12,220 research outputs found
Dynamical Exchanges in Facilitated Models of Supercooled liquids
We investigate statistics of dynamical exchange events in coarse--grained
models of supercooled liquids in spatial dimensions , 2, and 3. The
models, based upon the concept of dynamical facilitation, capture generic
features of statistics of exchange times and persistence times. Here,
distributions for both times are related, and calculated for cases of strong
and fragile glass formers over a range of temperatures. Exchange time
distributions are shown to be particularly sensitive to the model parameters
and dimensions, and exhibit more structured and richer behavior than
persistence time distributions. Mean exchange times are shown to be Arrhenius,
regardless of models and spatial dimensions. Specifically, , with being the excitation concentration. Different dynamical
exchange processes are identified and characterized from the underlying
trajectories. We discuss experimental possibilities to test some of our
theoretical findings.Comment: 11 pages, 14 figures, minor corrections made, paper published in
Journal of Chemical Physic
Measuring galaxy [OII] emission line doublet with future ground-based wide-field spectroscopic surveys
The next generation of wide-field spectroscopic redshift surveys will map the
large-scale galaxy distribution in the redshift range 0.7< z<2 to measure
baryonic acoustic oscillations (BAO). The primary optical signature used in
this redshift range comes from the [OII] emission line doublet, which provides
a unique redshift identification that can minimize confusion with other single
emission lines. To derive the required spectrograph resolution for these
redshift surveys, we simulate observations of the [OII] (3727,3729) doublet for
various instrument resolutions, and line velocities. We foresee two strategies
about the choice of the resolution for future spectrographs for BAO surveys.
For bright [OII] emitter surveys ([OII] flux ~30.10^{-17} erg /cm2/s like
SDSS-IV/eBOSS), a resolution of R~3300 allows the separation of 90 percent of
the doublets. The impact of the sky lines on the completeness in redshift is
less than 6 percent. For faint [OII] emitter surveys ([OII] flux ~10.10^{-17}
erg /cm2/s like DESi), the detection improves continuously with resolution, so
we recommend the highest possible resolution, the limit being given by the
number of pixels (4k by 4k) on the detector and the number of spectroscopic
channels (2 or 3).Comment: 5 pages, 1 figur
Diphenylphosphinoyl chloride as a chlorinating agent - The selective double activation of 1,2-diols
© The Royal Society of Chemistry 2006Treatment of 1,2-diols with diphenylphosphinoyl chloride in pyridine produces beta-chloroethyl phosphinates which react with complete control of stereochemistry to give epoxides and azido-alcohols, useful intermediates in cyclopropane synthesis.David J. Fox, Daniel Sejer Pedersen, Asger B. Petersen and Stuart Warre
Using Molecular-Level Simulations to Determine Diffusivities in the Classroom
We present work describing the practical use of molecular-level simulations to determine diffusivities in a course targeted at the general audience of first-year chemical engineering graduate students. We show how the simulation techniques can be used to directly complement traditional methods for obtaining diffusivities. Our philosophy is to provide a utilitarian tool that can be used in a manner analogous to existing techniques to obtain diffusion coefficients. The advantage of the simulation approach is that it will work in the absence of experimental data and can be easily applied to multicomponent mixtures with an arbitrary number of species. In the implementation of this work, we remain keenly aware of constraints due to time, computational resources, money, and target-audience qualifications, so that the implementation is feasible. We demonstrate that these simulations require only a few minutes to run on a contemporary (AMD Athlon 850 MHz) processor. In our approach we outline the basic steps necessary to obtain a transport diffusivity via molecular-level simulations. We also provide an example problem, where we compare the results of the simulation to the predictions from corresponding states and kinetic theory
Quantum Monte Carlo study of a magnetic-field-driven 2D superconductor-insulator transition
We numerically study the superconductor-insulator phase transition in a model
disordered 2D superconductor as a function of applied magnetic field. The
calculation involves quantum Monte Carlo calculations of the (2+1)D XY model in
the presence of both disorder and magnetic field. The XY coupling is assumed to
have the form -J\cos(\theta_i-\theta_j-A_{ij}), where A_{ij} has a mean of zero
and a standard deviation \Delta A_{ij}. In a real system, such a model would be
approximately realized by a 2D array of small Josephson-coupled grains with
slight spatial disorder and a uniform applied magnetic field. The different
values \Delta A_{ij} then corresponds to an applied field such that the average
number of flux quanta per plaquette has various integer values N: larger N
corresponds to larger \Delta A_{ij}. For any value of \Delta A_{ij}, there
appears to be a critical coupling constant K_c(\Delta
A_{ij})=\sqrt{[J/(2U)]_c}, where U is the charging energy, above which the
system is a Mott insulator; there is also a corresponding critical conductivity
\sigma^*(\Delta A_{ij}) at the transition. For \Delta A_{ij}=\infty, the order
parameter of the transition is a renormalized coupling constant g. Using a
numerical technique appropriate for disordered systems, we show that the
transition at this value of \Delta A_{ij} takes place from an insulating (I)
phase to a Bose glass (BG) phase, and that the dynamical critical exponent
characterizing this transition is z \sim 1.3. By contrast, z=1 for this model
at \Delta A_{ij}=0. We suggest that the superconductor to insulator transition
is actually of this I to BG class at all nonzero \Delta A_{ij}'s, and we
support this interpretation by both numerical evidence and an analytical
argument based on the Harris criterion.Comment: 17 pages, 23 figures, accepted for publication in Phys. Rev.
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