Vacancy ordering effects on the conductivity of yttria- and scandia-doped zirconia

Polarizable interaction potentials, parametrized using ab initio electronic structure calculations, have been used in molecular dynamics simulations to study the conduction mechanism in Y2 O3 - and Sc2 O3 -doped zirconias. The influence of vacancy-vacancy and vacancy-cation interactions on the conductivity of these materials has been characterised. While the latter can be avoided by using dopant cations with radii which match those of Zr4+ (as is the case of Sc3+), the former is an intrinsic characteristic of the fluorite lattice which cannot be avoided and which is shown to be responsible for the occurrence of a maximum in the conductivity at dopant concentrations between 8 and 13 %. The weakness of the Sc-vacancy interactions in Sc2 O3 -doped zirconia suggests that this material is likely to present the highest conductivity achievable in zirconias.Comment: 17 pages, 6 figur

BIRP: Software for interactive search and retrieval of image engineering data

Better Image Retrieval Programs (BIRP), a set of programs to interactively sort through and to display a database, such as engineering data for images acquired by spacecraft is described. An overview of the philosophy of BIRP design, the structure of BIRP data files, and examples that illustrate the capabilities of the software are provided

Management Buyouts: Creating or Appropriating Shareholder Wealth?

The name of the game in corporate America today is leverage.Whether through leveraged buyouts\u27 or leveraged recapitalizations, many of the United States\u27 largest corporations are rapidly trading equity capital for debt.\u27 This trend began only a few years ago when a small group of financial entrepreneurs, which included Carl Icahn, T.Boone Pickens, Asher Edelman,\u27 Irwin Jacobs, and Ronald Perelman, found that they could finance large stock purchases of major corporations through the use of high-yield ( junk ) bonds\u27 leading to either an acquisition of the target or its forced restructuring. The general goal of these financiers was to force a reconciliation between what they perceived as low stock prices and corporate assets of far greater potential value. Their efforts have been tremendously profitable. The corporate targets of these hostile share acquisitions, however,did not sit idly by and wait to have their shares gobbled up. The defenses they erected are now. famous because of their frequent use and colorful names: the Pac-Man defense, the scorched earth defense, shark repellents and poison pills. \u27 While these defenses proved to be an initial deterrent to hostile acquisitions, more creative financing techniques and other offensive weapons have rendered these defenses something of a Maginot Line. Target managements, searching for away to protect their shareholders, their jobs, or both, increasingly have taken the approach of fighting fire with fire-that is, using leverage and redeployment of assets in an attempt to create for themselves the same profits sought by the hostile bidder. The present-day management buyout developed primarily as a defensive response to the attacks of the financial entrepreneurs and other acquisition hungry companies. Top executives who became the equity holders in the private companies that followed buyouts generally have found this new defense as enormously profitable as the comparable offensive purchases of the financiers who initiated the first round of lever-aged stock acquisitions. Likewise, the leveraged recapitalization can be viewed largely as management\u27s attempt to effect the same reconciliation of values between stock prices and corporate assets by which a hostile bidder seeks to profit, while keeping the company independent with ownership continuing in the hands of the public shareholders.Here too, however, management will often grab a slice of the equity pie as an incentive booster in the course of revamping the corporation\u27s capital structure. It appears that like buyouts, top executives find the leveraged recapitalization quite profitable

Synthesis of Colloidal Mn2+:ZnO Quantum Dots and High-TC Ferromagnetic Nanocrystalline Thin Films

We report the synthesis of colloidal Mn2+-doped ZnO (Mn2+:ZnO) quantum dots and the preparation of room-temperature ferromagnetic nanocrystalline thin films. Mn2+:ZnO nanocrystals were prepared by a hydrolysis and condensation reaction in DMSO under atmospheric conditions. Synthesis was monitored by electronic absorption and electron paramagnetic resonance (EPR) spectroscopies. Zn(OAc)2 was found to strongly inhibit oxidation of Mn2+ by O2, allowing the synthesis of Mn2+:ZnO to be performed aerobically. Mn2+ ions were removed from the surfaces of as-prepared nanocrystals using dodecylamine to yield high-quality internally doped Mn2+:ZnO colloids of nearly spherical shape and uniform diameter (6.1 +/- 0.7 nm). Simulations of the highly resolved X- and Q-band nanocrystal EPR spectra, combined with quantitative analysis of magnetic susceptibilities, confirmed that the manganese is substitutionally incorporated into the ZnO nanocrystals as Mn2+ with very homogeneous speciation, differing from bulk Mn2+:ZnO only in the magnitude of D-strain. Robust ferromagnetism was observed in spin-coated thin films of the nanocrystals, with 300 K saturation moments as large as 1.35 Bohr magneton/Mn2+ and TC > 350 K. A distinct ferromagnetic resonance signal was observed in the EPR spectra of the ferromagnetic films. The occurrence of ferromagnetism in Mn2+:ZnO and its dependence on synthetic variables are discussed in the context of these and previous theoretical and experimental results.Comment: To be published in the Journal of the American Chemical Society Web on July 14, 2004 (http://dx.doi.org/10.1021/ja048427j

Cation composition effects on oxide conductivity in the Zr_2Y_2O_7-Y_3NbO_7 system

Realistic, first-principles-based interatomic potentials have been used in molecular dynamics simulations to study the effect of cation composition on the ionic conductivity in the Zr2Y2O7-Y3NbO7 system and to link the dynamical properties to the degree of lattice disorder. Across the composition range, this system retains a disordered fluorite crystal structure and the vacancy concentration is constant. The observed trends of decreasing conductivity and increasing disorder with increasing Nb5+ content were reproduced in simulations with the cations randomly assigned to positions on the cation sublattice. The trends were traced to the influences of the cation charges and relative sizes and their effect on vacancy ordering by carrying out additional calculations in which, for example, the charges of the cations were equalised. The simulations did not, however, reproduce all the observed properties, particularly for Y3NbO7. Its conductivity was significantly overestimated and prominent diffuse scattering features observed in small area electron diffraction studies were not always reproduced. Consideration of these deficiencies led to a preliminary attempt to characterise the consequence of partially ordering the cations on their lattice, which significantly affects the propensity for vacancy ordering. The extent and consequences of cation ordering seem to be much less pronounced on the Zr2Y2O7 side of the composition range.Comment: 22 pages, 8 figures, submitted to Journal of Physics: Condensed Matte

Price Discount Perception: Consumers\u27 Numeric Interpretation of Semantic Price Claims

Behavioral pricing research includes a considerable amount of focus on the effects of semantic cues (phrases) used to label reference and offer prices in price promotions, but a related type of semantic claim also frequently used in price promotions has continued to escape research attention - claims that attempt to encourage purchases by describing the consequences of buying at the discounted price (e.g. Super Savings). Using a variety of methods and conceptual foundations, the present research is the first to comprehensively study consumers\u27 discount and value associations of these semantic claims. In a series of three studies, we find evidence suggesting that at least some semantic claims have consistent numerical interpretations and a subset of those were found to influence discount expectations and perceptions of both transaction and acquisition value. These findings suggest the importance of recognizing that consumers may associate specific claims with certain discount magnitudes

The Angular Momentum Evolution of 0.1-10 Msun Stars From the Birthline to the Main Sequence

(Abridged) Projected rotational velocities (vsini) have been measured for a sample of 145 stars with masses between 0.4 and >10 Msun (median mass 2.1 Msun) located in the Orion star-forming complex. These measurements have been supplemented with data from the literature for Orion stars with masses as low as 0.1 Msun. The primary finding from analysis of these data is that the upper envelope of the observed values of angular momentum per unit mass (J/M) varies as M^0.25 for stars on convective tracks having masses in the range ~0.1 to ~3 Msun. This power law extends smoothly into the domain of more massive stars (3 to 10 Msun), which in Orion are already on the ZAMS. This result stands in sharp contrast to the properties of main sequence stars, which show a break in the power law and a sharp decline in J/M with decreasing mass for stars with M <2 Msun. A second result of our study is that this break is seen already among the PMS stars in our Orion sample that are on radiative tracks, even though these stars are only a few million years old. A comparison of rotation rates seen for stars on either side of the convective-radiative boundary shows that stars do not rotate as solid bodies during the transition from convective to radiative tracks.Comment: to appear in Ap

Dynamical segregation of galaxies in groups and clusters

We have performed a systematic analysis of the dynamics of different galaxy populations in galaxy groups from the 2dFGRS. For this purpose we have combined all the groups into a single system, where velocities v and radius r are expressed adimensionally. We have used several methods to compare the distributions of relative velocities of galaxies with respect to the group centre for samples selected according to their spectral type (as defined by Madgwick et al., 2002), bj band luminosity and B-R colour index. We have found strong segregation effects: spectral type I objects show a statistically narrower velocity distribution than that of galaxies with a substantial star formation activity (type II-IV). Similarly, the same behavior is observed for galaxies with colour index B-R>1 compared to galaxies with B-R<1. Bright (Mb-19) galaxies show the same segregation. It is not important once the sample is restricted to a given spectral type. These effects are particularly important in the central region (Rp<Rvirial/2) and do not have a strong dependence on the mass of the parent group. These trends show a strong correlation between the dynamics of galaxies in groups and star formation rate reflected both by spectral type and by colour index.Comment: 7 pages, 8 figures. Accepted for publication in MNRA

Experimentally induced community assembly of polypores reveals the importance of both environmental filtering and assembly history

The community assembly of wood-inhabiting fungi follows a successional pathway, with newly emerging resource patches being colonised by pioneer species, followed by those specialised on later stages of decay. The primary coloniser species have been suggested to strongly influence the assembly of the later-arriving community. We created an artificial resource pulse and studied the assembly of polypores over an 11yr period to ask how the identities of the colonising species depend on the environmental characteristics and the assembly history of the dead wood unit. Our results support the view that community assembly in fungi is a highly stochastic process, as even detailed description of the characteristics of dead wood (host tree species, size, decay class of the resource unit, its bark cover and how sunken it is to the ground) and the prior community structure provided only limited predictive power on the newly colonising species. Yet, we identified distinct links between primary and secondary colonising species and showed how the spatial aggregation of dead wood had a great impact on the community assembly. © 2019 Elsevier Ltd and British Mycological SocietyPeer reviewe