9 research outputs found
Interpreting and reporting ⁴⁰Ar/³⁹Ar geochronologic data
The ⁴⁰Ar/³⁹Ar dating method is among the most versatile of geochronometers, having the potential to date a broad variety of K-bearing materials spanning from the time of Earth’s formation into the historical realm. Measurements using modern noble-gas mass spectrometers are now producing ⁴⁰Ar/³⁹Ar dates with analytical uncertainties of ∼0.1%, thereby providing precise time constraints for a wide range of geologic and extraterrestrial processes. Analyses of increasingly smaller subsamples have revealed age dispersion in many materials, including some minerals used as neutron fluence monitors. Accordingly, interpretive strategies are evolving to address observed dispersion in dates from a single sample. Moreover, inferring a geologically meaningful “age” from a measured “date” or set of dates is dependent on the geological problem being addressed and the salient assumptions associated with each set of data. We highlight requirements for collateral information that will better constrain the interpretation of ⁴⁰Ar/³⁹Ar data sets, including those associated with single-crystal fusion analyses, incremental heating experiments, and in situ analyses of microsampled domains. To ensure the utility and viability of published results, we emphasize previous recommendations for reporting ⁴⁰Ar/³⁹Ar data and the related essential metadata, with the amendment that data conform to evolving standards of being findable, accessible, interoperable, and reusable (FAIR) by both humans and computers. Our examples provide guidance for the presentation and interpretation of ⁴⁰Ar/³⁹Ar dates to maximize their interdisciplinary usage, reproducibility, and longevity
Mediterranean winter rainfall in phase with African monsoons during the past 1.36 million years
Mediterranean climates are characterized by strong seasonal contrasts between dry summers and wet winters. Changes in winter rainfall are critical for regional socioeconomic development, but are difficult to simulate accurately1 and reconstruct on Quaternary timescales. This is partly because regional hydroclimate records that cover multiple glacial–interglacial cycles2,3 with different orbital geometries, global ice volume and atmospheric greenhouse gas concentrations are scarce. Moreover, the underlying mechanisms of change and their persistence remain unexplored. Here we show that, over the past 1.36 million years, wet winters in the northcentral Mediterranean tend to occur with high contrasts in local, seasonal insolation and a vigorous African summer monsoon. Our proxy time series from Lake Ohrid on the Balkan Peninsula, together with a 784,000-year transient climate model hindcast, suggest that increased sea surface temperatures amplify local cyclone development and refuel North Atlantic low-pressure systems that enter the Mediterranean during phases of low continental ice volume and high concentrations of atmospheric greenhouse gases. A comparison with modern reanalysis data shows that current drivers of the amount of rainfall in the Mediterranean share some similarities to those that drive the reconstructed increases in precipitation. Our data cover multiple insolation maxima and are therefore an important benchmark for testing climate model performance
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Intercalibration and age of the Alder Creek sanidine 40Ar/39Ar standard
The accuracy of 40Ar/39Ar geochronology relies in large part on precise and accurate calibration of the ages and K-Ar isotopic compositions of standards. A widely used standard for Quaternary samples, the ∼1.2 Ma Alder Creek sanidine (ACs), has published ages spanning a range of ∼2%. New measurements of ACs co-irradiated with the Fish Canyon sanidine (FCs) standard and sanidines from astronomically dated Miocene tuffs in Crete and Morocco yield results that enable both (i) a direct calibration of ACs relative to FCs, and (ii) stepwise calibrations between these two standards employing the Miocene intermediaries. Results are summarized by the parameter RFCsACs, defined as the ratio of (40Ar*/39ArK) of ACs to FCs, which embodies the fundamental age relationship between these standards that is independent of systematic variables such as decay constants or absolute ages of standards. Our new measurements, executed using three mass spectrometers and various irradiation and analytical protocols, yield a weighted mean RFCsACs = 0.041702 ± 0.000014 (σ). This result can be combined with previously published determinations of R values for ACs relative to the Miocene tuffs and to FCs to yield a recommended interlaboratory value ofRFCsACs = 0.041707 ± 0.000011. The weighted-mean age of ACs using this interlaboratory value, based on astronomically-calibrated ages of FCs and the Miocene intermediary sanidines, is tACs = 1.1848 ± 0.0006 Ma (±0.05%). Applying this result to the most precise published 40Ar/39Ar data for the Matuyama-Brunhes geomagnetic polarity reversal yields tMBB = 780.1 ± 0.8 ka. In addition, these new data for ACs support previous conclusions that U-Pb zircon ages from the Alder Creek rhyolite incorporate ∼13 ka of pre-eruptive residence time
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Terrestrial records of deglaciation events during terminations V and IV in the central Apennines (Italy) and insights on deglacial mechanisms.
40Ar/39Ar geochronology constraints to aggradational phases and grain size variations show that the two large gravel beds occurring in the sedimentary filling of the Liri fluvial-lacustrine basin (central Italy) recorded the occurrence of deglaciation events synchronous within uncertainties with global meltwater pulses at ca. 450 and 350 ka. In particular, we find a precise match between the ages of gravel deposition and the occurrence of moderate sea-level rise events which anticipate those more marked during the glacial termination V and IV in the Red Sea relative sea level curve, as already verified by data from the Tiber River catchment basin. Such correspondence suggests that gravel deposition is facilitated by melting of Apennine mountain range glaciers, which provide the water transport energy and a surplus of clastic input to the rivers draining the mountain regions and flowing into the Tyrrhenian Sea. Therefore, the thick gravel beds intercalated in the sedimentary filling of the catchment basins of the major rivers in central Italy may be regarded as an equivalent proxy of large deglaciation events, similar to the ice-rafted debris in northern Atlantic. Consistent with this hypothesis, we also show the close correspondence between the occurrence of particularly mild (warmer) minima of the mean summer insolation at 65° N and these early aggradational phases, as well as with other anomalous early sea-level rises occurring c. 750 ka and 540 ka at the onset of glacial termination VIII and VI, and 40 ka at the onset of the so-called Heinrich events
Evidence for a large magnitude eruption from Campi Flegrei caldera (Italy) at 29 ka
The 40 ka caldera-forming eruption of Campi Flegrei (Italy) is the largest known eruption in Europe during the last 200 kyr, but little is known about other large eruptions at the volcano prior to a more recent caldera-forming event at 15 ka. At 29 ka a widespread volcanic ash layer, termed the Y-3 tephra, covered >150,000 km2 of the Mediterranean. The glass compositions of the layer are consistent with Campi Flegrei being the source but no prominent proximal equivalent in the appropriate chrono-stratigraphic position had been previously identified. Here we report new glass chemistry data and 40Ar/39Ar ages (29.3 ± 0.7 ka [2σ]) that reveal the near-source Y-3 eruption deposit in a sequence at Ponti Rossi and a nearby borehole (S-19) in Naples. The dispersal and thickness of the deposits associated with this eruption, herein named the Masseria del Monte Tuff, were simulated using a tephra sedimentation model. The model indicates that ~16 km3 DRE (dense rock equivalent) of the magma erupted was deposited as fall. This volume and the areal distribution suggest the Masseria del Monte Tuff was a magnitude 6.6 eruption (corresponding to VEI 6), similar to the 15 ka caldera-forming Neapolitan Yellow Tuff (M6.8) eruption at Campi Flegrei. However, the lack of coarse, thick, traceable, near-vent deposit suggests peculiar eruption dynamics. Our reconstruction and modelling of the eruption show the fundamental role that distal tephrostratigraphy can play in constraining the scale and tempo of past activity, especially at highly productive volcanoe