The mathematical stability study for the system of the CoO(OH) – overoxidized polypyrrole composite synthesis in the presence of fluor ions

The potentiostatic synthesis of CoO(OH) – Overoxidized polypyrrole composite in the presence of fluor ions has been investigated mathematically. The corresponding mathematical model was described and analyzed by means of linear stability theory and bifurcation analysis. The steady-state stability requirements, like also oscillatory and monotonic instability conditions are derived.Mongolian Journal of Chemistry 16 (42), 2015, 13-1

O impacto da revascularização carotídea sobre a função cognitiva

The concept that carotid disease may compromise cognitive function was initially proposed by Fisher in 1951, based on an autopsy case. However, some topics involving cognitive function remain controversial, such as its correlation with carotid obstructive disease. So, the authors of this review evaluate the impact of carotid revascularization on cognitive function and the repercussions of the revascularization technique (carotid stenting vs. endarterectomy) chosen. It was clear from the literature reviewed that carotid stenosis is related to a decline in cognitive function over time. However, controversy still remains over the impact of carotid revascularization on cognitive function. With elation to the technique employed (carotid stenting vs. endarterectomy), the majority of studies found no difference between the two techniques in terms of overall cognitive outcome.The concept that carotid disease may compromise cognitive function was initially proposed by Fisher in 1951, based on an autopsy case. However, some topics involving cognitive function remain controversial, such as its correlation with carotid obstructive132116122sem informaçãosem informaçãoLal, B.K., Cognitive function after carotid artery revascularization (2007) Vasc Endovasc Surg, 41 (1), pp. 5-13. , http://dx.doi.org/10.1177/1538574406297253, PMid:17277237Fisher, C., Senile dementia - A new explanation of its causation (1951) Arch Neurol, 65, pp. 1-7Carrea, R., Molins, M., Murphy, G., Surgery of spontaneous thrombosis of internal carotid in the neckcarotid-carotid anastomosiscase report and analysis of the literature on surgical cases (1955) Medicina (B. Aires), 15, pp. 20-29Debakey, M.E., Successful carotid endarterectomy for cerebrovascular insufficiency. Nineteen-year follow-up (1975) JAMA, 233, pp. 1083-1085. , http://dx.doi.org/10.1001/jama.1975.03260100053020, PMid:1174155Eastcott, H.H., Pickering, G.W., Rob, C.G., Reconstruction of internal carotid artery in a patient with intermittent attacks of hemiplegia (1954) Lancet, 267, pp. 994-996. , http://dx.doi.org/10.1016/S0140-6736(54)90544-9Feliziani, F.T., Polidori, M.C., De Rango, P., Cognitive performance in elderly patients undergoing carotid endarterectomy or carotid artery stenting: A twelve-month follow-up study (2010) Cerebrovasc Dis, 30, pp. 244-251. , http://dx.doi.org/10.1159/000319066, PMid:20664257Seshadri, S., Beiser, A., Kelly-Hayes, M., The lifetime risk of stroke: Estimates from the Framingham study (2006) Stroke, 37, pp. 345-350. , http://dx.doi.org/10.1161/01.STR.0000199613.38911.b2, PMid:16397184Hachinski, V., The 2005 Thomas Willis lecture: Stroke and vascular cognitive impairment - A transdisciplinary, translational and transactional approach (2007) Stroke, 38, p. 1396. , http://dx.doi.org/10.1161/01.STR.0000260101.08944.e9, PMid:17347469Desmond, D.W., Moroney, J.T., Sano, M., Stern, Y., Incidence of dementia after ischemic stroke: Results of a longitudinal study (2002) Stroke, 33, pp. 2254-2260. , http://dx.doi.org/10.1161/01.STR.0000028235.91778.95, PMid:12215596Rao, S.M., Leo, G.J., Ellington, L., Nauertz, T., Bernardin, L., Unverzagt, F., Cognitive dysfunction in multiple sclerosis. II. 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Frequency, time of occurrence, and association with patient and surgical characteristics (1997) Stroke, 28, pp. 1988-1992. , http://dx.doi.org/10.1161/01.STR.28.10.1988, PMid:9341708Braekken, S.K., Endresen, K., Russell, D., Brucher, R., Kjekshus, J., Influence of guidewire and catheter type on the frequency of cerebral microembolic signals during left heart catheterization (1998) Am J Cardiol, 82, pp. 632-637. , http://dx.doi.org/10.1016/S0002-9149(98)00407-XBraekken, S.K., Reinvang, I., Russell, D., Brucher, R., Svennevig, J.L., Association between intraoperative cerebral microembolic signals and postoperative neuropsychological deficit: Comparison between patients with cardiac valve replacement and patients with coronary artery bypass grafting (1998) J Neurol Neurosurg Psychiatry, 65, pp. 573-576. , http://dx.doi.org/10.1136/jnnp.65.4.573, PMid:9771790Sylivris, S., Levi, C., Matalanis, G., Pattern and significance of cerebral microemboli during coronary artery bypass grafting (1998) Ann Thorac Surg, 66, pp. 1674-1678. , http://dx.doi.org/10.1016/S0003-4975(98)00891-1Laza, C., Popescu, B.O., Popa, M., Microemboli detection in patients with carotid artery stenting--a potential marker for future cognitive impairment? (2013) J Neurol Sci, 326 (1-2), pp. 96-99. , http://dx.doi.org/10.1016/j.jns.2013.01.025, PMid:23403326Crawley, F., Stygall, J., Lunn, S., Harrison, M., Brown, M.M., Newman, S., Comparison of microembolism detected by transcranial Doppler and neuropsychological sequelae of carotid surgery and percutaneous transluminal angioplasty (2000) Stroke, 31, pp. 1329-1334. , http://dx.doi.org/10.1161/01.STR.31.6.1329, PMid:10835452Jordan, W.D., Jr., Voellinger, D.C., Doblar, D.D., Plyushcheva, N.P., Fisher, W.S., McDowell, H.A., Microemboli detected by transcranial Doppler monitoring in patients during carotid angioplasty versus carotid endarterectomy (1999) Cardiovasc Surg, 7, pp. 33-38. , http://dx.doi.org/10.1016/S0967-2109(98)00097-0Wolf, O., Heider, P., Heinz, M., Microembolic signals detected by transcranial doppler sonography during carotid endarterectomy and correlation with serial diffusionweighted imaging (2004) Stroke, 35, pp. e373-e375. , http://dx.doi.org/10.1161/01.STR.0000143184.69343.ec, PMid:15388901Ghogawala, Z., Westerveld, M., Amin-Hanjani, S., Cognitive outcomes after carotid revascularization: The role of cerebral emboli and hypoperfusion (2008) Neurosurg, pp. 385-395. , PMid:18382316Ringelstein, E.B., Droste, D.W., Babikian, V.L., Consensus on microembolus detection by TCD. International Consensus Group on Microembolus Detection (1998) Stroke, 29, pp. 725-729. , http://dx.doi.org/10.1161/01.STR.29.3.725, PMid:9506619Gaunt, M.E., Smith, J.L., Bell, P.R., Martin, P.J., Naylor, A.R., Microembolism and hemodynamic changes in the brain during carotid endarterectomy (1994) Stroke, 25, pp. 2504-2505. , http://dx.doi.org/10.1161/01.STR.25.12.2504, PMid:7974598Chen, C.I., Iguchi, Y., Garami, Z., Analysis of emboli during carotid stenting with distal protection device (2006) Cerebrovasc Dis, 21, pp. 223-228. , http://dx.doi.org/10.1159/000091218, PMid:16446534Gupta, N., Corriere, M.A., Dodson, T.F., The incidence of microemboli to the brain is less with endarterectomy than percutaneous revascularization with distal filters or flow reversal (2011) J Vasc Surg, 53, pp. 316-322. , http://dx.doi.org/10.1016/j.jvs.2010.08.063, PMid:21129899Capoccia, L., Speziale, F., Gazzetti, M., Comparative study on carotid revascularization(endarterectomy vs stenting) using markers of cellular brain injury, neuropychometric tests, and diffusion-weighted magnetic resonance imaging (2010) J Vasc Surg, 51, pp. 584-592. , http://dx.doi.org/10.1016/j.jvs.2009.10.079, PMid:20045614Roh, H.G., Byun, H.S., Ryoo, J.W., Prospective analysis of cerebral infarction after carotid endarterectomy and carotid artery stent placement by using diffusion-weighted imaging (2005) Am J Neuroradiol, 26, pp. 376-384. , PMid:15709140Rapp, J.H., Wakil, L., Sawhney, R., Subclinical embolization after carotid artery stenting:New lesions on diffusion-weighted magnetic resonance imaging occur postprocedure (2007) J Vasc Surg, 45, pp. 867-874. , http://dx.doi.org/10.1016/j.jvs.2006.12.058, PMid:17376643Hauth, E.A., Jansen, C., Drescher, R., MR and clinical follow-up of diffusion-weighted cerebral lesions after carotid artery stenting (2005) Am J Neuroradiol, 26, pp. 2336-2344. , PMid:16219842Fearn, S.J., Pole, R., Wesnes, K., Faragher, E.B., Hooper, T.L., McCollum, C.N., Cerebral injury during cardiopulmonary bypass: Emboli impair memory (2001) J Thorac Cardiovasc Surg, 121, pp. 1150-1160. , http://dx.doi.org/10.1067/mtc.2001.114099, PMid:11385383Sasoh, M., Ogasawara, K., Kuroda, K., Effects of EC-IC bypass surgery on cognitive impairment in patients with hemodynamic cerebral ischemia (2003) Surg Neurol, 59, pp. 455-460. , discussion 460-453Younkin, D., Hungerbuhler, J.P., O’connor, M., Superficial temporal-middle cerebral artery anastomosis: Effects on vascular, neurologic, and neuropsychological functions (1985) Neurology, 35, pp. 462-469. , http://dx.doi.org/10.1212/WNL.35.4.462, PMid:3982632Marshall, R.S., Lazar, R.M., Pile-Spellman, J., Recovery of brain function during induced cerebral hypoperfusion (2001) Brain, 124, pp. 1208-1217. , http://dx.doi.org/10.1093/brain/124.6.1208, PMid:11353736Borroni, B., Tiberio, G., Bonardelli, S., Is mild vascular cognitive impairment reversible? Evidence from a study on the effect of carotid endarterectomy (2004) Neurol Res, 26, pp. 594-597. , http://dx.doi.org/10.1179/016164104225016245, PMid:15265280Costin, M., Rampersad, A., Solomon, R.A., Connolly, E.S., Heyer, E.J., Cerebral injury predicted by transcranial Doppler ultrasonography but not electroencephalography during carotid endarterectomy (2002) J Neurosurg Anesthesiol, 14, pp. 287-292. , http://dx.doi.org/10.1097/00008506-200210000-00003, PMid:12357085 PMCid:PMC2435244Heyer, E.J., Adams, D.C., Solomon, R.A., Neuropsychometric changes in patients after carotid endarterectomy (1998) Stroke, 29, pp. 1110-1115. , http://dx.doi.org/10.1161/01.STR.29.6.1110, PMid:9626280 PMCid:PMC2435204Ogasawara, K., Inoue, T., Kobayashi, M., Cognitive impairment associated with intraoperative and postoperative hypoperfusion without neurologic deficits in a patient undergoing carotid endarterectomy (2006) Surg Neurol, 65, pp. 577-581. , http://dx.doi.org/10.1016/j.surneu.2005.07.011, PMid:16720178Lund, C., Hol, P.K., Lundblad, R., Comparison of cerebral embolization during off-pump and on-pump coronary artery bypass surgery (2003) Ann Thorac Surg, 76, pp. 765-770. , http://dx.doi.org/10.1016/S0003-4975(03)00679-9, discussion 770Sundt, T.M., Sharbrough, F.W., Piepgras, D.G., Kearns, T.P., Messick, J.M., O’Fallon, W.M., Correlation of cerebral blood flow and electroencephalographic changes during carotid endarterectomy: With results of surgery and hemodynamics of cerebral ischemia (1981) Mayo Clin Proc, 56, pp. 533-543. , PMid:7266064Halsey, J.H., Risks and benefits of shunting in carotid endarterectomy. The International Transcranial Doppler Collaborators (1992) Stroke, 23, pp. 1583-1587. , http://dx.doi.org/10.1161/01.STR.23.11.1583Lawrence, P.F., Alves, J.C., Jicha, D., Bhirangi, K., Dobrin, P.B., Incidence, timing, and causes of cerebral ischemia during carotid endarterectomy with regional anesthesia (1998) J Vasc Surg, 27, pp. 329-337. , http://dx.doi.org/10.1016/S0741-5214(98)70363-5Calderon-Arnulphi, M., Alaraj, A., Amin-Hanjani, S., Detection of cerebral ischemia in neurovascular surgery using quantitative frequency-domain near-infrared spectroscopy (2007) J Neurosurg, 106, pp. 283-290. , http://dx.doi.org/10.3171/jns.2007.106.2.283, PMid:17410713White, P.F., Use of cerebral monitoring during anaesthesia. Effect on recovery profile (2006) Best Pract Res Clin Anaesthesiol, 20, pp. 181-189. , http://dx.doi.org/10.1016/j.bpa.2005.08.001, PMid:16634424Mendelsohn, F.O., Weissman, N.J., Lederman, R.J., Acute hemodynamic changes during carotid artery stenting (1998) Am J Cardiol, 82, pp. 1077-1081. , http://dx.doi.org/10.1016/S0002-9149(98)00562-1Trocciola, S.M., Chaer, R.A., Lin, S.C., Analysis of parameters associated with hypotension requiring vasopressor support after carotid angioplasty and stenting (2006) J Vasc Surg, 43, p. 714. , http://dx.doi.org/10.1016/j.jvs.2005.12.008, PMid:16616226Gupta, R., Abou-Chebl, A., Bajzer, C.T., Schumacher, H.C., Yadav, J.S., Rate, predictors, and consequences of hemodynamic depression after carotid artery stenting (2006) J Am Coll Cardiol, 47, pp. 1538-1543. , http://dx.doi.org/10.1016/j.jacc.2005.08.079, PMid:16630988Park, B., Shapiro, D., Dahn, M., Arici, M., Carotid artery angioplasty with stenting and postprocedure hypotension (2005) Am J Surg, 190, pp. 691-695. , http://dx.doi.org/10.1016/j.amjsurg.2005.07.004, PMid:16226941Connolly, E.S., Winfree, C.J., Rampersad, A., Serum S100B protein levels are correlated with subclinical neurocognitive declines after carotid endarterectomy (2001) Neurosurg, 49, pp. 1076-1083Lunn, S., Crawley, F., Harrison, M.J., Brown, M.M., Newman, S.P., Impact of carotid endarterectomy upon cognitive functioning. A systematic review of the literature (1999) Cerebrovasc Dis, 9, pp. 74-81. , http://dx.doi.org/10.1159/000015901, PMid:9973649Irvine, C.D., Gardner, F.V., Davies, A.H., Lamont, P.M., Cognitive testing in patients undergoing carotid endarterectomy (1998) Eur J Vasc Endovasc Surg, 15, pp. 195-204. , http://dx.doi.org/10.1016/S1078-5884(98)80176-7Heyer, E.J., Sharma, R., Rampersad, A., A controlled prospective study of neuropsychological dysfunction following carotid endarterectomy (2002) Arch Neurol, 59, pp. 217-222. , http://dx.doi.org/10.1001/archneur.59.2.217, PMid:11843692 PMCid:PMC2435245Hobson, R.W., Update on the Carotid Revascularization Endarterectomy versus Stent Trial (CREST) protocol (2002) J Am Coll Surg, 194 (1), pp. S9-14. , http://dx.doi.org/10.1016/S1072-7515(01)01078-XXu, G., Liu, X., Meyer, J.S., Yin, Q., Zhang, R., Cognitive performance after carotid angioplasty and stenting with brain protection devices (2007) Neurol Res, 29, pp. 251-255. , http://dx.doi.org/10.1179/016164107X159216, PMid:17178010Endovascular versus surgical treatment in patients with carotid stenosis in the Carotid and Vertebral Artery Transluminal Angioplasty Study (CAVATAS):A randomised trial (2001) Lancet, 357, pp. 1729-1737. , http://dx.doi.org/10.1016/S0140-6736(00)04893-5, No authors listedGrunwald, I., Suppurian, T., Struffert, T., Falkai, P., Krick, C., Politi, M., Cognitive Changes after Carotid Artery Stenting (2006) Neuroradiology, 48, pp. 319-323. , http://dx.doi.org/10.1007/s00234-006-0064-5, PMid:16703361Mlekusch, W., Mlekusch, I., Haumer, M., Kopp, C.W., Lehrner, J., Ahmadi, R., Improvement of neurocognitive function after protected carotid artery stenting (2008) Catheter Cardiovasc Interv, 71 (1), pp. 114-119. , http://dx.doi.org/10.1002/ccd.21407, PMid:18098213Gaudet, J.G., Meyers, P.M., McKinsey, J.F., Incidence of moderate to severe cognitive dysfunction in patients treated with carotid artery stenting (2009) Neurosurgery, 65 (2), pp. 325-329. , http://dx.doi.org/10.1227/01.NEU.0000349920.69637.78, discussion 329-30, PMid:19625912 PMCid:PMC2716040Lal, B.K., Younes, M., Cruz, G., Kapadia, I., Jamil, Z., Pappas, P.J., Cognitive changes after surgery vs stenting for carotid artery stenosis (2011) J Vasc Surg, 54 (3), pp. 691-698. , http://dx.doi.org/10.1016/j.jvs.2011.03.253, PMid:21700413Takaiwa, A., Hayashi, N., Kuwayama, N., Akioka, N., Kubo, M., Endo, S., Changes in cognitive function during the 1-year period following endarterectomy and stenting of patients with high-grade carotid artery stenosis (2009) Acta Neurochir, 151, pp. 1593-1600. , http://dx.doi.org/10.1007/s00701-009-0420-4, PMid:19533017Zhou, W., Hitchner, E., Gillis, K., Prospective neurocognitive evaluation of patients undergoing carotid interventions (2012) J Vasc Surg, 56 (6), pp. 1571-1578. , http://dx.doi.org/10.1016/j.jvs.2012.05.092, PMid:22889720 PMCid:PMC3508143Altinbas, A., Van Zandvoort, M.J., Van Den Berg, E., Cognition after carotid endarterectomy or stenting: A randomized comparison (2011) Neurology, 77 (11), pp. 1084-1090. , http://dx.doi.org/10.1212/WNL.0b013e31822e55b9, PMid:21880992Witt, K., Börsch, K., Daniels, C., Neuropsychological consequences of endarterectomy and endovascular angioplasty with stent placement for treatment of symptomatic carotid stenosis: A prospective randomised study (2007) J Neurol, 254 (11), pp. 1524-1532. , http://dx.doi.org/10.1007/s00415-007-0576-x, PMid:17657403A noção de que a doença carotídea pode comprometer a função cognitiva foi proposta inicialmente por Fisher, em 1951, baseado em um caso de necropsia. Porém, alguns tópicos envolvendo a função cognitiva permanecem controversos, tais como sua correlação

Development of molecular biology techniques for the detection of genetically modified organisms in maize food products

In the last years, the increase in the cultivated area of genetically modified (GM) maize has become a reality. GA21, MON810 and MON 863 maize crops are some of the authorized maize events for food and feed under the European Union (EU) regulations. These crops of transgenic maize bring profit towards the conventional ones, as they confer resistence to some plagues and/or herbices. Concerning the raise of production and consumption of foodstuffs derived from genetically modified organisms (GMO), the EU has established new demand levels, including the labeling requirements when the product has GMO in proportion higher than 0.9% (Regulation (EC) Nº. 1829/2003)

Quantiication of coumarins in wine spirit aged by different technologies using Chestnut wood

info:eu-repo/semantics/publishedVersio

'Just Little Things': Nurses' perceptions of quality of life for people with severe multiple impairments.

ABSTRACT Notions of quality of life dictate philosophies and policies for services for people with developmental disabilities. There is an abundance of research on quality of life, much of which has influenced the significant amount of study of quality of life for people with developmental disabilities. According to specialist developmental disability nurses, however, this research has little meaning for one group of people with developmental disabilities with whom they work - people with severe multiple impairments. Nevertheless, judgements and decisions about the lives of this group continue to be driven by the idea of quality of life. While the literature review found that researchers are urged to seek the perceptions of people regarding their own quality of life by asking them, some authors have noted the difficulty in pursuing such a method with people, such as people with severe multiple impairments, who are unable to communicate in the usual ways. Given, then, that it is difficult to directly determine the views of people with severe multiple impairments, this study sought the perceptions of nurses about the quality of life of the people with whom they work. In order to discover and conceptualise nurses' views, a symbolic interaction perspective was chosen to guide this study and data were analysed using the grounded theory approach. The study was conducted in two stages. Stage One consisted of semi-structured indepth interviews with expert nurses to explore their perceptions of quality of life for the people with whom they worked. A significant finding in these interviews was that perceptions of quality of life are mediated by interaction. Consequently, Stage Two involved a participant observation study in which the interactions of nurses and people with severe multiple impairments were examined. Specialist developmental disability nurses have a unique view of quality of life for people with severe multiple impairments. They refer to it as 'just little things', a phrase which masks complex nursing knowledge and skills, and which can be described by four interrelated categories which emerged from the data: humans being, supporting, becoming intimate, and situated belonging. As nurses become more intimate with individuals, they perceive that people with severe multiple impairments are humans being as they wish, and that quality resides in supporting their everyday lives in a context of situated belonging. This thesis represents a new conceptualisation of quality of life for people with severe multiple impairments, a conceptualisation which may have significance for other groups and, indeed, for the whole quality of life enterprise. This conceptualisation draws on knowledge not usually related to quality of life, that is, knowledge of the body, of the emotions, of identity and of humanness. Such findings demonstrate the power of an interpretive approach in explicating the meanings nurses have regarding quality of life. Further, these findings have implications for how the question of quality of life is approached, for how different ways of thinking about people impact on quality of life, and for the importance of the life in quality of life

Degradation of the insecticide propoxur by electrochemical advanced oxidation processes using a boron-doped diamond/air-diffusion cell

A solution with 0.38 mM of the pesticide propoxur (PX) at pH 3.0 has been comparatively treated by electrochemical oxidation with electrogenerated H2O2 (EO-H2O2), electro-Fenton (EF) and photoelectro-Fenton (PEF). The trials were carried out with a 100 mL boron-doped diamond (BDD)/air-diffusion cell. The EO-H2O2 process had the lowest oxidation ability due to the slow reaction of intermediates with ¿OH produced from water discharge at the BDD anode. The EF treatment yielded quicker mineralization due to the additional ¿OH formed between added Fe2+ and electrogenerated H2O2. The PEF process was the most powerful since it led to total mineralization by the combined oxidative action of hydroxyl radicals and UVA irradiation. The PX decay agreed with a pseudo-first-order kinetics in EO-H2O2, whereas in EF and PEF it obeyed a much faster pseudo-first-order kinetics followed by a much slower one, which are related to the oxidation of its Fe(II) and Fe(III) complexes, respectively. EO-H2O2 showed similar oxidation ability within the pH range 3.0-9.0. The effect of current density and Fe2+ and substrate contents on the performance of the EF process was examined. Two primary aromatic products were identified by LC-MS during PX degradation