Single-Shot Electron Diffraction using a Cold Atom Electron Source

Cold atom electron sources are a promising alternative to traditional photocathode sources for use in ultrafast electron diffraction due to greatly reduced electron temperature at creation, and the potential for a corresponding increase in brightness. Here we demonstrate single-shot, nanosecond electron diffraction from monocrystalline gold using cold electron bunches generated in a cold atom electron source. The diffraction patterns have sufficient signal to allow registration of multiple single-shot images, generating an averaged image with significantly higher signal-to-noise ratio than obtained with unregistered averaging. Reflection high-energy electron diffraction (RHEED) was also demonstrated, showing that cold atom electron sources may be useful in resolving nanosecond dynamics of nanometre scale near-surface structures.Comment: This is an author-created, un-copyedited version of an article published in Journal of Physics B: Atomic, Molecular and Optical Physics. IOP Publishing Ltd is not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at http://dx.doi.org/10.1088/0953-4075/48/21/21400

Protein annotation and modelling servers at University College London

The UCL Bioinformatics Group web portal offers several high quality protein structure prediction and function annotation algorithms including PSIPRED, pGenTHREADER, pDomTHREADER, MEMSAT, MetSite, DISOPRED2, DomPred and FFPred for the prediction of secondary structure, protein fold, protein structural domain, transmembrane helix topology, metal binding sites, regions of protein disorder, protein domain boundaries and protein function, respectively. We also now offer a fully automated 3D modelling pipeline: BioSerf, which performed well in CASP8 and uses a fragment-assembly approach which placed it in the top five servers in the de novo modelling category. The servers are available via the group web site at http://bioinf.cs.ucl.ac.uk/

The Broad Absorption Line Tidal Disruption Event iPTF15af: Optical and Ultraviolet Evolution

We present multi-wavelength observations of the tidal disruption event (TDE) iPTF15af, discovered by the intermediate Palomar Transient Factory (iPTF) survey at redshift $z=0.07897$. The optical and ultraviolet (UV) light curves of the transient show a slow decay over five months, in agreement with previous optically discovered TDEs. It also has a comparable black-body peak luminosity of $L_{\rm{peak}} \approx 1.5 \times 10^{44}$ erg/s. The inferred temperature from the optical and UV data shows a value of (3$-$5) $\times 10^4$ K. The transient is not detected in X-rays up to $L_X < 3 \times 10^{42}$erg/s within the first five months after discovery. The optical spectra exhibit two distinct broad emission lines in the He II region, and at later times also H$\alpha$ emission. Additionally, emission from [N III] and [O III] is detected, likely produced by the Bowen fluorescence effect. UV spectra reveal broad emission and absorption lines associated with high-ionization states of N V, C IV, Si IV, and possibly P V. These features, analogous to those of broad absorption line quasars (BAL QSOs), require an absorber with column densities $N_{\rm{H}} > 10^{23}$ cm$^{-2}$. This optically thick gas would also explain the non-detection in soft X-rays. The profile of the absorption lines with the highest column density material at the largest velocity is opposite that of BAL QSOs. We suggest that radiation pressure generated by the TDE flare at early times could have provided the initial acceleration mechanism for this gas. Spectral UV line monitoring of future TDEs could test this proposal.Comment: 20 pages, 12 figures, published in Ap

Time Dependent Monte Carlo Radiative Transfer Calculations For 3-Dimensional Supernova Spectra, Lightcurves, and Polarization

We discuss Monte-Carlo techniques for addressing the 3-dimensional time-dependent radiative transfer problem in rapidly expanding supernova atmospheres. The transfer code SEDONA has been developed to calculate the lightcurves, spectra, and polarization of aspherical supernova models. From the onset of free-expansion in the supernova ejecta, SEDONA solves the radiative transfer problem self-consistently, including a detailed treatment of gamma-ray transfer from radioactive decay and with a radiative equilibrium solution of the temperature structure. Line fluorescence processes can also be treated directly. No free parameters need be adjusted in the radiative transfer calculation, providing a direct link between multi-dimensional hydrodynamical explosion models and observations. We describe the computational techniques applied in SEDONA, and verify the code by comparison to existing calculations. We find that convergence of the Monte Carlo method is rapid and stable even for complicated multi-dimensional configurations. We also investigate the accuracy of a few commonly applied approximations in supernova transfer, namely the stationarity approximation and the two-level atom expansion opacity formalism.Comment: 16 pages, ApJ accepte

Chandra and FUSE spectroscopy of the hot bare stellar core H1504+65

H1504+65 is an extremely hot hydrogen-deficient white dwarf with an effective temperature close to 200,000 K. We present new FUV and soft X-ray spectra obtained with FUSE and Chandra, which confirm that H1504+65 has an atmosphere primarily composed of carbon and oxygen. The Chandra LETG spectrum (60-160 Angstroem) shows a wealth of photospheric absorption lines from highly ionized oxygen, neon, and - for the first time identified in this star - magnesium and suggests relatively high Ne and Mg abundances. This corroborates an earlier suggestion that H1504+65 represents a naked C/O stellar core or even the C/O envelope of an O-Ne-Mg white dwarf.Comment: 15 pages, 10 figures, accepted for publication in A&

K-corrections and Extinction Corrections for Type Ia Supernovae

The measurement of the cosmological parameters from Type Ia supernovae hinges on our ability to compare nearby and distant supernovae accurately. Here we present an advance on a method for performing generalized K-corrections for Type Ia supernovae which allows us to compare these objects from the UV to near-IR over the redshift range 0<z<2. We discuss the errors currently associated with this method and how future data can improve upon it significantly. We also examine the effects of reddening on the K-corrections and the light curves of Type Ia supernovae. Finally, we provide a few examples of how these techniques affect our current understanding of a sample of both nearby and distant supernovae.Comment: Accepted for the August issue of PASP. 39 pages, 15 figure

Double-detonation sub-Chandrasekhar supernovae: synthetic observables for minimum helium shell mass models

Abridged. In the double detonation scenario for Type Ia supernovae (SNe Ia) a detonation initiates in a shell of He-rich material accreted from a companion star by a sub-Chandrasekhar-mass White Dwarf (WD). This shell detonation drives a shock front into the carbon-oxygen (C/O) WD that triggers a secondary detonation in the core. The core detonation results in a complete disruption of the WD. Earlier studies concluded that this scenario has difficulties in accounting for the observed properties of SNe Ia since the explosion ejecta are surrounded by the products of explosive He burning in the shell. Recently, it was proposed that detonations might be possible for much less massive He shells than previously assumed. Moreover, it was shown that even detonations of these minimum He shell masses robustly trigger detonations of the C/O core. Here we present time-dependent multi-wavelength radiative transfer calculations for models with minimum He shell mass and derive synthetic observables for both the optical and {\gamma}-ray spectral regions. These differ strongly from those found in earlier simulations of sub-Chandrasekhar-mass explosions in which more massive He shells were considered. Our models predict light curves which cover both the range of brightnesses and the rise and decline times of observed SNe Ia. However, their colours and spectra do not match the observations. In particular, their B-V colours are generally too red. We show that this discrepancy is mainly due to the composition of the burning products of the He shell of our models which contain significant amounts of Ti and Cr. Using a toy model, we also show that the burning products of the He shell depend crucially on its initial composition. This leads us to conclude that good agreement between sub-Chandrasekhar-mass explosions and observed SNe Ia may still be feasible but further study of the shell properties is required.Comment: 17 pages, 13 figures. Accepted for publication by Ap

A new role for organometallic reactions in organic synthesis in industry

Abstract -Organometallic compounds are coming to play a significant role as catalysts and reagents for the synthesis of organic compounds in high technology industry. Some examples involving C-C bond formation include alkylation of chloronaphthoquinones and halobenzenes, a titanium-mediated cyclization of diynes, and a simultaneous alkylation and ring closure of hexenedioates to give cyclopentanone derivatives. Transition metal imides provide convenient reagents for C-N bond formation in a new synthesis of allylic amines