Sources and budgets for CO and O-3 in the northeastern Pacific during the spring of 2001: Results from the PHOBEA-II Experiment

Abstract. Ground and airborne measurements of CO, ozone, and aerosols were obtained in th

Analytical solutions for a two-level system driven by a class of chirped pulses

We present analytical solutions for the problem of a two-level atom driven by a class of chirped pulses. The solutions are given in terms of Heun functions. Using appropriate chirping parameters an enhancement of four-orders of magnitudes in the population transfer is obtained.Comment: 5 pages, 5 figure

Coherent Excitation of a Two-Level Atom driven by a far off-resonant Classical Field: Analytical Solutions

We present an analytical treatment of coherent excitation of a Two-Level Atom driven by a far-off resonant classical field. A class of pulse envelope is obtained for which this problem is exactly solvable. The solutions are given in terms of Heun function which is a generalization of the Hypergeometric function. The degeneracy of Heun to Hypergeometric equation can give all the exactly solvable pulse shapes of Gauss Hypergeometric form, from the generalized pulse shape obtained here. We discuss the application of the results obtained to the generation of XUV.Comment: 9 Pages, 8 Figures. Accepted for Physical Review A as a regular articl

Sources and Secondary Production of Organic Aerosols in the Northeastern United States during WINTER

Most intensive field studies investigating aerosols have been conducted in summer, and thus, wintertime aerosol sources and chemistry are comparatively poorly understood. An aerosol mass spectrometer was flown on the National Science Foundation/National Center for Atmospheric Research C‐130 during the Wintertime INvestigation of Transport, Emissions, and Reactivity (WINTER) 2015 campaign in the northeast United States. The fraction of boundary layer submicron aerosol that was organic aerosol (OA) was about a factor of 2 smaller than during a 2011 summertime study in a similar region. However, the OA measured in WINTER was almost as oxidized as OA measured in several other studies in warmer months of the year. Fifty‐eight percent of the OA was oxygenated (secondary), and 42% was primary (POA). Biomass burning OA (likely from residential heating) was ubiquitous and accounted for 33% of the OA mass. Using nonvolatile POA, one of two default secondary OA (SOA) formulations in GEOS‐Chem (v10‐01) shows very large underpredictions of SOA and O/C (5×) and overprediction of POA (2×). We strongly recommend against using that formulation in future studies. Semivolatile POA, an alternative default in GEOS‐Chem, or a simplified parameterization (SIMPLE) were closer to the observations, although still with substantial differences. A case study of urban outflow from metropolitan New York City showed a consistent amount and normalized rate of added OA mass (due to SOA formation) compared to summer studies, although proceeding more slowly due to lower OH concentrations. A box model and SIMPLE perform similarly for WINTER as for Los Angeles, with an underprediction at ages \u3c6 hr, suggesting that fast chemistry might be missing from the models

Elasto-thermoelectric non-linear, fully coupled, and dynamic finite element analysis of pulsed thermoelectrics

This paper presents a numerical study on the influence of pulsed electric signals applied to the overcooling of thermoelectric devices. To this end, an experimental setup taken from the literature and a commercial cell are simulated using a complete, specially developed research finite element code. The electro-thermal coupling is extended to include the elastic field, demonstrating that the increment of cooling can produce mechanical failure. Numerical results are developed and the variation of overcooling versus pulse gain and versus duration is validated towards a new analytical expression and the experimental data. The issue of optimal intensity at steady-state is also newly developed. Thermal and mechanical trends are presented using constant and variable (with temperature) material properties for a single thermoelement. While some of the first trends are similar to those of published works, others are different or directly new, all closer to those of the experiments. The mechanical results have not been thoroughly studied until recently. The three-dimensional finite element mesh includes non-thermoelectric materials that are fundamental for the current study. Distribution of stresses during steady and transient states are shown inside the thermoelement, for five components and for the combined Tresca stress. Concentrations at corners of the lower side appear close to the cold face. Due to these concentrations, 27-node isoparametric, quadratic brick elements are used. It is shown that the mechanical field is an important factor in the design of pulsed thermoelectrics, since for practical applications the stress levels are close or slightly above the admissible limits.This research was partially supported by grants CSD2008-00037 Canfranc Underground Physics and Polytechnic University of Valencia under programs PAID 02-11-1828 and 05-10-2674.Pérez-Aparicio, JL.; Palma, R.; Moreno-Navarro, P. (2016). Elasto-thermoelectric non-linear, fully coupled, and dynamic finite element analysis of pulsed thermoelectrics. Applied Thermal Engineering. 107:398-409. https://doi.org/10.1016/j.applthermaleng.2016.05.114S39840910

Observations of Reactive Gaseous Mercury in the Free Troposphere at the Mount Bachelor Observatory

We measured gaseous elemental mercury (GEM), particulate mercury (PHg), and reactive gaseous mercury (RGM), along with CO, ozone, and aerosol scatter at the Mount Bachelor Observatory (2.7 km above sea level), Oregon, from May to August 2005. The mean mercury concentrations (at standard conditions) were 1.54 ng/m3 (GEM), 5.2 pg/m3 (PHg), and 43 pg/m3 (RGM). RGM enhancements, up to 600 pg/m3, occurred at night and were linked to a diurnal pattern of upslope and downslope flows that mixed in boundary layer air during the day and free tropospheric air at night. During the night, RGM was inversely correlated (P < 0.0001) with CO (r = −0.36), GEM (r = −0.73), and H2O (r = −0.44), was positively correlated with ozone (r = 0.38), and could not be linked to recent anthropogenic emissions from local sources or long-range transport. Principal component analysis and a composite of change in RGM versus change in GEM during RGM enhancements indicate that a nearly quantitative shift in speciation is associated with increases in ozone and decreases in water vapor and CO. This argues that high concentrations of RGM are present in the free troposphere because of in situ oxidation of GEM to RGM. A global chemical transport model reproduces the RGM mean and diurnal pattern but underestimates the magnitude of the largest observed enhancements. Since the only modeled, in situ RGM production mechanisms are oxidation of GEM by ozone and OH, this implies that there are faster reaction rates or additional RGM production mechanisms in the free troposphere.Earth and Planetary SciencesEngineering and Applied Science

Quasi-free photoproduction of η-mesons off 3He nuclei

Quasi-free photoproduction of η-mesons has been measured off nucleons bound in 3He nuclei for incident photon energies from the threshold region up to 1.4 GeV. The experiment was performed at the tagged photon facility of the Mainz MAMI accelerator with an almost 4π covering electromagnetic calorimeter, combining the TAPS and Crystal Ball detectors. The η-mesons were detected in coincidence with the recoil nucleons. This allowed a comparison of the production cross section off quasi-free protons and quasi-free neutrons and a full kinematic reconstruction of the final state, eliminating effects from nuclear Fermi motion. In the S11(1535) resonance peak, the data agree with the neutron/proton cross section ratio extracted from measurements with deuteron targets. More importantly, the prominent structure observed in photoproduction off quasi-free neutrons bound in the deuteron is also clearly observed. Its parameters (width, strength) are consistent with the expectations from the deuteron results. On an absolute scale the cross sections for both quasi-free protons and neutrons are suppressed with respect to the deuteron target pointing to significant nuclear final-state interaction effects

A crucial role for the ubiquitously expressed transcription factor Sp1 at early stages of hematopoietic specification

Mammalian development is regulated by the interplay of tissue-specific and ubiquitously expressed transcription factors, such as Sp1. Sp1 knockout mice die in utero with multiple phenotypic aberrations, but the underlying molecular mechanism of this differentiation failure has been elusive. Here, we have used conditional knockout mice as well as the differentiation of mouse ES cells as a model with which to address this issue. To this end, we examine