782 research outputs found
Versatile Coordination of Cyclopentadienyl-Arene Ligands and Its Role in Titanium-Catalyzed Ethylene Trimerization
Cationic titanium(IV) complexes with ansa-(η5-cyclopentadienyl,η6-arene) ligands were synthesized and characterized by X-ray crystallography. The strength of the metal-arene interaction in these systems was studied by variable-temperature NMR spectroscopy. Complexes with a C1 bridge between the cyclopentadienyl and arene moieties feature hemilabile coordination behavior of the ligand and consequently are active ethylene trimerization catalysts. Reaction of the titanium(IV) dimethyl cations with CO results in conversion to the analogous cationic titanium(II) dicarbonyl species. Metal-to-ligand backdonation in these formally low-valent complexes gives rise to a strongly bonded, partially reduced arene moiety. In contrast to the η6-arene coordination mode observed for titanium, the more electron-rich vanadium(V) cations [cyclopentadienyl-arene]V(NiPr2)(NC6H4-4-Me)+ feature η1-arene binding, as determined by a crystallographic study. The three different metal-arene coordination modes that we experimentally observed model intermediates in the cycle for titanium-catalyzed ethylene trimerization. The nature of the metal-arene interaction in these systems was studied by DFT calculations.
Obscured Activity: AGN, Quasars, Starbursts and ULIGs observed by the Infrared Space Observatory
Some of the most active galaxies in the Universe are obscured by large
quantities of dust and emit a substantial fraction of their bolometric
luminosity in the infrared. Observations of these infrared luminous galaxies
with the Infrared Space Observatory (ISO) have provided a relatively unabsorbed
view to the sources fuelling this active emission. The improved sensitivity,
spatial resolution and spectroscopic capability of ISO over its predecessor
Infrared Astronomical Satellite (IRAS), has enabled significant advances in the
understanding of the infrared properties of active galaxies. ISO surveyed a
wide range of active galaxies which, in the context of this review, includes
those powered by intense bursts of star-formation as well as those containing a
dominant active galactic nucleus (AGN). Mid infrared imaging resolved for the
first time the dust enshrouded nuclei in many nearby galaxies, while a new era
in infrared spectroscopy was opened by probing a wealth of atomic, ionic and
molecular lines as well as broad band features in the mid and far infrared.
This was particularly useful since it resulted in the understanding of the
power production, excitation and fuelling mechanisms in the nuclei of active
galaxies including the intriguing but so far elusive ultraluminous infrared
galaxies. Detailed studies of various classes of AGN and quasars greatly
improved our understanding of the unification scenario. Far-infrared imaging
and photometry also revealed the presence of a new very cold dust component in
galaxies and furthered our knowledge of the far-infrared properties of faint
starbursts, ULIGs and quasars. We summarise almost nine years of key results
based upon ISO data spanning the full range of luminosity and type of active
galaxies.Comment: Accepted for publication in 'ISO science legacy - a compact review of
ISO major achievements', Space Science Reviews - dedicated ISO issue. To be
published by Springer in 2005. 62 pages (low resolution figures version).
Higher resolution PDFs available from
http://users.physics.uoc.gr/~vassilis/papers/VermaA.pdf or
http://www.iso.vilspa.esa.es/science/SSR/Verma.pd
Energy scan of the cross sections and evidence for decays into charged bottomonium-like states
Using data collected with the Belle detector at the KEKB asymmetric-energy
collider, we measure the energy dependence of the cross sections from thresholds up to GeV.
We find clear and peaks with little or no
continuum contribution. We study the resonant substructure of the
transitions and find evidence that they
proceed entirely via the intermediate isovector states and
. The relative fraction of these states is loosely constrained by
the current data: the hypothesis that only is produced is excluded
at the level of 3.3 standard deviations, while the hypothesis that only
is produced is not excluded at a significant level.Comment: 8 pages, 4 figures, submitted to Physical Review Letter
Study of Excited States Decaying into and Baryons
Using a data sample of 980 of annihilation data
taken with the Belle detector operating at the KEKB asymmetric-energy
collider, we report the results of a study of excited states that
decay, via the emission of photons and/or charged pions, into or
ground state charmed-strange baryons. We present new measurements of
the masses of all members of the , ,
, , and isodoublets, measurements of
the intrinsic widths of those that decay strongly, and evidence of previously
unknown transitions.Comment: Submitted to PR
Search for a massive invisible particle in and decays
We present a search for a non-Standard-Model invisible particle in the
mass range in and
decays. The results are obtained from a data sample that corresponds to pairs,
collected at the resonance with the Belle detector at the KEKB
collider. One meson is fully reconstructed in a hadronic mode to
determine the momentum of the lepton of the signal decay in the rest frame of
the recoiling partner meson. We find no evidence of a signal and set upper
limits on the order of .Comment: 8 pages, 4 figures, 3 table
Heavy-light mesons in the epsilon-regime
We study the finite-size scaling of heavy-light mesons in the static limit.
We compute two-point functions of chiral current densities as well as
pseudoscalar densities in the epsilon-regime of heavy meson Chiral Perturbation
Theory (HMChPT). As expected, finite volume dependence turns out to be
significant in this regime and can be predicted in the effective theory in
terms of the infinite-volume low-energy couplings. These results might be
relevant for extraction of heavy-meson properties from lattice simulations.Comment: 32 pages, 4 figure
First Observation of Doubly Cabibbo-Suppressed Decay of a Charmed Baryon:
We report the first observation of the decay using a 980 data sample collected by the
Belle detector at the KEKB asymmetric-energy collider. This is the
first doubly Cabibbo-suppressed decay of a charmed baryon to be observed. We
measure the branching ratio of this decay with respect to its Cabibbo-favored
counterpart to be , where the uncertainties are
statistical and systematic, respectively.Comment: 6 pages, 3 figure
First model-independent Dalitz analysis of , decay
We report a measurement of the amplitude ratio of
and decays with a Dalitz analysis of decays, for the first time using a model-independent method.
We set an upper limit at the 68\% confidence level, using the full
data sample of pairs collected at the
resonance with the Belle detector at the KEKB collider. This result is
obtained from observables , , and , where , and
is the weak (strong) phase difference between and .Comment: arXiv admin note: substantial text overlap with arXiv:1502.0755
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