1,054 research outputs found
Asymptotic tunneling conductance in Luttinger liquids
Conductance through weak constrictions in Luttinger liquids is shown to
vanish with frequency as , where
is a dimensionless parameter characterizing the Luttinger liquid phase, and
and are nonuniversal constants. The first term arises from the ^^
Coulomb blockade' effect and dominates for , whereas the second
results from eliminating high-energy modes and dominates for .Comment: Latex file + one appended postcript figur
Surface Core Level Shifts of Clean and Oxygen Covered Ru(0001)
We have performed high resolution XPS experiments of the Ru(0001) surface,
both clean and covered with well-defined amounts of oxygen up to 1 ML coverage.
For the clean surface we detected two distinct components in the Ru 3d_{5/2}
core level spectra, for which a definite assignment was made using the high
resolution Angle-Scan Photoelectron Diffraction approach. For the p(2x2),
p(2x1), (2x2)-3O and (1x1)-O oxygen structures we found Ru 3d_{5/2} core level
peaks which are shifted up to 1 eV to higher binding energies. Very good
agreement with density functional theory calculations of these Surface Core
Level Shifts (SCLS) is reported. The overriding parameter for the resulting Ru
SCLSs turns out to be the number of directly coordinated O atoms. Since the
calculations permit the separation of initial and final state effects, our
results give valuable information for the understanding of bonding and
screening at the surface, otherwise not accessible in the measurement of the
core level energies alone.Comment: 16 pages including 10 figures. Submitted to Phys. Rev. B. Related
publications can be found at http://www.fhi-berlin.mpg.de/th/paper.htm
Bonding, Moment Formation, and Magnetic Interactions in Ca14MnBi11 and Ba14MnBi11
The ``14-1-11'' phase compounds based on magnetic Mn ions and typified by
Ca14MnBi11 and Ba14MnBi11 show unusual magnetic behavior, but the large number
(104) of atoms in the primitive cell has precluded any previous full electronic
structure study. Using an efficient, local orbital based method within the
local spin density approximation to study the electronic structure, we find a
gap between a bonding valence band complex and an antibonding conduction band
continuum. The bonding bands lack one electron per formula unit of being
filled, making them low carrier density p-type metals. The hole resides in the
MnBi4 tetrahedral unit and partially compensates the high spin d^5 Mn moment,
leaving a net spin near 4 \mu_B that is consistent with experiment. These
manganites are composed of two disjoint but interpenetrating `jungle gym'
networks of spin 4/2 MnBi4^{9-} units with ferromagnetic interactions within
the same network, and weaker couplings between the networks whose sign and
magnitude is sensitive to materials parameters. Ca14MnBi11 is calculated to be
ferromagnetic as observed, while for Ba14MnBi11 (which is antiferromagnetic)
the ferro- and antiferromagnetic states are calculated to be essentially
degenerate. The band structure of the ferromagnetic states is very close to
half metallic.Comment: 17 pages, containing 10 postscript figures and 5 tables. Two
additional figures (Fig.8 and 11 of the paper) are provided in JPG format in
separate files. Submitted to Phys. Rev. B on September 20th 200
CDH1 mutation distribution and type suggests genetic differences between the etiology of orofacial clefting and gastric cancer
Pathogenic variants in CDH1, encoding epithelial cadherin (E-cadherin), have been implicated in hereditary diffuse gastric cancer (HDGC), lobular breast cancer, and both syndromic and non-syndromic cleft lip/palate (CL/P). Despite the large number of CDH1 mutations described, the nature of the phenotypic consequence of such mutations is currently not able to be predicted, creating significant challenges for genetic counselling. This study collates the phenotype and molecular data for available CDH1 variants that have been classified, using the American College of Medical Genetics and Genomics criteria, as at least âlikely pathogenicâ, and correlates their molecular and structural characteristics to phenotype. We demonstrate that CDH1 variant type and location differ between HDGC and CL/P, and that there is clustering of CL/P variants within linker regions between the extracellular domains of the cadherin protein. While these differences do not provide for exact prediction of the phenotype for a given mutation, they may contribute to more accurate assessments of risk for HDGC or CL/P for individuals with specific CDH1 variants
Ab-Initio Calculation of Molecular Aggregation Effects: a Coumarin-343 Case Study
We present time-dependent density functional theory (TDDFT) calculations for
single and dimerized Coumarin-343 molecules in order to investigate the quantum
mechanical effects of chromophore aggregation in extended systems designed to
function as a new generation of sensors and light-harvesting devices. Using the
single-chromophore results, we describe the construction of effective
Hamiltonians to predict the excitonic properties of aggregate systems. We
compare the electronic coupling properties predicted by such effective
Hamiltonians to those obtained from TDDFT calculations of dimers, and to the
coupling predicted by the transition density cube (TDC) method. We determine
the accuracy of the dipole-dipole approximation and TDC with respect to the
separation distance and orientation of the dimers. In particular, we
investigate the effects of including Coulomb coupling terms ignored in the
typical tight-binding effective Hamiltonian. We also examine effects of orbital
relaxation which cannot be captured by either of these models
Nucleation of a sodium droplet on C60
We investigate theoretically the progressive coating of C60 by several sodium
atoms. Density functional calculations using a nonlocal functional are
performed for NaC60 and Na2C60 in various configurations. These data are used
to construct an empirical atomistic model in order to treat larger sizes in a
statistical and dynamical context. Fluctuating charges are incorporated to
account for charge transfer between sodium and carbon atoms. By performing
systematic global optimization in the size range 1<=n<=30, we find that Na_nC60
is homogeneously coated at small sizes, and that a growing droplet is formed
above n=>8. The separate effects of single ionization and thermalization are
also considered, as well as the changes due to a strong external electric
field. The present results are discussed in the light of various experimental
data.Comment: 17 pages, 10 figure
The electronic structure of amorphous silica: A numerical study
We present a computational study of the electronic properties of amorphous
SiO2. The ionic configurations used are the ones generated by an earlier
molecular dynamics simulations in which the system was cooled with different
cooling rates from the liquid state to a glass, thus giving access to
glass-like configurations with different degrees of disorder [Phys. Rev. B 54,
15808 (1996)]. The electronic structure is described by a tight-binding
Hamiltonian. We study the influence of the degree of disorder on the density of
states, the localization properties, the optical absorption, the nature of
defects within the mobility gap, and on the fluctuations of the Madelung
potential, where the disorder manifests itself most prominently. The
experimentally observed mismatch between a photoconductivity threshold of 9 eV
and the onset of the optical absorption around 7 eV is interpreted by the
picture of eigenstates localized by potential energy fluctuations in a mobility
gap of approximately 9 eV and a density of states that exhibits valence and
conduction band tails which are, even in the absence of defects, deeply located
within the former band gap.Comment: 21 pages of Latex, 5 eps figure
On inelastic hydrogen atom collisions in stellar atmospheres
The influence of inelastic hydrogen atom collisions on non-LTE spectral line
formation has been, and remains to be, a significant source of uncertainty for
stellar abundance analyses, due to the difficulty in obtaining accurate data
for low-energy atomic collisions either experimentally or theoretically. For
lack of a better alternative, the classical "Drawin formula" is often used.
Over recent decades, our understanding of these collisions has improved
markedly, predominantly through a number of detailed quantum mechanical
calculations. In this paper, the Drawin formula is compared with the quantum
mechanical calculations both in terms of the underlying physics and the
resulting rate coefficients. It is shown that the Drawin formula does not
contain the essential physics behind direct excitation by H atom collisions,
the important physical mechanism being quantum mechanical in character.
Quantitatively, the Drawin formula compares poorly with the results of the
available quantum mechanical calculations, usually significantly overestimating
the collision rates by amounts that vary markedly between transitions.Comment: 9 pages, 6 figures, accepted for A&
Measurement of the scintillation time spectra and pulse-shape discrimination of low-energy beta and nuclear recoils in liquid argon with DEAP-1
The DEAP-1 low-background liquid argon detector was used to measure
scintillation pulse shapes of electron and nuclear recoil events and to
demonstrate the feasibility of pulse-shape discrimination (PSD) down to an
electron-equivalent energy of 20 keV.
In the surface dataset using a triple-coincidence tag we found the fraction
of beta events that are misidentified as nuclear recoils to be (90% C.L.) for energies between 43-86 keVee and for a nuclear recoil
acceptance of at least 90%, with 4% systematic uncertainty on the absolute
energy scale. The discrimination measurement on surface was limited by nuclear
recoils induced by cosmic-ray generated neutrons. This was improved by moving
the detector to the SNOLAB underground laboratory, where the reduced background
rate allowed the same measurement with only a double-coincidence tag.
The combined data set contains events. One of those, in the
underground data set, is in the nuclear-recoil region of interest. Taking into
account the expected background of 0.48 events coming from random pileup, the
resulting upper limit on the electronic recoil contamination is
(90% C.L.) between 44-89 keVee and for a nuclear recoil
acceptance of at least 90%, with 6% systematic uncertainty on the absolute
energy scale.
We developed a general mathematical framework to describe PSD parameter
distributions and used it to build an analytical model of the distributions
observed in DEAP-1. Using this model, we project a misidentification fraction
of approx. for an electron-equivalent energy threshold of 15 keV for
a detector with 8 PE/keVee light yield. This reduction enables a search for
spin-independent scattering of WIMPs from 1000 kg of liquid argon with a
WIMP-nucleon cross-section sensitivity of cm, assuming
negligible contribution from nuclear recoil backgrounds.Comment: Accepted for publication in Astroparticle Physic
Mechanical and Electronic Properties of MoS Nanoribbons and Their Defects
We present our study on atomic, electronic, magnetic and phonon properties of
one dimensional honeycomb structure of molybdenum disulfide (MoS) using
first-principles plane wave method. Calculated phonon frequencies of bare
armchair nanoribbon reveal the fourth acoustic branch and indicate the
stability. Force constant and in-plane stiffness calculated in the harmonic
elastic deformation range signify that the MoS nanoribbons are stiff quasi
one dimensional structures, but not as strong as graphene and BN nanoribbons.
Bare MoS armchair nanoribbons are nonmagnetic, direct band gap
semiconductors. Bare zigzag MoS nanoribbons become half-metallic as a
result of the (2x1) reconstruction of edge atoms and are semiconductor for
minority spins, but metallic for the majority spins. Their magnetic moments and
spin-polarizations at the Fermi level are reduced as a result of the
passivation of edge atoms by hydrogen. The functionalization of MoS
nanoribbons by adatom adsorption and vacancy defect creation are also studied.
The nonmagnetic armchair nanoribbons attain net magnetic moment depending on
where the foreign atoms are adsorbed and what kind of vacancy defect is
created. The magnetization of zigzag nanoribbons due to the edge states is
suppressed in the presence of vacancy defects.Comment: 11 pages, 5 figures, first submitted at November 23th, 200
- âŠ