Resonance Fluorescence of a Single Artificial Atom

An atom in open space can be detected by means of resonant absorption and reemission of electromagnetic waves, known as resonance fluorescence, which is a fundamental phenomenon of quantum optics. We report on the observation of scattering of propagating waves by a single artificial atom. The behavior of the artificial atom, a superconducting macroscopic two-level system, is in a quantitative agreement with the predictions of quantum optics for a pointlike scatterer interacting with the electromagnetic field in one-dimensional open space. The strong atom-field interaction as revealed in a high degree of extinction of propagating waves will allow applications of controllable artificial atoms in quantum optics and photonics.Comment: 5 pages, 4 figure

Evidence of a Curved Synchrotron Spectrum in the Supernova Remnant SN 1006

A joint spectral analysis of some Chandra ACIS X-ray data and Molonglo Observatory Synthesis Telescope radio data was performed for 13 small regions along the bright northeastern rim of the supernova remnant SN 1006. These data were fitted with a synchrotron radiation model. The nonthermal electron spectrum used to compute the photon emission spectra is the traditional exponentially cut off power law, with one notable difference: The power-law index is not a constant. It is a linear function of the logarithm of the momentum. This functional form enables us to show, for the first time, that the synchrotron spectrum of SN 1006 seems to flatten with increasing energy. The effective power-law index of the electron spectrum is 2.2 at 1 GeV (i.e., radio synchrotron-emitting momenta) and 2.0 at about 10 TeV (i.e., X-ray synchrotron-emitting momenta). This amount of change in the index is qualitatively consistent with theoretical models of the amount of curvature in the proton spectrum of the remnant. The evidence of spectral curvature implies that cosmic rays are dynamically important instead of being "test" particles. The spectral analysis also provides a means of determining the critical frequency of the synchrotron spectrum associated with the highest-energy electrons. The critical frequency seems to vary along the northeastern rim, with a maximum value of 1.1e17 (0.6e17 - 2.1e17) Hz. This value implies that the electron diffusion coefficient can be no larger than a factor of ~4.5-21 times the Bohm diffusion coefficient if the velocity of the forward shock is in the range 2300-5000 km/s. Since the coefficient is close to the Bohm limit, electrons are accelerated nearly as fast as possible in the regions where the critical frequency is about 1.0e17 Hz.Comment: 41 pages, 8 figures, accepted by Ap

The Power of Action Plots: Unveiling Reaction Selectivity of Light‐Stabilized Dynamic Covalent Chemistry

Exploiting the optimum wavelength of reactivity for efficient photochemical reactions has been well-established based on the development of photochemical action plots. We herein demonstrate the power of such action plots by a remarkable example of the wavelength-resolved photochemistry of two triazolinedione (TAD) substrates, i.e., aliphatic and aromatic substituted, that exhibit near identical absorption spectra yet possess vastly disparate photoreactivity. We present our findings in carefully recorded action plots, from which reaction selectivity is identified. The profound difference in photoreactivity is exploited by designing a ‘hybrid’ bisfunctional TAD molecule, enabling the formation of a dual-gated reaction manifold that demonstrates the exceptional and site-selective (photo)chemical behavior of both TAD substrates within a single small molecule

Optimal generation of Fock states in a weakly nonlinear oscillator

We apply optimal control theory to determine the shortest time in which an energy eigenstate of a weakly anharmonic oscillator can be created under the practical constraint of linear driving. We show that the optimal pulses are beatings of mostly the transition frequencies for the transitions up to the desired state and the next leakage level. The time of a shortest possible pulse for a given nonlinearity scale with the nonlinearity parameter delta as a power law of alpha with alpha=-0.73 +/-0.029. This is a qualitative improvement relative to the value alpha=1 suggested by a simple Landau-Zener argument.Comment: 10 pages, 6 figure

Decomposing Dusty Galaxies. I. Multi-Component Spectral Energy Distribution Fitting

We present a new multi-component spectral energy distribution (SED) decomposition method and use it to analyze the ultraviolet to millimeter wavelength SEDs of a sample of dusty infrared-luminous galaxies. SEDs are constructed from spectroscopic and photometric data obtained with the Spitzer Space Telescope, in conjunction with photometry from the literature. Each SED is decomposed into emission from populations of stars, an AGN accretion disk, PAHs, atomic and molecular lines, and distributions of graphite and silicate grains. Decompositions of the SEDs of the template starburst galaxies NGC7714 and NGC2623 and the template AGNs PG0804+761 and Mrk463 provide baseline properties to aid in quantifying the strength of star-formation and accretion in the composite systems NGC6240 and Mrk1014. We find that obscured radiation from stars is capable of powering the total dust emission from NGC6240, although we cannot rule out a contribution from a deeply embedded AGN visible only in X-rays. The decomposition of Mrk1014 is consistent with ~65% of its power emerging from an AGN and ~35% from star-formation. We suggest that many of the variations in our template starburst SEDs may be explained in terms of the different mean optical depths through the clouds of dust surrounding the young stars within each galaxy. Prompted by the divergent far-IR properties of our template AGNs, we suggest that variations in the relative orientation of their AGN accretion disks with respect to the disks of the galaxies hosting them may result in different amounts of AGN-heated cold dust emission emerging from their host galaxies. We estimate that 30-50% of the far-IR and PAH emission from Mrk1014 may originate from such AGN-heated material in its host galaxy disk.Comment: 27 pages, 12 figures. Accepted for publication in the Ap

The Neon Abundance of Galactic Wolf-Rayet Stars

The fast, dense winds which characterize Wolf-Rayet (WR) stars obscure their underlying cores, and complicate the verification of evolving core and nucleosynthesis models. Core evolution can be probed by measuring abundances of wind-borne nuclear processed elements, partially overcoming this limitation. Using ground-based mid-infrared spectroscopy and the 12.81um [NeII] emission line measured in four Galactic WR stars, we estimate neon abundances and compare to long-standing predictions from evolved-core models. For the WC star WR121, this abundance is found to be >~11x the cosmic value, in good agreement with predictions. For the three less-evolved WN stars, little neon enhancement above cosmic values is measured, as expected. We discuss the impact of clumping in WR winds on this measurement, and the promise of using metal abundance ratios to eliminate sensitivity to wind density and ionization structure.Comment: Accepted for publication in ApJ; 9 pages, 2 color figures, 4 table

PAH Emission from Ultraluminous Infrared Galaxies

We explore the relationships between the Polycyclic Aromatic Hydrocarbon (PAH) feature strengths, mid-infrared continuum luminosities, far-infrared spectral slopes, optical spectroscopic classifications, and silicate optical depths within a sample of 107 ULIRGs observed with the Infrared Spectrograph on the Spitzer Space Telescope. The detected 6.2 micron PAH equivalent widths (EQWs) in the sample span more than two orders of magnitude (0.006-0.8 micron), and ULIRGs with HII-like optical spectra or steep far-infrared spectral slopes (S_{25} / S_{60} < 0.2) typically have 6.2 micron PAH EQWs that are half that of lower-luminosity starbursts. A significant fraction (~40-60%) of HII-like, LINER-like, and cold ULIRGs have very weak PAH EQWs. Many of these ULIRGs also have large (tau_{9.7} > 2.3) silicate optical depths. The far-infrared spectral slope is strongly correlated with PAH EQW, but not with silicate optical depth. In addition, the PAH EQW decreases with increasing rest-frame 24 micron luminosity. We argue that this trend results primarily from dilution of the PAH EQW by continuum emission from dust heated by a compact central source, probably an AGN. High luminosity, high-redshift sources studied with Spitzer appear to have a much larger range in PAH EQW than seen in local ULIRGs, which is consistent with extremely luminous starburst systems being absent at low redshift, but present at early epochs.Comment: 15 pages, 9 Figures; Accepted for publication in Ap

The Spatial Extent of (U)LIRGs in the mid-Infrared I: The Continuum Emission

We present an analysis of the extended mid-infrared (MIR) emission of the Great Observatories All-Sky LIRG Survey (GOALS) sample based on 5-15um low resolution spectra obtained with the IRS on Spitzer. We calculate the fraction of extended emission as a function of wavelength for the galaxies in the sample, FEE_lambda. We can identify 3 general types of FEE_lambda: one where it is constant, one where features due to emission lines and PAHs appear more extended than the continuum, and a third which is characteristic of sources with deep silicate absorption at 9.7um. More than 30% of the galaxies have a median FEE_lambda larger than 0.5 implying that at least half of their MIR emission is extended. Luminous Infrared Galaxies (LIRGs) display a wide range of FEE in their warm dust continuum (0<=FEE_13.2um<=0.85). The large values of FEE_13.2um that we find in many LIRGs suggest that their extended MIR continuum emission originates in scales up to 10kpc. The mean size of the LIRG cores at 13.2um is 2.6kpc. However, once the LIR of the systems reaches the threshold of ~10^11.8Lsun, all sources become clearly more compact, with FEE_13.2um<=0.2, and their cores are unresolved. Our estimated upper limit for the core size of ULIRGs is less than 1.5kpc. The analysis indicates that the compactness of systems with LIR>~10^11.25Lsun strongly increases in those classified as mergers in their final stage of interaction. The FEE_13.2um is also related to the contribution of an active galactic nucleus (AGN) to the MIR. Galaxies which are more AGN-dominated are less extended, independently of their LIR. We finally find that the extent of the MIR continuum emission is correlated with the far-IR IRAS log(f_60um/f_100um) color. This enables us to place a lower limit to the area in a galaxy from where the cold dust emission may originate, a prediction which can be tested soon with the Herschel Space Telescope.Comment: 18 pages, 8 figures, accepted for publication in Ap

The Detection of Crystalline Silicates in Ultra-Luminous Infrared Galaxies

Silicates are an important component of interstellar dust and the structure of these grains -- amorphous versus crystalline -- is sensitive to the local physical conditions. We have studied the infrared spectra of a sample of ultra-luminous infrared galaxies. Here, we report the discovery of weak, narrow absorption features at 11, 16, 19, 23, and 28 microns, characteristic of crystalline silicates, superimposed on the broad absorption bands at 10 and 18 microns due to amorphous silicates in a subset of this sample. These features betray the presence of forsterite (Mg_2SiO_4), the magnesium-rich end member of the olivines. Previously, crystalline silicates have only been observed in circumstellar environments. The derived fraction of forsterite to amorphous silicates is typically 0.1 in these ULIRGs. This is much larger than the upper limit for this ratio in the interstellar medium of the Milky Way, 0.01. These results suggest that the timescale for injection of crystalline silicates into the ISM is short in a merger-driven starburst environment (e.g., as compared to the total time to dissipate the gas), pointing towards massive stars as a prominent source of crystalline silicates. Furthermore, amorphization due to cosmic rays, which is thought to be of prime importance for the local ISM, lags in vigorous starburst environments.Comment: 7 pages, 5 figures, accepted for publication in Ap