6,535 research outputs found
Temperature driven to phase-transformation in Ti, Zr and Hf from first principles theory combined with lattice dynamics
Lattice dynamical methods used to predict phase transformations in crystals
typically deal with harmonic phonon spectra and are therefore not applicable in
important situations where one of the competing crystal structures is unstable
in the harmonic approximation, such as the bcc structure involved in the hcp to
bcc martensitic phase transformation in Ti, Zr and Hf. Here we present an
expression for the free energy that does not suffer from such shortcomings, and
we show by self consistent {\it ab initio} lattice dynamical calculations
(SCAILD), that the critical temperature for the hcp to bcc phase transformation
in Ti, Zr and Hf, can be effectively calculated from the free energy difference
between the two phases. This opens up the possibility to study quantitatively,
from first principles theory, temperature induced phase transitions.Comment: 4 pages, 3 figure
Water vapor on supergiants. The 12 micron TEXES spectra of mu Cephei
Several recent papers have argued for warm, semi-detached, molecular layers
surrounding red giant and supergiant stars, a concept known as a MOLsphere.
Spectroscopic and interferometric analyses have often corroborated this general
picture. Here, we present high-resolution spectroscopic data of pure rotational
lines of water vapor at 12 microns for the supergiant mu Cephei. This star has
often been used to test the concept of molecular layers around supergiants.
Given the prediction of an isothermal, optically thick water-vapor layer in
Local Thermodynamic Equilibrium around the star (MOLsphere), we expected the 12
micron lines to be in emission or at least in absorption but filled in by
emission from the molecular layer around the star. Our data, however, show the
contrary; we find definite absorption. Thus, our data do not easily fit into
the suggested isothermal MOLsphere scenario. The 12 micron lines, therefore,
put new, strong constraints on the MOLsphere concept and on the nature of water
seen in signatures across the spectra of early M supergiants. We also find that
the absorption is even stronger than that calculated from a standard,
spherically symmetric model photosphere without any surrounding layers. A cool
model photosphere, representing cool outer layers is, however, able to
reproduce the lines, but this model does not account for water vapor emission
at 6 microns. Thus, a unified model for water vapor on mu Cephei appears to be
lacking. It does seem necessary to model the underlying photospheres of these
supergiants in their whole complexity. The strong water vapor lines clearly
reveal inadequacies of classical model atmospheres.Comment: Accepted for publication in the Astrophysical Journa
Poloidal ULF oscillations in the dayside magnetosphere: a Cluster study
Three ULF wave events, all occurring in the dayside magnetopshere during magnetically quiet times, are studied using the Cluster satellites. The multi-point measurements obtained from Cluster are used to determine the azimuthal wave number for the events by means of the phase shift and the azimuthal separation between the satellites. Also, the polarisation of the electric and magnetic fields is examined in a field-aligned coordinate system, which, in turn, gives the mode of the oscillations. The large-inclination orbits of Cluster allow us to examine the phase relationship between the electric and magnetic fields along the field lines. The events studied have large azimuthal wave numbers (<i>m</i>~100), two of them have eastward propagation and all are in the poloidal mode, consistent with the large wave numbers. We also use particle data from geosynchronous satellites to look for signatures of proton injections, but none of the events show any sign of enhanced proton flux. Thus, the drift-bounce resonance instability seems unlikely to have played any part in the excitation of these pulsations. As for the drift-mirror instability we conclude that it would require an unreasonably high plasma pressure for the instability criterion to be satisfied.<br><br><b>Keywords.</b> Ionosphere (Wave propagation) â Magnetospheric physics (Plasma waves and instabilities; Instruments and techniques
Poisson equation and self-consistent periodical Anderson model
We show that the formally exact expression for the free energy (with a
non-relativistic Hamiltonian) for the correlated metal generates the Poisson
equation within the saddle-point approximation for the electric potential,
where the charge density automatically includes correlations. In this
approximation the problem is reduced to the self-consistent periodical Anderson
model (SCPAM). The parameter of the mixing interaction in this formulation have
to be found self-consistently together with the correlated charge density. The
factors, calculated by Irkhin, for the mixing interaction, which reflect the
structure of the many-electron states of the \f-ion involved, arise
automatically in this formulation and are quite sensitive to the specific
element we are interested in. We also discuss the definitions of the mixing
interaction for the mapping from ab initio to model calculations.Comment: 25 pages, no figure
Distinguishing among Scalar Field Models of Dark Energy
We show that various scalar field models of dark energy predict degenerate
luminosity distance history of the Universe and thus cannot be distinguished by
supernovae measurements alone. In particular, models with a vanishing
cosmological constant (the value of the potential at its minimum) are
degenerate with models with a positive or negative cosmological constant whose
magnitude can be as large as the critical density. Adding information from CMB
anisotropy measurements does reduce the degeneracy somewhat but not
significantly. Our results indicate that a theoretical prior on the preferred
form of the potential and the field's initial conditions may allow to
quantitatively estimate model parameters from data. Without such a theoretical
prior only limited qualitative information on the form and parameters of the
potential can be extracted even from very accurate data.Comment: 15 pages, 5 figure
Electronic structure investigation of Ti3AlC2, Ti3SiC2, and Ti3GeC2 by soft-X-ray emission spectroscopy
The electronic structures of epitaxially grown films of Ti3AlC2, Ti3SiC2 and
Ti3GeC2 have been investigated by bulk-sensitive soft X-ray emission
spectroscopy. The measured high-resolution Ti L, C K, Al L, Si L and Ge M
emission spectra are compared with ab initio density-functional theory
including core-to-valence dipole matrix elements. A qualitative agreement
between experiment and theory is obtained. A weak covalent Ti-Al bond is
manifested by a pronounced shoulder in the Ti L-emission of Ti3AlC2. As Al is
replaced with Si or Ge, the shoulder disappears. For the buried Al and
Si-layers, strongly hybridized spectral shapes are detected in Ti3AlC2 and
Ti3SiC2, respectively. As a result of relaxation of the crystal structure and
the increased charge-transfer from Ti to C, the Ti-C bonding is strengthened.
The differences between the electronic structures are discussed in relation to
the bonding in the nanolaminates and the corresponding change of materials
properties.Comment: 15 pages, 8 figure
Spatial distribution of low-energy plasma around 2 comet 67P/CG from Rosetta measurements
International audienceWe use measurements from the Rosetta plasma consortium (RPC) Langmuir probe (LAP) and mutual impedance probe (MIP) to study the spatial distribution of low-energy plasma in the near-nucleus coma of comet 67P/Churyumov-Gerasimenko. The spatial distribution is highly structured with the highest density in the summer hemisphere and above the region connecting the two main lobes of the comet, i.e. the neck region. There is a clear correlation with the neutral density and the plasma to neutral density ratio is found to be âŒ1-2·10 â6 , at a cometocentric distance of 10 km and at 3.1 AU from the sun. A clear 6.2 h modulation of the plasma is seen as the neck is exposed twice per rotation. The electron density of the collisonless plasma within 260 km from the nucleus falls of with radial distance as âŒ1/r. The spatial structure indicates that local ionization of neutral gas is the dominant source of low-energy plasma around the comet
Comparative Modelling of the Spectra of Cool Giants
Our ability to extract information from the spectra of stars depends on
reliable models of stellar atmospheres and appropriate techniques for spectral
synthesis. Various model codes and strategies for the analysis of stellar
spectra are available today. We aim to compare the results of deriving stellar
parameters using different atmosphere models and different analysis strategies.
The focus is set on high-resolution spectroscopy of cool giant stars. Spectra
representing four cool giant stars were made available to various groups and
individuals working in the area of spectral synthesis, asking them to derive
stellar parameters from the data provided. The results were discussed at a
workshop in Vienna in 2010. Most of the major codes currently used in the
astronomical community for analyses of stellar spectra were included in this
experiment. We present the results from the different groups, as well as an
additional experiment comparing the synthetic spectra produced by various codes
for a given set of stellar parameters. Similarities and differences of the
results are discussed. Several valid approaches to analyze a given spectrum of
a star result in quite a wide range of solutions. The main causes for the
differences in parameters derived by different groups seem to lie in the
physical input data and in the details of the analysis method. This clearly
shows how far from a definitive abundance analysis we still are.Comment: accepted for publication in A&A. This version includes also the
online tables. Reference spectra will later be available via the CD
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