Rheological study of structural transitions in triblock copolymers in a liquid crystal solvent

Rheological properties of triblock copolymers dissolved in a nematic liquid crystal (LC) solvent demonstrate that their microphase separated structure is heavily influenced by changes in LC order. Nematic gels were created by swelling a well-defined, high molecular weight ABA block copolymer with the small-molecule nematic LC solvent 4-pentyl-4-cyanobiphenyl (5CB). The B midblock is a side-group liquid crystal polymer (SGLCP) designed to be soluble in 5CB and the A endblocks are polystyrene, which is LC-phobic and microphase separates to produce a physically cross-linked, thermoreversible, macroscopic polymer network. At sufficiently low polymer concentration a plateau modulus in the nematic phase, characteristic of a gel, abruptly transitions to terminal behavior when the gel is heated into its isotropic phase. In more concentrated gels, endblock aggregates persist into the isotopic phase. Dramatic changes in network structure are observed over small temperature windows (as little as 1 °C) due to tccche rapidly changing LC order near the isotropization point. The discontinuous change in solvent quality produces an abrupt change in viscoelastic properties for three polymers having different pendant mesogenic groups and matched block lengths

Statistical properties of fractures in damaged materials

We introduce a model for the dynamics of mud cracking in the limit of of extremely thin layers. In this model the growth of fracture proceeds by selecting the part of the material with the smallest (quenched) breaking threshold. In addition, weakening affects the area of the sample neighbour to the crack. Due to the simplicity of the model, it is possible to derive some analytical results. In particular, we find that the total time to break down the sample grows with the dimension L of the lattice as L^2 even though the percolating cluster has a non trivial fractal dimension. Furthermore, we obtain a formula for the mean weakening with time of the whole sample.Comment: 5 pages, 4 figures, to be published in Europhysics Letter

PRESENCE AND PREVALENCE OF BD (BATRACHOCHYTRIUM DENDROBATIDIS) IN CENTRAL PENNSYLVANIAN WOODLAND VERNAL POOLS

Batrachochytrium dendrobatidis (Bd), a virulent chytrid fungus responsible for dramatic amphibian declines, has been detected in the northwestern and southeastern regions of Pennsylvania. However, little environmental Bd testing has been performed in central Pennsylvania, particularly in the unique and speciose habitats of woodland vernal pools. Our study included sampling in four vernal pools over a period of three months during amphibian breeding periods. Skin swabs were taken from three caudate and two anuran species, during the course of late winter and spring migrations (n = 143). Low Bd zoospore equivalent loads were detected in only a few individuals, in three of the five species but in all four vernal pools sampled. No significant trends were seen between zoospore loads and ambient temperature or migration timing across the species sampled

Oxidation processes in magneto-optic and related materials

The surface oxidation processes of thin films of magneto-optic materials, such as the rare-earth transition metal alloys have been studied, starting in ultrahigh vacuum environments, using surface analysis techniques, as a way of modeling the oxidation processes which occur at the base of a defect in an overcoated material, at the instant of exposure to ambient environments. Materials examined have included FeTbCo alloys, as well as those same materials with low percentages of added elements, such a Ta, and their reactivities to both O2 and H2O compared with materials such as thin Fe films coated with ultrathin adlayers of Ti. The surface oxidation pathways for these materials is reviewed, and XPS data presented which indicates the type of oxides formed, and a critical region of Ta concentration which provides optimum protection

Thickness dependence of spin-orbit torques generated by WTe2

We study current-induced torques in WTe2/permalloy bilayers as a function of WTe2 thickness. We measure the torques using both second-harmonic Hall and spin-torque ferromagnetic resonance measurements for samples with WTe2 thicknesses that span from 16 nm down to a single monolayer. We confirm the existence of an out-of-plane antidamping torque, and show directly that the sign of this torque component is reversed across a monolayer step in the WTe2. The magnitude of the out-of-plane antidamping torque depends only weakly on WTe2 thickness, such that even a single-monolayer WTe2 device provides a strong torque that is comparable to much thicker samples. In contrast, the out-of-plane field-like torque has a significant dependence on the WTe2 thickness. We demonstrate that this field-like component originates predominantly from the Oersted field, thereby correcting a previous inference drawn by our group based on a more limited set of samples.Comment: 8 pages, 8 figure

Abell 2111: An Optical and Radio Study of the Richest Butcher-Oemler Cluster

We present an in-depth analysis of the Butcher-Oemler cluster A2111, including new optical spectroscopy plus a deep Very Large Array (VLA) radio continuum observation. These are combined with optical imaging from the Sloan Digital Sky Survey (SDSS) to assess the activity and properties of member galaxies. Prior X-ray studies have suggested A2111 is a head-on cluster merger, a dynamical state which might be connected to the high level of activity inferred from its blue fraction. We are able to directly assess this claim, using our spectroscopic data to identify 95 cluster members among 196 total galaxy spectra. These galaxy velocities do not themselves provide significant evidence for the merger interpretation, however they are consistent with it provided the system is viewed near the time of core passage and at a viewing angle >~30 degrees different from the merger axis. The SDSS data allow us to confirm the high blue fraction for A2111, f_b = 0.15 +/- 0.03 based on photometry alone and f_b = 0.23 +/- 0.03 using spectroscopic data to remove background galaxies. We are able to detect 175 optical sources from the SDSS in our VLA radio data, of which 35 have redshift information. We use the SDSS photometry to determine photometric redshifts for the remaining 140 radio-optical sources. In total we identify up to 26 cluster radio galaxies, 14 of which have spectroscopic redshifts. The optical spectroscopy and radio data reveal a substantial population of dusty starbursts within the cluster. The high blue fraction and prevalence of star formation is consistent with the hypothesis that dynamically-active clusters are associated with more active member galaxies than relaxed clusters.Comment: To appear in AJ; 53 pages including 10 figures and several long table

Torque-Limited Growth of Massive Black Holes in Galaxies Across Cosmic Time

We combine cosmological hydrodynamic simulations with analytic models to evaluate the role of galaxy-scale gravitational torques on the evolution of massive black holes at the centers of star-forming galaxies. We confirm and extend our earlier results to show that torque-limited growth yields black holes and host galaxies evolving on average along the Mbh-Mbulge relation from early times down to z = 0 and that convergence onto the scaling relation occurs independent of the initial conditions and with no need for mass averaging through mergers or additional self-regulation processes. Smooth accretion dominates the long-term evolution, with black hole mergers with mass ratios >1:5 representing typically a small fraction of the total growth. Winds from the accretion disk are required to eject significant mass to suppress black hole growth, but there is no need for coupling this wind to galactic-scale gas to regulate black holes in a non-linear feedback loop. Torque-limited growth yields a close-to-linear relation for the star formation rate and the black hole accretion rate averaged over galaxy evolution time scales. However, the SFR-AGN connection has significant scatter owing to strong variability of black hole accretion at all resolved time scales. Eddington ratios can be described by a broad lognormal distribution with median value evolving roughly as (1 + z)^1.9, suggesting a main sequence for black hole growth similar to the cosmic evolution of specific SFRs. Our results offer an attractive scenario consistent with available observations in which cosmological gas infall and transport of angular momentum in the galaxy by gravitational instabilities regulate the long-term co-evolution of black holes and star-forming galaxies.Comment: 26 pages, 15 figures, replaced by published versio

The Observability of Metal Lines Associated with the Lyman-alpha Forest

We develop a prescription for characterizing the strengths of metal lines associated with Lyman-alpha forest absorbers (LYFAs) of a given neutral hydrogen column density N_HI and metallicity [Fe/H]. This Line Observability Index (LOX) is line-specific and translates, for weak lines, into a measure of the equivalent width. It can be evaluated quickly for thousands of transitions within the framework of a given model of the Lyman-alpha forest, providing a ranking of the lines in terms of their strengths and enabling model builders to select the lines that should be detectable in observed spectra of a given resolution and signal-to-noise ratio. We compute the LOX for a large number of elements and transitions in two cosmological models of the Lyman-alpha forest at z=3 derived from a hydrodynamic simulation of structure formation, and we discuss how the LOX depends on redshift and on model parameters such as the mean baryonic density and radiation field. We find that the OVI (1032,1038) doublet is the best probe of the metallicity in low column density LYFAs N_{HI} \approx 10^{14.5} cm^{-2}). Metallicities down to [O/H] \sim -3 ([Fe/H] \sim -3.5 with the assumed [O/Fe] ratio) yield OVI absorption features that should be detectable in current high-quality spectra, provided that the expected position of the OVI feature is not contaminated by HI absorption. The strongest transitions in lower ionisation states of oxygen are OV(630), OIV(788), and OIII(833), and are likely to be detected with next generation UV instruments. Of the lines with rest wavelengths \lambda_r > 1216, which can potentially be observed redwards of the \lya forest, the CIV(1548,1551) doublet is expected to dominate in all LYFAs, regardless of the value of N_HI.Comment: Substantially revised version: larger line database, additional cosmological model analyzed. Accepted for Ap