Strong plasmonic fluorescence enhancement of individual plant light-harvesting complexes

Plasmonic coupling of metallic nanoparticles and adjacent pigments can dramatically increase the brightness of the pigments due to the enhanced local electric field. Here, we demonstrate that the fluorescence brightness of a single plant light-harvesting complex (LHCII) can be significantly enhanced when coupled to single gold nanorods (AuNRs). The AuNRs utilized in this study were prepared via chemical reactions, and the hybrid system was constructed using a simple and economical spin-assisted layer-by-layer technique. Enhancement of fluorescence brightness of up to 240-fold was observed, accompanied by a 109-fold decrease in the average (amplitude-weighted) fluorescence lifetime from approximately 3.5 ns down to 32 ps, corresponding to an excitation enhancement of 63-fold and emission enhancement of up to 3.8-fold. This large enhancement is due to the strong spectral overlap of the longitudinal localized surface plasmon resonance of the utilized AuNRs and the absorption or emission bands of LHCII. This study provides an inexpensive strategy to explore the fluorescence dynamics of weakly emitting photosynthetic light-harvesting complexes at the single molecule level.Comment: 23 pages, 6 figures, 2 supplementary figures, and supplementary equation

Thermal analysis of the LLR optical telescope tube assembly based in Hartebeesthoek Radio Astronomy Observatory

The Hartebeesthoek Radio Astronomy Observatory of South Africa is currently developing a lunar laser ranger (LLR) system based on a one metre aperture telescope in collaboration with National Aeronautics and Space Administration and the Observatoire de la Côte d’Azur. This LLR will be an addition to a limited list of operating LLR stations globally and it is expected to achieve sub-centimetre range precision to the Moon. Key to this expectation including the overall telescope operational performance is thermal analysis of the telescope structure, based on the thermal properties of component materials and their interaction with the environment through conventional heat transfer mechanisms. This paper presents transient thermal simulation results of the telescope’s optical tube and one metre primary mirror in terms of thermal variations and consequent structural deformations. The results indicate that on a non-windy, cloud-free and winter day, the temperature gradients on the structure could be within 1 °C with respect to the temporal ambient air temperatures at the site when these are between 9 and 23 °C. Furthermore, these gradients were coupled with thermally-induced total deformations that vary between 2.9 and 40.7 μm of the assembled telescope components. In overall, these findings suggest that both the tube and especially the mirror may respond very slowly to ambient temperatures; however, correcting for structural thermal variations is imperative in maximizing the pointing accuracy of the telescope thereby increasing the chance being on-target with the retroreflectors located on the Moon surface.P. L. Tsela hereby acknowledges research support in part by the National Research Foundation of South Africa for the grant, Unique Grant No. 93952.http://link.springer.com/journal/403282017-09-30hb2016Geography, Geoinformatics and Meteorolog

Simulation of the enhanced infrared photoresponse of type-II GaSb/GaAs quantum ring solar cells

The extended photo-response of solar cells containing ten periods of GaSb/GaAs quantum rings imbedded in the p-i-n junction has been described using a single-band representation of the type-II quantum ring structure. By fitting the experimental data, the authors were able to deduce that the quantum rings are well represented by a Gaussian height distribution and a large valence band discontinuity. The simulated band of states is shown to be well matched to the photoluminescence analysis of the structure, with the inhomogeneous size distribution resulting in a band of hole states roughly 390 meV above the valence band

Evaluation of the two-photon absorption characteristics of GaSb/GaAs quantum rings

The optical parameters describing the sub-bandgap response of GaSb/GaAs quantum rings solar cells have been obtained from photocurrent measurements using a modulated pseudomonochromatic light source in combination with a second, continuous photo-filling source. By controlling the charge state of the quantum rings, the photoemission cross-sections describing the two-photon sub-bandgap transitions could be determined independently. Temperature dependent photo-response measurements also revealed that the barrier for thermal hole emission from the quantum rings is significantly below the quantum ring localisation energy. The temperature dependence of the sub-bandgap photo-response of the solar cell is also described in terms of the photo-and thermal-emission characteristics of the quantum rings. (C) 2014 AIP Publishing LLC

Pre-operative Planning and Intra-operative Guidance for Shoulder Replacement Surgery

Shoulder joint replacement, or arthroplasty, is indicated in cases where arthritis or trauma has resulted in severe joint damage that in turn causes increased pain and decreased function. However, shoulder arthroplasty is less successful than hip and knee replacement, mostly due to the complexity of the shoulder joint and the resultant complexity of the replacement operation. In this paper we present a complete visualization-oriented pre-operative planning and intra-operative guidance approach for shoulder joint replacement. Our system assists the surgeon by allowing a virtual arthroplasty procedure whilst giving feedback, primarily via patient- and procedure-specific joint range of motion (ROM) simulation and visualization. After a successful planning, our system automatically generates a 3D model of a patient-specific mechanical guidance device that is then produced by a rapid prototyping machine and can be used during the operation. In this way, a computer-based guidance system is not required in the operating room

On the flare induced seismicity in the active region NOAA 10930 and related enhancement of global waves in the sun

A major flare (of class X3.4) occurred on 13 December 2006 in the active region NOAA 10930. The energy released during flares is also known to induce acoustic oscillations in the Sun. Here, we analyze the line-of-sight velocity patterns in this active region during the X3.4 flare using the Dopplergrams obtained by GONG instrument. We have also analyzed the disk-integrated velocity observations of the Sun obtained by GOLF instrument onboard SOHO spacecraft as well as full-disk collapsed velocity signals from GONG observations during this flare to study any possible connection between the flare related changes seen in the local and global velocity oscillations in the Sun. We apply wavelet transform to the time series of the localized velocity oscillations as well as the global velocity oscillations in the Sun spanning the flare event. The line-of-sight velocity shows significant enhancement in some localized regions of the penumbra of this active region during the flare. The affected region is seen to be away from the locations of the flare ribbons and the hard X-ray footpoints. The sudden enhancement in this velocity seems to be caused by the Lorentz force driven by the "magnetic jerk" in the localized penumbral region. Application of wavelet analysis to these flare induced localized seismic signals show significant enhancement in the high-frequency domain (5-8 mHz) and a feeble enhancement in the p-mode oscillations (2-5 mHz) during the flare. On the other hand, the wavelet analysis of GOLF velocity data and the full-disk collapsed GONG velocity data spanning the flare event indicate significant post-flare enhancements in the high-frequency global velocity oscillations in the Sun. We find indications of a connection between flare induced localized seismic signals and the excitation of global high-frequency oscillations in the Sun.Comment: 29 pages, 7 figures, To appear in The Astrophysical Journa

Less hunger, better health and more wealth: the benefits of knowledge sharing in Malawi’s Orange-Fleshed Sweet Potato project

Agricultural researchers, NGOs and farmers in Malawi have pooled their knowledge and resources to develop and distribute new vitamin-enriched and drought-resistant sweet potato varieties, and to devise and promote new commercial activities that will help its spread

The ‘Galilean Style in Science’ and the Inconsistency of Linguistic Theorising

Chomsky’s principle of epistemological tolerance says that in theoretical linguistics contradictions between the data and the hypotheses may be temporarily tolerated in order to protect the explanatory power of the theory. The paper raises the following problem: What kinds of contradictions may be tolerated between the data and the hypotheses in theoretical linguistics? First a model of paraconsistent logic is introduced which differentiates between week and strong contradiction. As a second step, a case study is carried out which exemplifies that the principle of epistemological tolerance may be interpreted as the tolerance of week contradiction. The third step of the argumentation focuses on another case study which exemplifies that the principle of epistemological tolerance must not be interpreted as the tolerance of strong contradiction. The reason for the latter insight is the unreliability and the uncertainty of introspective data. From this finding the author draws the conclusion that it is the integration of different data types that may lead to the improvement of current theoretical linguistics and that the integration of different data types requires a novel methodology which, for the time being, is not available

The ‘Galilean Style in Science’ and the Inconsistency of Linguistic Theorising

Chomsky’s principle of epistemological tolerance says that in theoretical linguistics contradictions between the data and the hypotheses may be temporarily tolerated in order to protect the explanatory power of the theory. The paper raises the following problem: What kinds of contradictions may be tolerated between the data and the hypotheses in theoretical linguistics? First a model of paraconsistent logic is introduced which differentiates between week and strong contradiction. As a second step, a case study is carried out which exemplifies that the principle of epistemological tolerance may be interpreted as the tolerance of week contradiction. The third step of the argumentation focuses on another case study which exemplifies that the principle of epistemological tolerance must not be interpreted as the tolerance of strong contradiction. The reason for the latter insight is the unreliability and the uncertainty of introspective data. From this finding the author draws the conclusion that it is the integration of different data types that may lead to the improvement of current theoretical linguistics and that the integration of different data types requires a novel methodology which, for the time being, is not available