Chemical composition of phytoplankton and Particulate Organic Matter in the Ría de Vigo (NW Spain)

15 pages, 2 figures, 7 tables.Elemental (C, H, O, N, Si, P) and biochemical composition (proteins, carbohydrates, lipids, phosphorus compounds, chlorophyll and opal) in particulate organic matter, diatoms, other autotrophs, heterotrophs and detritus from natural plankton were established simultaneously by measuring relatively few components. Using standard techniques in marine chemistry on board ship, it is possible to infer a great deal about the composition and condition of the plankton. In addition, the organic matter content in terms of cell volume was determined for each group of plankton. Variation of chemical composition with depth was also considered. The ratio carbohydrates/lipids (Cbh/Lip) was used as an indicator of the chemical quality of the plankton.This paper was supported by the Consellería de Educación of the Xunta de Galicia and Comisión Interministerial de Ciencia y Tecnología (CICYT) Grant No. MAR88-245.Peer reviewe

Diseño, fundamentación y validación de un programa virtual colaborativo en educación ambiental

Los programas colaborativos constituyen una adecuada herramienta para hacer Educación Ambiental. A lo largo del texto fundamentamos el modelo didáctico MACELEA que ha servido para la creación y puesta en marcha del programa colaborativo virtual de innovación curricular Ecourban. Describimos los aspectos más relevantes para su diseño e implementación, y damos cuenta de los criterios de validez y componentes de innovación virtual que lo sustentan: contextual, pedagógico-didáctica, epistemológica, multimedia, cognitiva y comunicacional.Collaborative programmes are an appropriate tool for Environmental Education. In this work we show the foundations of the didactic model, that we have named MACELEA and which has served for the implementation of a virtual collaborative program to promote the curricular innovation: Ecourban. Here we describe the most relevant dimensions of its design and development, so as the validity criteria and components of virtual innovation: contextual, pedagogical-didactic, epistemological, multimedia, cognitive and communicative

Caracterización química y cuantificación del rendimiento de extracción de pigmento en siete accesiones mexicanas de Bixa orellana

Achiote (Bixa orellana) is a plant used for obtaining a natural dye rich on carotenoids (mainly bixin and norbixin); it is also the plant species with the highest content of tocotrienols in nature. In the present work, the pigment extraction yield of seven Mexican accessions of Bixa orellana was quantified. Also color parameters and content of tocotrienols, tocopherols, norbixin, bixin, total phenolic compounds and antioxidant capacity were evaluated in the corresponding annatto extracts. The highest percentage of pigment extraction yield was obtained with KOH (4.84%). Accessions 43 (L*= 4.01 ± 0.79, C*= 7.33 ± 1.07, h= 25.76 ± 6.35) and 50 (L*= 3.17 ± 0.64, C*= 6.81 ± 0.53, h= 26.41 ± 4.41) had the lowest color values, meaning these accessions had a darker and redder color. Four accessions showed the highest content of bixin: accession 48 (3.1%), 45 (2.6%) 43 (2.4%) and 47 (2.2%). Accession 50 had showed the highest content of total phenolic compounds and of tocotrienols (T3), mainly the isoform δ-T3 (5.03 ± 0.64 mg g−1 Seed Dry Weight), as well as the highest antioxidant capacity.El achiote (Bixa orellana) es una planta utilizada para obtener un colorante natural rico en carotenoides (principalmente bixina y norbixina); además, es la especie vegetal con el mayor contenido de tocotrienoles. En este trabajo, se determinó el rendimiento de extracción de pigmento de siete accesiones mexicanas de Bixa orellana. También se evaluaron los parámetros de color y el contenido de tocotrienoles, tocoferoles, norbixina, bixina, compuestos fenólicos totales y la capacidad antioxidante en extractos de annato. El mayor porcentaje de rendimiento de extracción de pigmento fue obtenido con KOH (4.847905%). Las accesiones 43 (L*= 4.01 ± 0.79, C*= 7.33 ± 1.07, h= 25.76 ± 6.35) y 50 (L*= 3.17 ± 0.64, C*= 6.81 ± 0.53, h= 26.41 ± 4.41) presentaron los valores más bajos de los párametros de color, lo que significa que estas accesiones tuvieron un color más oscuro y más rojo. Cuatro accesiones mostraron el mayor contenido de bixina: accesión 48 (3.1%), 45 (2.6%) 43 (2.4%) and 47 (2.2%). La accession 50 mostró el mayor contenido de compuestos fenólicos totales y de tocotrienoles (T3), principalmente la isoforma δ-T3 (5.03 ± 0.64 mg g-1 Peso Seco), así como también la mayor capacidad antioxidante.Fil: Raddatz Mota, D.. Universidad Autónoma Metropolitana; MéxicoFil: Pérez Flores, L. J.. Universidad Autónoma Metropolitana; MéxicoFil: Carrari, Fernando Oscar. Instituto Nacional de Tecnología Agropecuaria. Centro de Investigación en Ciencias Veterinarias y Agronómicas. Instituto de Biotecnología; ArgentinaFil: Insani, Ester Marina. Instituto Nacional de Tecnología Agropecuaria. Centro de Investigación en Ciencias Veterinarias y Agronómicas. Instituto de Biotecnología; ArgentinaFil: Asis, Ramón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Centro de Investigaciones en Bioquímica Clínica e Inmunología; ArgentinaFil: Mendoza Espinoza, J. A.. Universidad Nacional Autónoma de México; MéxicoFil: Díaz de León Sánchez, F.. Universidad Autónoma Metropolitana; MéxicoFil: Rivera Cabrera, F.. Universidad Autónoma Metropolitana; Méxic

Recycled hybrid material for use as shielding in operations with ionizing radiation

One of the most efficient measures to prevent gamma radiation is shielding, which can take the form of protection barriers, storage containers, wall coating, bunkers, or many others aimed at minimizing the exposure of people to radiation. The materials used to this end have not changed much since the invention of X-rays, when materials with high attenuation capacity were employed, such as lead, tungsten, or concrete. These are all high-density materials and, therefore, also very heavy, and some of them are expensive and not environmentally friendly, as they do not have many possibilities with regards to their recycling. Circular economy provides an opportunity to reintroduce subproducts and waste in the same production processes that generated them or as raw matters in others. The use of sustainable materials is one of these options; however, there is little research in the field of radiation protection about the use of recycled material to this end, and there are few alternative sustainable options different from conventional materials that show similar behaviour. In our study, we have designed and built shielded panels called Mixlead® for gammagraphy, made of 100 % recyclable materials with sandwich structures combining polymeric fractions of electric cables and lead-alloy protection sheets used in the packaging of radiographic plates. With a methodology combining shielding calculations and a series of thermomechanical-radiological tests, it was possible to accurately determine the thickness of Mixlead® necessary to perform the tests with security guarantees and meeting sustainability requirements for radioactive sources of Iridium (192Ir) and Selenium (75Se), the use of the former being predominant, with an average activity of 1 GBq. In order to reduce this activity 2 and 10 times, the necessary thickness would be 24 and 79 mm respectively, which represents 3 or 4 layers of Mixlead® material.15 página

Arrested dynamics of the dipolar hard-sphere model

We report the combined results of molecular dynamics simulations and theoretical calculations concerning various dynamical arrest transitions in a model system representing a dipolar fluid, namely, N (softcore) rigid spheres interacting through a truncated dipole-dipole potential. By exploring different regimes of concentration and temperature, we find three distinct scenarios for the slowing down of the dynamics of the translational and orientational degrees of freedom: At low ({$\eta$} = 0.2) and intermediate (${\eta}$ = 0.4) volume fractions, both dynamics are strongly coupled and become simultaneously arrested upon cooling. At high concentrations ({$\eta$} $\lt$ 0.6), the translational dynamics shows the features of an ordinary glass transition, either by compressing or cooling down the system, but with the orientations remaining ergodic, thus indicating the existence of partially arrested states. In this density regime, but at lower temperatures, the relaxation of the orientational dynamics also freezes. The physical scenario provided by the simulations is discussed and compared against results obtained with the self-consistent generalized Langevin equation theory, and both provide a consistent description of the dynamical arrest transitions in the system. Our results are summarized in an arrested states diagram which qualitatively organizes the simulation data and provides a generic picture of the glass transitions of a dipolar fluid

Banks’ Net Interest Margin in the 2000s: A Macro-Accounting International Perspective

This paper re-examines the determinants of Net Interest Margin (NIM) in the banking industries of 15 developed and emerging economies. It presents three main contributions with respect to previous studies: first, we analyze the determinants of NIM in the years leading to the 2008 financial crisis; second, we account for the role of different accounting standards across countries; third, we use multi-way cluster estimation methodologies which control for cross-sectional and time-series dependence in macroeconomic and banking variables. We find that the introduction of International Financial Reporting Standards (IFRSs) contributed to lower NIM variations unexplained by standard accounting variables. Interest rate volatility is found to be positively and strongly related to NIM dynamics, whereas inflation risk is often found to be a relevant driver of NIM crosscountry differences

Selección de variables en la predicción de llamadas en un centro de atención telefónica

En este artículo se ilustra la importancia de la selección de variables independientes para modelos neuronales destinados a la predicción de la demanda en un centro de atención telefónica. Los modelos tienen como objetivo ayudar en la planificación semanal del personal del centro, tarea que se realiza con 14 días de antelación. Los modelos requeridos pueden hacer uso de gran cantidad de variables independientes. Sin embargo, el número de casos que pueden ser usados para obtener los parámetros del modelo es escaso debido a los cambios socio-económicos. Esto plantea la necesidad de seleccionar cuidadosamente las variables independientes y utilizar el menor número posible de ellas, de otro modo la generalización del modelo se degradaría. Para resolver el problema se utiliza un método mixto que permite trabajar con un alto número de variables candidatas, en una primera fase, y seleccionar más cuidadosamente un número menor de variables en una segunda fase. Los resultados obtenidos por los modelos resultantes de aplicar el método propuesto y sus variantes son analizados utilizando datos reales de un centro de atención telefónica. Los resultados de la comparación muestran que la correcta selección de variables independientes es vital para este tipo de aplicación.Unión Europea HYCON FP6-511368

Wannier-Bloch approach to localization in high harmonics generation in solids

Emission of high-order harmonics from solids provides a new avenue in attosecond science. On one hand, it allows to investigate fundamental processes of the non-linear response of electrons driven by a strong laser pulse in a periodic crystal lattice. On the other hand, it opens new paths toward efficient attosecond pulse generation, novel imaging of electronic wave functions, and enhancement of high-order harmonic generation (HHG) intensity. A key feature of HHG in a solid (as compared to the well-understood phenomena of HHG in an atomic gas) is the delocalization of the process, whereby an electron ionized from one site in the periodic lattice may recombine with any other. Here, we develop an analytic model, based on the localized Wannier wave functions in the valence band and delocalized Bloch functions in the conduction band. This Wannier-Bloch approach assesses the contributions of individual lattice sites to the HHG process, and hence addresses precisely the question of localization of harmonic emission in solids. We apply this model to investigate HHG in a ZnO crystal for two different orientations, corresponding to wider and narrower valence and conduction bands, respectively. Interestingly, for narrower bands, the HHG process shows significant localization, similar to harmonic generation in atoms. For all cases, the delocalized contributions to HHG emission are highest near the band-gap energy. Our results pave the way to controlling localized contributions to HHG in a solid crystal, with hard to overestimate implications for the emerging area of atto-nanoscience

Time Series

This paper first shows that survey-based expectations (SBE) outperform standard time series models in U.S. quarterly inflation out-of-sample prediction and that the term structure of survey-based inflation forecasts has predictive power over the path of future inflation changes. It then proposes some empirical explanations for the forecasting success of survey-based inflation expectations. We show that SBE pool a large amount of heterogeneous information on inflation expectations and react more flexibly and accurately to macro conditions both contemporaneously and dynamically. We illustrate the flexibility of SBE forecasts in the context of the recent financial crisis