Comparison between two mobile absolute gravimeters: optical versus atomic interferometers

We report a comparison between two absolute gravimeters: the LNE-SYRTE cold atoms gravimeter and FG5#220 of Leibniz Universit\"at of Hannover. They rely on different principles of operation: atomic and optical interferometry. Both are movable which enabled them to participated to the last International Comparison of Absolute Gravimeters (ICAG'09) at BIPM. Immediately after, their bilateral comparison took place in the LNE watt balance laboratory and showed an agreement of 4.3 +/- 6.4 {\mu}Gal

Sediment release of dissolved organic matter in the oxygen minimum zone off Peru

In combination to sluggish ventilation by ocean currents, the nutrient upwelling and high surface productivity, followed by organic matter remineralization, leads to a pronounced oxygen minimum zone (OMZ) in the eastern tropical South Pacific (ETSP). There, oxygen concentrations drop below 1 �mol/kg at a water depth <80 m. The high productivity results in the supply of organic matter (OM) to the anoxic sediments and its utilization by heterotrophic communities. The microbial utilization of OM under anoxia leads to nitrogen loss processes, and an accumulation of sulphide and methane. The proximity of the OMZ to the ocean surface in the ETSP may lead to an active outgassing of climate relevant products of the anoxic OM remineralization. The degradation of OM in sediments is associated with production of dissolved organic matter (DOM) from organic particles (POM) that is further remineralized into inorganic nutrients and dissolved inorganic carbon, which then can be released back to the water column, fuelling productivity. Part of the DOM pool may be released to the overlying water column and serve as ligands for micronutrients, such as iron, or provide an additional substrate for microbial communities to respire, affecting overlying water column biogeochemistry. Despite the potential relevance for biogeochemical processes, the quality of the DOM in the pore waters that may be released to the overlying water column has been barely studied in the ETSP off Peru. High spatial resolution measurements of DOM fluorescence (FDOM) during the research cruise M93 (Feb-March 2013) indicated elevated intensities near the sediments in the ETSP off Peru. Those intensities were interpreted as a sediment release of DOM, the quantification of dissolved organic carbon (DOC) flux, however, was not possible at the time. To estimate DOM fluxes and DOM quality, DOC and DOM samples were collected from the sediment pore waters and from benthic incubation chambers from six stations along the 12°S transect in the Peruvian upwelling in 2017 (cruises M136, M137). Samples were collected using a multiple-corer and by Biogeochemical Observatories, respectively. Here, we evaluate DOC fluxes from the sediments and relate them to the measurements of FDOM. We evaluate the quality of DOM by Excitation Emission spectroscopy, followed by parallel factor analysis. The possible implications of the DOM release for water column biogeochemistry are discussed

Segmentation of the Himalayas as revealed by arc-parallel gravity anomalies

International audienceLateral variations along the Himalayan arc are suggested by an increasing number of studies and carry important information about the orogen’s segmentation. Here we compile the hitherto most complete land gravity dataset in the region which enables the currently highest resolution plausible analysis. To study lateral variations in collisional structure we compute arc-parallel gravity anomalies (APaGA) by subtracting the average arc-perpendicular profile from our dataset; we compute likewise for topography (APaTA). We find no direct correlation between APaGA, APaTA and background seismicity, as suggested in oceanic subduction context. In the Himalayas APaTA mainly reflect relief and erosional effects, whereas APaGA reflect the deep structure of the orogen with clear lateral boundaries. Four segments are outlined and have disparate flexural geometry: NE India, Bhutan, Nepal & India until Dehradun, and NW India. The segment boundaries in the India plate are related to inherited structures, and the boundaries of the Shillong block are highlighted by seismic activity. We find that large earthquakes of the past millennium do not propagate across the segment boundaries defined by APaGA, therefore these seem to set limits for potential rupture of megathrust earthquakes

Long-lived photoexcited states in polydiacetylenes with different molecular and supramolecular organization

With the aim of determining the importance of the molecular and supramolecular organization on the excited states of polydiacetylenes, we have studied the photoinduced absorption spectra of the red form of poly[1,6-bis(3,6-didodecyl-N-carbazolyl)-2,4-hexadiyne] (polyDCHD-S) and the results compared with those of the blue form of the same polymer. An interpretation of the data is given in terms of both the conjugation length and the interbackbone separation also in relation to the photoinduced absorption spectra of both blue and red forms of poly[1,6-bis(N-carbazolyl)-2,4-hexadiyne] (polyDCHD), which does not carry the alkyl substituents on the carbazolyl side groups. Information on the above properties is derived from the analysis of the absorption and Raman spectra of this class of polydiacetylenes

Carbon sequestration in the deep Atlantic enhanced by Saharan dust

Enhanced atmospheric input of dust-borne nutrients and minerals to the remote surface ocean can potentially increase carbon uptake and sequestration at depth. Nutrients can enhance primary productivity, and mineral particles act as ballast, increasing sinking rates of particulate organic matter. Here we present a two-year time series of sediment trap observations of particulate organic carbon flux to 3,000 m depth, measured directly in two locations: the dust-rich central North Atlantic gyre and the dust-poor South Atlantic gyre. We find that carbon fluxes are twice as high and a higher proportion of primary production is exported to depth in the dust-rich North Atlantic gyre. Low stable nitrogen isotope ratios suggest that high fluxes result from the stimulation of nitrogen fixation and productivity following the deposition of dust-borne nutrients. Sediment traps in the northern gyre also collected intact colonies of nitrogen-fixing Trichodesmium species. Whereas ballast in the southern gyre is predominantly biogenic, dust-derived mineral particles constitute the dominant ballast element during the enhanced carbon fluxes in the northern gyre. We conclude that dust deposition increases carbon sequestration in the North Atlantic gyre through the fertilization of the nitrogen-fixing community in surface waters and mineral ballasting of sinking particles