On the derived category of quasi-coherent sheaves on an Adams geometric stack

Let X be an Adams geometric stack. We show that D(Aqc(X)), its derived category of quasi-coherent sheaves, satisfies the axioms of a stable homotopy category defined by Hovey, Palmieri and Strickland in [13]. Moreover we show how this structure relates to the derived category of comodules over a Hopf algebroid that determines X.Ministerio de Ciencia e Innovación | Ref. MTM2011-26088Ministerio de Economía y Competitividad | Ref. MTM2014-59456Xunta de Galicia | Ref. GRC2013-04

A functorial formalism for quasi-coherent sheaves on a geometric stack

A geometric stack is a quasi-compact and semi-separated algebraic stack. We prove that the quasi-coherent sheaves on the small flat topology, Cartesian presheaves on the underlying category, and comodules over a Hopf algebroid associated to a presentation of a geometric stack are equivalent categories. As a consequence, we show that the category of quasi-coherent sheaves on a geometric stack is a Grothendieck category. We also associate, in a 2-functorial way, to a 1-morphism of geometric stacks, an adjunction f^∗⊣f_∗ for the corresponding categories of quasi-coherent sheaves that agrees with the classical one defined for schemes. This construction is described both geometrically in terms of the small flat site and algebraically in terms of comodules over the Hopf algebroid.Ministerio de Ciencia e Innovación | Ref. MTM2008-03465Ministerio de Ciencia e Innovación | Ref. MTM2011-26088Xunta de Galicia | Ref. GRC2013-04

Ethnobotany, volatile iols and secretion tissues of Werneria poposa from Argentina

Folk medicines are gaining great importance as information sources on traditional medicinal plants. The aim of this paper is the study of a plant traditionally employed by the Puna inhabitants: Werneria poposa Phil. Morphology of its secretory tissue and other histological diagnostic features, as well as the chemical composition of its essential oil, is described. Puna inhabitants use W. poposa mainly as an infusion for mountain sickness ('soroche'), stomach and hepatic disorders and cold. It is also used externally as a hot bath or unguent for rheumatic pains or traumas. Secretory tissues are schizogenous ducts in leaves and stems. Thirty-one components were detected in the essential oil by means of GC/MS analysis. Oil was characterized by the presence of high content of β-pinene (21.7%), α-pinene (5.5%), terpinen-4-ol (5.3%), α-terpinene (5.2%), β-phellandrene + 1,8-cineole (4.8%), isopulegol (4.8%) and β-citronellal (4.6%). At the present time, W. poposa is consumed as a medicinal plant, mainly in the northwest of Argentina, not being commercialized in the urban centers.Facultad de Ciencias Naturales y Muse

The derived category of quasi-coherent sheaves and axiomatic stable homotopy

We prove in this paper that for a quasi-compact and semi-separated (non necessarily noetherian) scheme X, the derived category of quasi-coherent sheaves over X, D(A_qc(X)), is a stable homotopy category in the sense of Hovey, Palmieri and Strickland, answering a question posed by Strickland. Moreover we show that it is unital and algebraic. We also prove that for a noetherian semi-separated formal scheme X, its derived category of sheaves of modules with quasi-coherent torsion homologies D_qct(X) is a stable homotopy category. It is algebraic but if the formal scheme is not a usual scheme, it is not unital, therefore its abstract nature differs essentially from that of the derived category of a usual scheme.Comment: v2: 31 pages, some improvements in exposition; v3 updated bibliography, to appear Adv. Mat

Una variedad blanca (Vitis vinifera L.) de alto interés comercial, y en vías de extinción. Sinonimias y homonimias

Comunicación presentada al X Congreso Nacional de Ciencias Hortícolas, celebrado en Pontevedra en mayo de 2003.Peer reviewe

Molecular characterization and heterologous expression of a Xanthophyllomyces dendrorhous ¿-glucosidase with potential for prebiotics production

Abstract Basidiomycetous yeast Xanthophyllomyces dendrorhous expresses an α-glucosidase with strong transglycosylation activity producing prebiotic sugars such as panose and an unusual tetrasaccharides mixture including α–(1–6) bonds as major products, which makes it of biotechnological interest. Initial analysis pointed to a homodimeric protein of 60 kDa subunit as responsible for this activity. In this study, the gene Xd-AlphaGlu was characterized. The 4131-bp-long gene is interrupted by 13 short introns and encodes a protein of 990 amino acids (Xd-AlphaGlu). The N-terminal sequence of the previously detected 60 kDa protein resides in this larger protein at residues 583–602. Functionality of the gene was proved in Saccharomyces cerevisiae, which produced a protein of about 130 kDa containing Xd-AlphaGlu sequences. All properties of the heterologously expressed protein, including thermal and pH profiles, activity on different substrates, and ability to produce prebiotic sugars were similar to that of the α-glucosidase produced in X. dendrorhous. No activity was detected in S. cerevisiae containing exclusively the 1256-bp from gene Xd-AlphaGlu that would encode synthesis of the 60 kDa protein previously detected. Data were compatible with an active monomeric α-glucosidase of 990 amino acids and an inactive hydrolysis product of 60 kDa. Protein Xd-AlphaGlu contained most of the elements characteristic of α-glucosidases included in the glycoside hydrolases family GH31 and its structural model based on the homologous human maltase-lucoamylase was obtained. Remarkably, the Xd-AlphaGlu C-terminal domain presents an unusually long 115-residue insertion that could be involved in this enzyme’s activity against long-size substrates such as maltoheptaose and soluble starch.Spanish Ministry of Economy and Competitiveness supported this research. We thank Fundación Ramón Areces for the institutional grant to the Centro de Biología Molecular Severo OchoaPeer Reviewe

Synthesis of tetranuclear rhodium and iridium complexes directed by 6-mercaptopyridin-2-ol: Electrochemical behavior, chemical oxidation, and coordination chemistry

The new ligand 6-mercapto-2(1 H)-pyridone (H2PySO) has been prepared in good yield by reaction of 6-chloro-pyridin-2-ol with NaSH. Reaction of the salt K2PySO, generated in situ, with the appropriate complex [M(μ-C1)(diolefin)]2affords the tetranuclear complexes [M 4(μ-PySO)2(diolefin)4] [M = Rh, diolefin = 1,5-cyclooctadiene (cod) (1), tetrafluorobenzobarralene (tfbb) (2); M = lr, diolefin = cod (3)]. The molecular structure of complex 1 has been determined by X-ray diffraction methods. The tetranuclear structure is supported by two S, N, Otridentate ligands exhibiting a 1κO, 2κN, 3:4κ2 S coordination mode. Carbonylation of the rhodium diolefin complexes at atmospheric pressure gives [Rh4(μ-PyS0)2(C0)8] (4). The carbonylation of 1 is partially reversible, and the mixed-ligand complex [Rh4(μ-PySO)2(cod)2(CO)4] (5) has been obtained as a single isomer. The reaction of 4 with triphenylphosphine gives the compound [Rh4(μ-PySO)2(CO)4(PPh 3)4] (6) which also exists as a single isomer of C 2 symmetry. The diolefin complexes are redox active and exhibit two one-electron oxidations at a platinum disk electrode in dichloromethane separated by approximately 0.5 V at potentials accessible by chemical oxidants. The tetranuclear complexes were selectively oxidized to the 63-electron mixed-valence cationic complexes [M4(μ-PySO)2(diolefin) 4]+(1a+, 2+, and 3+) by using AgCF3SO3 as oxidant and isolated as the triflate salts. Alternatively, the oxidation with [Cp2Fe]PF6 gives [Rh4(μ-PySO)2(cod)4][PF6] (1b+). The parameters obtained from the simulation of the electron paramagnetic resonance spectra of the oxidized species strongly suggest that the unpaired electron is delocalized over only two metal atoms in the complexes.The financial support from Ministerio de Educación y Ciencia (MEC/FEDER) Project CTQ2006-03973/BQU and Grant CSD2006-0015 Consolider Ingenio 2010 is gratefully acknowledged.Peer Reviewe

Stretching the design: extending analytical circuit design from the linear to the nonlinear domain

In the design of most electronic circuits and systems, designers use computer-aided design (CAD) tools to guide the design flow. They exploit the ability of CAD tools to perform algebraic operations to compute/ predict circuit and system performance. This is possible because, in most electronic circuits and systems, linear operation can be assumed. The behavior of microwave components, circuits, and systems can, for example, be described in terms of "behavioral" parameters, such as Z-parameters, Y-parameters, and S-parameters. Transformation from one parameter to another is achieved by simple linear algebraic operations [1]. The performance of more complex circuits can be computed via linear matrix operations using the relevant parameters, i.e., Y-parameters for parallel connections and Z-parameters for series connections. More significantly, performance predictions can also be obtained via linear algebra transformations, i.e., the maximum gain, minimum noise figure, potential instability, etc., along with design insight, i.e., gain circles, noise circles, optimum input/output match requirements, and so on [1], [2].Ministerio de Ciencia e Innovación | Ref. TEC2011-29264-C03-03Ministerio de Ciencia e Innovación | Ref. TEC2011-28683-C02-0

Application of mixed reality to ultrasound-guided femoral arterial cannulation during real-time practice in cardiac interventions

Producción CientíficaMixed reality opens interesting possibilities as it allows physicians to interact with both, the real physical and the virtual computer-generated environment and objects, in a powerful way. A mixed reality system, based in the HoloLens 2 glasses, has been developed to assist cardiologists in a quite complex interventional procedure: the ultrasound-guided femoral arterial cannulations, during real-time practice in interventional cardiology. The system is divided into two modules, the transmitter module, responsible for sending medical images to HoloLens 2 glasses, and the receiver module, hosted in the HoloLens 2, which renders those medical images, allowing the practitioner to watch and manage them in a 3D environment. The system has been successfully used, between November 2021 and August 2022, in up to 9 interventions by 2 different practitioners, in a large public hospital in central Spain. The practitioners using the system confirmed it as easy to use, reliable, real-time, reachable, and cost-effective, allowing a reduction of operating times, a better control of typical errors associated to the interventional procedure, and opening the possibility to use the medical imagery produced in ubiquitous e-learning. These strengths and opportunities were only nuanced by the risk of potential medical complications emerging from system malfunction or operator errors when using the system (e.g., unexpected momentary lag). In summary, the proposed system can be taken as a realistic proof of concept of how mixed reality technologies can support practitioners when performing interventional and surgical procedures during real-time daily practice.Junta de Castilla y León - Gerencia Regional de Salud (SACyL) (grant number GRS 2275/A/2020)Instituto de Salud Carlos III (grant number DTS21/00158)Publicación en abierto financiada por el Consorcio de Bibliotecas Universitarias de Castilla y León (BUCLE), con cargo al Programa Operativo 2014ES16RFOP009 FEDER 2014-2020 DE CASTILLA Y LEÓN, Actuación:20007-CL - Apoyo Consorcio BUCL

Turning light into a liquid via atomic coherence

We study a four level atomic system with electromagnetically induced transparency with giant $\chi^{(3)}$ and $\chi^{(5)}$ susceptibilities of opposite signs. This system would allow to obtain multidimensional solitons and light condensates with surface tension properties analogous to those of usual liquids