strategies to make best use of the current advances in materials science combined with computational design, electrochemistry, and battery engineering, all to propel the Ca battery technology to reality and ultimately reach its full potential for energy storage
Anomaly Detection for Diagnosing Failures in a Centrifugal Compressor Train
Predicting machine failures is of the utmost importance in industrial systems as it can turn expensive crashes and repair costs into affordable maintenance costs. To this end, this paper presents preliminary work for detecting failures in a centrifugal compressor train based on sensorial data. We show the detection capabilities of a two-step process consisting of: (1) a preprocessing step to reduce the dimensionality of the input data using Principal Component Analysis, and (2) an anomaly detection step using the Mahalanobis distance to detect anomalous observations on the sensors' data. The experiments using real-world data demonstrate the feasibility of our approach and the ability of the method to detect the failures eight days in advance
Towards standard electrolytes for sodium-ion batteries: physical properties, ion solvation and ion-pairing in alkyl carbonate solvents
The currently emerging sodium-ion battery technology is in need of an optimized standard organic solvent electrolyte based on solid and directly comparable data. With this aim we have made a systematic study of "simple"electrolyte systems consisting of two sodium salts (NaTFSI and NaPF6) dissolved in three different alkyl carbonate solvents (EC, PC, DMC) within a wide range of salt concentrations and investigated: (i) their more macroscopic physico-chemical properties such as ionic conductivity, viscosity, thermal stability, and (ii) the molecular level properties such as ion-pairing and solvation. From this all electrolytes were found to have useful thermal operational windows and electrochemical stability windows, allowing for large scale energy storage technologies focused on load levelling or (to a less extent) electric vehicles, and ionic conductivities on par with analogous lithium-ion battery electrolytes, giving promise to also be power performant. Furthermore, at the molecular level the NaPF6-based electrolytes are more dissociated than the NaTFSI-based ones because of the higher ionic association strength of TFSI compared to PF6- while two different conformers of DMC participate in the Na+ first solvation shells-a Na+ affected conformational equilibrium and induced polarity of DMC. The non-negligible presence of DMC in the Na+ first solvation shells increases as a function of salt concentration. Overall, these results should both have a general impact on the design of more performant Na-conducting electrolytes and provide useful insight on the very details of the importance of DMC conformers in any cation solvation studies
Interfaces and Interphases in Ca and Mg Batteries
The development of high energy density battery technologies based on divalent metals as the negative electrode is very appealing. Ca and Mg are especially interesting choices due to their combination of low standard reduction potential and natural abundance. One particular problem stalling the technological development of these batteries is the low efficiency of plating/stripping at the negative electrode, which relates to several factors that have not yet been looked at systematically; the nature/concentration of the electrolyte, which determines the mass transport of electro-active species (cation complexes) toward the electrode; the possible presence of passivation layers, which may hinder ionic transport and hence limit electrodeposition; and the mechanisms behind the charge transfer leading to nucleation/growth of the metal. Different electrolytes are investigated for Mg and Ca, with the presence/absence of chlorides in the formulation playing a crucial role in the cation desolvation. From a R&D point-of-view, proper characterization alongside modeling is crucial to understand the phenomena determining the mechanisms of the plating/stripping processes. The state-of-the-art is here presented together with a short perspective on the influence of the cation solvation also on the positive electrode and finally an attempt to define guidelines for future research in the field
A UML Profile for the Design, Quality Assessment and Deployment of Data-intensive Applications
Big Data or Data-Intensive applications (DIAs) seek to mine, manipulate, extract or otherwise exploit the potential intelligence hidden behind Big Data. However, several practitioner surveys remark that DIAs potential is still untapped because of very difficult and costly design, quality assessment and continuous refinement. To address the above shortcoming, we propose the use of a UML domain-specific modeling language or profile specifically tailored to support the design, assessment and continuous deployment of DIAs. This article illustrates our DIA-specific profile and outlines its usage in the context of DIA performance engineering and deployment. For DIA performance engineering, we rely on the Apache Hadoop technology, while for DIA deployment, we leverage the TOSCA language. We conclude that the proposed profile offers a powerful language for data-intensive software and systems modeling, quality evaluation and automated deployment of DIAs on private or public clouds
Control theory applied to the design of AGC circuits
Applications of control theory in the design of automatic gain control (AGC) circuits are presented. A general model for AGC circuits is presented, and an equivalent linear system is proposed. Its behavior is compared with the dynamical response of two implemented AGC circuits. The results of classic and state variable correctors based on the model are presented. These results show the usefulness of this linear model in the design of the AGC dynamic response. By using a linear and t-variant system the dynamical behavior is improved. This approach is used to design hyperstability and Lyapunov-based correctorsPeer ReviewedPostprint (published version
Stabilization of p21 by mTORC1/4E-BP1 predicts clinical outcome of head and neck cancers
The levels, regulation and prognostic value of p21 in head and neck squamous cell carcinomas (HNSCC) has been puzzling for years. Here, we report a new mechanism of regulation of p21 by the mTORC1/4E-BP1 pathway. We find that non-phosphorylated 4E-BP1 interacts with p21 and induces its degradation. Accordingly, hyper-activation of mTORC1 results in phosphorylation of 4E-BP1 and stabilization of p21. In HNSCC, p21 levels strongly correlate with mTORC1 activity but not with p53 status. Finally, clinical data indicate that HNSCC patients with p21 and phospho-S6-double-positive tumours present a better disease-specific survival. We conclude that over-activation of the mTORC1/4E-BP1/p21 pathway is a frequent and clinically relevant alteration in HNSCC.We are grateful to Reidar Grenman, Silvio Gutkind, Nahum Sonenberg, Gordon Peters, David Sabatini and Mariano Barbacid for sharing critical reagents. We also thank Aurora Astudillo, Aitana Vallina, Laura Alonso-Dura ́n and Eva Allonca for excellent technical assistance. Work in the laboratory of M.S. is funded by the CNIO and by grants from the Spanish Ministry of Economy (SAF) co-funded by the European Regional Development Fund, the European Research Council (ERC Advanced Grant), the Regional Government
of Madrid co-funded by the European Social Fund, the Botin Foundation and BancoSantander (Santander Universities Global Division), the Ramon Areces Foundation an the AXA Foundation. Work in the laboratory of J.M.G.-P. and J.P.R. was supported bygrants from Plan Nacional de DþI 2013–2016 ISCIII (CP13/00013 andPI13/00259),RD12/0036/0015 of Red Tematica de Investigacio ́n Cooperativa en Cancer (RTICC),
Spain and the FEDER Funding Program from the European UnionS
TTF-Podants and TTF-Calixarene assemblies : original striuctural solutions towards redoxresponsive ligands
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