Structural and electrical properties of ceramic Li-ion conductors based on Li1.3_{1.3}Al0.3_{0.3}Ti1.7_{1.7}(PO4_4)3_3-LiF

The work presents the investigations of Li1.3Al0.3Ti1.7(PO4)3-xLiF Li-ion conducting ceramics with 0 < x < 0.3 by means of X-ray diffractometry (XRD), 7Li, 19F, 27Al and 31P Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR) spectroscopy, thermogravimetry (TG), scanning electron microscopy (SEM), impedance spectroscopy (IS) and density method. It has been shown that the total ionic conductivity of both as-prepared and ceramic Li1.3Al0.3Ti1.7(PO4)3 is low due to a grain boundary phase exhibiting high electrical resistance. This phase consists mainly of berlinite crystalline phase as well as some amorphous phase containing Al3+ ions. The electrically resistant phases of the grain boundary decompose during sintering with LiF additive. The processes leading to microstructure changes and their effect on the ionic properties of the materials are discussed in the frame of the brick layer model (BLM). The highest total ionic conductivity at room temperature was measured for LATP-0.1LiF ceramic sintered at 800{\deg}C and was equal to {\sigma}tot = 1.1 x 10-4 Scm-1

Impact of Li2.9_{2.9}B0.9_{0.9}S0.1_{0.1}O3.1_{3.1} glass additive on the structure and electrical properties of the LATP-based ceramics

The existing solid electrolytes for lithium ion batteries suffer from low total ionic conductivity, which restricts its usefulness for the lithium-ion battery technology. Among them, the NASICON-based materials, such as Li1.3Al0.3Ti1.7(PO4)3 (LATP) exhibit low total ionic conductivity due to highly resistant grain boundary phase. One of the possible approaches to efficiently enhance their total ionic conductivity is the formation of a composite material. Herein, the Li2.9B0.9S0.1O3.1 glass, called LBSO hereafter, was chosen as an additive material to improve the ionic properties of the ceramic Li1.3Al0.3Ti1.7(PO4)3 base material. The properties of this Li1.3Al0.3Ti1.7(PO4)3-xLi2.9B0.9S0.1O3.1 (0 < x < 0.3) system have been studied by means of high temperature X-ray diffractometry (HTXRD), 7Li, 11B, 27Al and 31P magic angle spinning nuclear magnetic resonance spectroscopy (MAS NMR), thermogravimetry (TG), scanning electron microscopy (SEM), impedance spectroscopy (IS) and density methods. We show here that the introduction of the foreign LBSO phase enhances their electric properties. This study reveals several interesting correlations between the apparent density, the microstructure, the composition, the sintering temperature and the ionic conductivity. Moreover, the electrical properties of the composites will be discussed in the terms of the brick-layer model (BLM). The highest value of {\sigma}tot = 1.5 x 10-4 Scm-1 has been obtained for LATP-0.1LBSO material sintered at 800{\deg}C

The effect of entrepreneurship education on nascent entrepreneurship

The literature has been enriched by studies examining the effect of entrepreneurship education on entrepreneurial or goal intention. Yet, few articles have considered how entrepreneurship education affects nascent entrepreneurship as a more sought-after outcome. Similarly, some scholars assess entrepreneurship education as an aggregate rather than a multidimensional construct comprised of alternative methods with peculiar characteristics yielding distinct student outcomes. Possibly, the present shortage of specificity in the investigation of methods in entrepreneurship education reduces empirical understanding of efficacious teaching and learning modes for optimising entrepreneurial behaviour. Hence, by way of contribution, this inquiry isolates and measures the direct effect of courses, workshops, guest speakers and simulations on new venture creation among UK students. It also measures indirect influence in the same relationships, with self-efficacy as a mediator. A structural equation analysis is performed and the findings show that discretely, in this order, simulations, workshops and courses stimulate nascent entrepreneurship. However, there is particular insignificance in the direct link between guest speakers and nascent entrepreneurship, and further dissociation in the indirect link between workshops and simulations leading to self-efficacy. Theoretical implications arise for future correlation and configurational studies, as well as practical ramifications for entrepreneurship education practitioners, simulation developers and public institutions

Dissecting the effect of family business exposure on entrepreneurial implementation intention

Purpose Scholars have typically examined family business exposure as an aggregate variable. However, it is probable that this trend oversimplifies the complexity of family exposure and its nuanced influence on entrepreneurial behaviour. Thus, to extend the theoretical boundary, this inquiry investigates distinct dimensions of family exposure in Nigeria while drawing on the theory of planned behaviour. Methodology Data were collected from five public universities in Nigeria. A sample of 1,314 respondents was analysed using a partial least squares structural equation modelling approach to determine the influence of alternate family business exposures. Findings The results show that entrepreneurial exposure in the forms of parent, family member and work involvement have salient and distinctive influences on implementation intention to the extent that entrepreneurial self-efficacy, attitudes and subjective norms are uniquely impacted. Originality This study offers novel insights on the predictors of entrepreneurial implementation intention through the distinctive effects of (1) family member exposure, (2) parent exposure and (3) work involvement exposure among students in the family firm context

A basal lithostrotian titanosaur (Dinosauria: Sauropoda) with a complete skull: Implications for the evolution and paleobiology of titanosauria

We describe Sarmientosaurus musacchioi gen. et sp. nov., a titanosaurian sauropod dinosaur from the Upper Cretaceous (Cenomanian - Turonian) Lower Member of the Bajo Barreal Formation of southern Chubut Province in central Patagonia, Argentina. The holotypic and only known specimen consists of an articulated, virtually complete skull and part of the cranial and middle cervical series. Sarmientosaurus exhibits the following distinctive features that we interpret as autapomorphies: (1) maximum diameter of orbit nearly 40% rostrocaudal length of cranium; (2) complex maxilla - lacrimal articulation, in which the lacrimal clasps the ascending ramus of the maxilla; (3) medial edge of caudal sector of maxillary ascending ramus bordering bony nasal aperture with low but distinct ridge; (4) ´tongue-like´ ventral process of quadratojugal that overlaps quadrate caudally; (5) separate foramina for all three branches of the trigeminal nerve; (6) absence of median venous canal connecting infundibular region to ventral part of brainstem; (7) subvertical premaxillary, procumbent maxillary, and recumbent dentary teeth; (8) cervical vertebrae with ´strut-like´ centroprezygapophyseal laminae; (9) extremely elongate and slender ossified tendon positioned ventrolateral to cervical vertebrae and ribs. The cranial endocast of Sarmientosaurus preserves some of the most complete information obtained to date regarding the brain and sensory systems of sauropods. Phylogenetic analysis recovers the new taxon as a basal member of Lithostrotia, as the most plesiomorphic titanosaurian to be preserved with a complete skull. Sarmientosaurus provides a wealth of new cranial evidence that reaffirms the close relationship of titanosaurs to Brachiosauridae. Moreover, the presence of the relatively derived lithostrotian Tapuiasaurus in Aptian deposits indicates that the new Patagonian genus represents a ´ghost lineage´ with a comparatively plesiomorphic craniodental form, the evolutionary history of which is missing for at least 13 million years of the Cretaceous. The skull anatomy of Sarmientosaurus suggests that multiple titanosaurian species with dissimilar cranial structures coexisted in the early Late Cretaceous of southern South America. Furthermore, the new taxon possesses a number of distinctive morphologies - such as the ossified cervical tendon, extremely pneumatized cervical vertebrae, and a habitually downward- facing snout - that have rarely, if ever, been documented in other titanosaurs, thus broadening our understanding of the anatomical diversity of this remarkable sauropod clade. The latter two features were convergently acquired by at least one penecontemporaneous diplodocoid, and may represent mutual specializations for consuming low-growing vegetation.Fil: Martínez, Rubén Darío. Universidad Nacional de la Patagonia; ArgentinaFil: Lamanna, Matthew C.. Carnegie Museum Of Natural History; Estados UnidosFil: Novas, Fernando Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Museo Argentino de Ciencias Naturales "bernardino Rivadavia"; ArgentinaFil: Ridgely, Ryan C.. Ohio University College Of Osteopathic Medicine; Estados UnidosFil: Casal, Gabriel. Universidad Nacional de la Patagonia; ArgentinaFil: Martínez, Javier E.. Hospital Regional de Comodoro Rivadavia; ArgentinaFil: Vita, Javier R.. Resonancia Magnética Borelli; ArgentinaFil: Witmer, Lawrence M.. Ohio University College Of Osteopathic Medicine; Estados Unido

The determinants of SMEs’ export entry: A systematic review of the literature

Despite the plethora of studies on SMEs’ export performance and survival, empirical works on export initiation are relatively limited. Thus far, extant literature has fallen short of determining a comprehensive set of factors affecting firms’ entry to export markets. For these reasons, building on from previous reviews involving export entry, we review 82 papers related to the determinants of SMEs’ export entry published between 2008 and 2019, in order to develop a holistic framework. We provide a comprehensive model that encompasses the key factors associated with this behaviour. We also discuss key issues and propose areas of future research

Warunków występowania tarcia płynnego

The engineering practice shows that there are many bearings designed to operate in the field of hydrodynamic friction, but sometimes the oil film breaks and symptoms of wear appear on surfaces. We are interested in the possibility of determining these friction conditions under which the oil film effectively separates the two friction surfaces, and at the same time has a high load capacity and low friction. Parameters describing the selected range of hydrodynamic friction that interests us are as follows: pressure, sliding velocity, temperature and length of the slide at which the oil film not only is not interrupted, but still has a high load capacity and low friction. In this paper, we assume the boundary for the occurrence of hydrodynamic friction to be conditions under which a type of fluid friction changes into a kind of boundary friction. Establishing conditions in which one type of friction takes place helps to make conscious use of this fact to design a plain bearing with low friction and high strength non-interrupting film, and possible wear processes will occur only at moments of start-up and stop.Praktyka pokazuje, że w technice istnieje wiele łożysk przeznaczonych do pracy w zakresie tarcia hydrodynamicznego, w których czasami ulega zerwaniu film olejowy i na powierzchni pojawiają się objawy zużycia. Ważna jest możliwość określenia warunków tarcia gdy film olejowy skutecznie oddziela dwie powierzchnie tarcia, a jednocześnie ma dużą nośność i niski współczynnik tarcia. Parametry opisujące wybrany zakres tarcia hydrodynamicznego są następujące: ciśnienie, prędkość przemieszczania, temperatura i długość prowadnicy, w których film olejowy nie tylko nie ulega prze-rwaniu, lecz wciąż ma wysoką obciążalność i niskie tarcie. W artykule założono granicę dla występowania tarcia hydrodynamicznego w celu ustalenia warunków w których rodzaj tarcia płynu zmienia się w rodzaj tarcia granicznego. Two-rzenie warunków, w których występuje jeden rodzaj tarcia pozwala na dokonanie świadomego korzystania z tej wiedzy do projektowania łożysk ślizgowych z niskim współczynnikiem tarcia i wysokiej wytrzymałości bez przerywania filmu i występowaniu ewentualnych procesów zużywania tylko w momentach rozruchu i zatrzymania