Atmosphere dynamic processes structure at 80-105 km altitude

Determination of wind velocity by means of Doppler meteor radars is based on the assumption that an ionized meteor trail drifts together with the neutral atmosphere. From the Doppler frequency shift it is possible to estimate the radial velocity of the trail drift. Conversion of the recorded radial velocity to the true wind velocity vector in the given space region depends both on the radar technical parameters and the chosen atmospheric motion model. The atmospheric dynamic processes structure is considered

Sports games as a means of enhancing mental and social health of schoolchildren

Studied possibilities of physical training and sports activities for schoolchildren in strengthening mental and social health. Influence of sports games on the formation of connectivity and emotional stabilityИзучены возможности физкультурно-спортивной деятельности школьников в укреплении психического и социального здоровья. Выявлено влияние занятий спортивными играми на формирование коммуникативности и эмоциональной устойчивост

Correlative Microscopy: A Potent Tool for Biomedicine

The correlative microscopy method based on a combination of optical and electronic techniques that is increasingly widely used now, has a number of limitations. Here, an alternative approach is considered that uses scanning probe microscopy (SPM) technique to get high-resolution and ultra-high-resolution data. SPM greatly increases the possibilities of collecting new information (on topological, morphological, electrical, magnetic etc. properties). To obtain three-dimensional distributions of different parameters of the sample, ultramicrotomography is used, which allows to scan the sample in steps of up to 20 nm. The principal advantage of the approach is that spectral data are used which due to the combination in near field microscopy can be gained with high and ultrahigh resolution. All above mentioned features are implemented in a single instrument, which allows to have 3-D data and their distributions at the same instrumental platform. A special feature of the approach is the possibility to use all the power of micro(nano)spectral methods. Therefore, it would be more correct to name the proposed approach ”Correlative microspectroscopy”. Keywords: correlative microscopy, correlative microspectroscopy, scanning near-ielf optical microscopy, ultramicrotomography, Raman, TER

Technology for Creation and Detailed Analysis of Polymer Composites with Uniform Distribution of Quantum Dots and Liquid Crystals

One of the most actual tasks in biotechnology is the creation of a new generation of nanobiosensors with improved brightness, photo stability, and sensitivity. Compositions of polymers and colloidal quantum dots (QDs) are the most promising base to develop such sensors. This work presents the technology for creation and detailed analysis of nanostructured composite films based on polypropylene matrices with uniformly distributed CdSe/ZnS quantum dots and liquid crystals. Methods of optical microscopy, scanning probe microscopy and confocal fluorescen tmicrospectroscopy were used. The presence of liquid crystals in the composite allows additional control of QDs fluorescence. The methodology proposed is applicable not only to polypropylene, but also to other porous polymers. The results of this work indicate the possibility of creating high-quality polymer/QDs composite materials and open the way to the development of nanomaterials (nanosensors) with optical properties sensitive to various environmental parameters (electric field, photo irradiation, mechanical action, etc.). Keywords: quantum dot-polymer composites, nanoporous polypropylene, fluorescenc

Design of the Model of Ratiometric Polymer Nanobiothermometer Based on Quantum Dots

To solve many modern biological and biotechnological tasks it is necessary to realize strictly control and regulation of temperature of the cells and their organelles. Thi stasks include control of various exo- and endothermic reactions, monitoring of tissues‘ and individual cell‘s temperature in in vitro researches and in vivo procedures such as the hyperthermia procedure that used for cancer treatment. The today known methods of measuring and controlling of temperature at the cellular level can not provide the necessary level of locality and accuracy due to too big size and heightened sensitivity to external factors. The real alternative of existing today methods is nanoscale temperature biosensor operating on a ratiometric principle and based on the composite structure from polymers and colloidal quantum dots. In this paper we present a working model and plan of investigation of ratiometric nanoscale polymer nanobiothermometer based on quantum dots. Keywords: thermosensors, quantum dots, local temperature, polymers, temperature measuremen

Porous matrixes based on ion-irradiated polymer as templates for synthesis of nanowires

Irradiation with swift heavy ions is usually used for production of track membranes (nuclear filters). These membranes traditionally used as filters for fine filtration in medicine and biology. Another application is matrixes for so called matrix synthesis. The idea of this technique is to fill pores by any desired material- metal,polymer, semiconductor and so on. This work is devoted to formation of membrane for template synthesis, to investigation of filling process and to study some properties of obtained structures. It was found that filtration track membranes are not the best material for template synthesis –another type of matrixes are needed- with different pores profiles and parallel pores orientation These parameters could be obtained during irradiation. Different types of etching gave possibility to vary by will the shape of the pores and to obtain pores with conical shape. The process of etching in the alkali solution in mixture of water and alcohol was investigated. The main part of the work devoted to fabrication of micro- and nanowires via electrodeposition. Different types of metals-copper, silver, cobalt and nickel were used for galvanic deposition of the pores. Two types of the processes- galvanostatic and potentiostatic were investigated. It was also demonstrated that obtained metallic nanowires could be used as the substrates for deposition of the probe (biological molecules) in mass-spectrometer. The application of such structures in non-linear optic was also described. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/2083

Evaluation of interspecific populations of grapevine in breeding for complex resistance to fungal diseases and phylloxera

Roentgenoscopy was used as a method to determine the quality of hybrid seeds and to predict the development of viable plants from interspecific hybridization. The seeds were grouped into five classes of quality (embryo classes) depending on embryo size and degree of endosperm development As the index number of a class increased, the proportion of plantlets and vigorous plants produced also increased. In order to evaluate genotypic peculiarities of the original forms and seedlings, the seedlings were studied at the juvenile stage of ontogeny. Analysis of development of the hybrids studied during 5-6 years under conditions of complex infection pressure at a special planting site made it possible to evaluate the degree of their resistance to phylloxera, pathogenic soil microflora and fungal diseases and to eliminate susceptible genotypes. The heritability of resistance to fungal diseases (mildew, oidium, grey rot) and phylloxera was studied, conclusions were made concerning the combining ability of the original forms, and these forms were evaluated as donors of the desirable characters. Using transgressive resistant hybrids as donors in backcrossing provided improved quality with a broad range of resistance variability, which made it possible to select promising genotypes

Reactivity of the Indenyl Radical (C9 H7 ) with Acetylene (C2 H2 ) and Vinylacetylene (C4 H4 ).

The reactions of the indenyl radicals with acetylene (C2 H2 ) and vinylacetylene (C4 H4 ) is studied in a hot chemical reactor coupled to synchrotron based vacuum ultraviolet ionization mass spectrometry. These experimental results are combined with theory to reveal that the resonantly stabilized and thermodynamically most stable 1-indenyl radical (C9 H7 . ) is always formed in the pyrolysis of 1-, 2-, 6-, and 7-bromoindenes at 1500 K. The 1-indenyl radical reacts with acetylene yielding 1-ethynylindene plus atomic hydrogen, rather than adding a second acetylene molecule and leading to ring closure and formation of fluorene as observed in other reaction mechanisms such as the hydrogen abstraction acetylene addition or hydrogen abstraction vinylacetylene addition pathways. While this reaction mechanism is analogous to the bimolecular reaction between the phenyl radical (C6 H5 . ) and acetylene forming phenylacetylene (C6 H5 CCH), the 1-indenyl+acetylene→1-ethynylindene+hydrogen reaction is highly endoergic (114 kJ mol-1 ) and slow, contrary to the exoergic (-38 kJ mol-1 ) and faster phenyl+acetylene→phenylacetylene+hydrogen reaction. In a similar manner, no ring closure leading to fluorene formation was observed in the reaction of 1-indenyl radical with vinylacetylene. These experimental results are explained through rate constant calculations based on theoretically derived potential energy surfaces

Современные тенденции изменения снеголавинного режима Центрального Кавказа (на примере Приэльбрусья)

The climate change during cold seasons of 1995–2017 in the Central Caucasus is estimated, and its influence on the avalanche regime is shown. Data on the avalanche releases in the Central Caucasus for the period 1968– 2017 together with observations of high-altitude meteorological stations were used for the analysis. The paper presents estimates of snowiness of the winters and their frequency of occurrence in the area under investigation. The winter snowiness was noted to decrease since the beginning of the 2000s. The last decade of the period was not snowy, especially its series of six winters having very small amounts of snow. It is shown that in the second half of the XX century the heaviest snowfalls took place mostly in Januaries, and they were followed by releases of avalanches with the volumes exceeding 1 million cubic metres. In the early 2000‑ies, intensive January snowfalls were observed later, i.e. during the winter-spring period. In the warmer months March and April, the destructive potential of avalanches was noticeably smaller. In the present time, the warming and decrease of winter snowiness resulted in significant diminution of the avalanche hazard in the region. At the same time, on the background of general warming the certain increase in inter-seasonal variability of air temperature was noted. These changes may be compared to the warming of 1910–1945 when during its warmest phase the Europe suffered with one of the harshest winters in 1941/42. The swing of the «temperature pendulum» indicates that a harsh winter with heavy snowfalls and avalanches with catastrophic consequences may occur on the background of winters with mild and moderate avalanche danger. This is one of probable scenarios in the development of avalanche activity in the Greater Caucasus in the context of the current climate change.На рубеже XX–XXI вв. (1995–2017 гг.) увеличились изменчивость и частота экстремальных явлений. Рассмотрены тенденции изменения снеголавинного режима в Приэльбрусье за последние десятилетия, показана их связь с изменениями климата.

Зимы лавинного максимума на Большом Кавказе за период инструментальных наблюдений (1968–2016 гг.)

This investigation has been carried out to identify winters with the maximum frequency of avalanches in the Greater Caucasus. The analysis was performed for decades and for the entire period of instrumental observations (1968–2016). We chose severe snow winters which were followed by releases of particularly large and heavy avalanches (Lmax) and the maximum area of damage to the mountain territory during the study period. The following materials were used for this work: 1) 47‑year-old (1968–2016) series of data on snow avalanches from observations performed at the high-altitude station of the Faculty of Geography of the Lomonosov Moscow State University in the near-Elbrus area (Central Caucasus); 2) the results of winter and summer investigations of snow and avalanches in Arkhyz (the Western Caucasus); 3) materials of field works carried out in the Caucasus at different times; 4) the results of winter typing from data of 41 mid- and high-mountain meteorological stations in the Greater Caucasus; 5) literature sources; 6) survey data. The dependence of avalanche activity on the types of winters was established for key observational sites in the near-Elbrus area (Central Caucasus) and Arkhyz (Western Caucasus). This dependence formed the basis for determining the Lmax winters from factors of the avalanche formation, i.e. the air temperature and precipitation for the cold period from meteorological observations. Based on the method of winter typing, the winters of the maximal avalanche occurrence were estimated from data of 41 meteorological stations of the Greater Caucasus for 1936–2016. Results of the typing revealed similar avalanche extremes as it was found from direct observations of releases of snow avalanches: on the Southern macro-slope of the Western and Central Caucasus – 1986/87; on the Eastern Caucasus – 1971/72. Two seasons, claiming the role of the Lmax – 1967/68 and 1975/76, were revealed on the Northern macro-slope.Дана оценка зим экстремального лавинообразоваия на Большом Кавказе по десятилетиям и за весь период инструментальных наблюдений (1968–2016). Использованы данные о сходе снежных лавин и результаты типизации зим по материалам 41 метеорологической станции Большого Кавказа. Установлено, что на южном макросклоне Западного и Центрального Кавказа к таким зимам относится 1986/87 г., на Восточном Кавказе – 1971/72 г., а на северном макросклоне – зимы 1967/68 и 1975/76 гг