Pt-impregnated catalysts on powdery SiC and other commercial supports for the combustion of hydrogen under oxidant conditions

We report the study of the catalytic hydrogen combustion over Pt-impregnated powdery silicon carbide (SiC) using H2PtCl6 as precursor. The reaction was conducted in excess of oxygen. β-SiC was selected for the study because of its thermal conductivity, mechanical properties, chemical inertness and surface area. The obtained Pt particles over SiC were medium size (average particle diameter of 5 nm for 0.5 wt% Pt). The activity of the Pt-impregnated catalyst over SiC was compared to those obtained in oxidized form over TiO2 and Al2O3 commercial supports (Pt particles very small in size, average particle diameter of 1 nm for 0.5 wt% Pt in both cases). The case of a SiO2 support was also discussed. Those Pt/SiC particles were the most active because of their higher contribution of surface Pt0, indicating that partially oxidized surfaces have better activity than those totally oxidized in these conditions. SiC was modified with an acid treatment and thus bigger (average particle diameter of 7 nm for 0.5 wt% Pt) and more active Pt particles were obtained. Durability of the SiC and TiO2 supported catalysts was tested upon 5 cycles and both have shown to be durable and even more active than initially. Exposure to the oxidative reaction mixture activates the catalysts and the effect is more pronounced for the completely oxidized particles. This is due to the surface oxygen chemisorption which activates catalystś surface.Junta de Andalucía PE2012-TEP862Ministerio de Economía y Competitividad CTQ2012-32519, CTQ2015-65918-RConsejo Superior de Investigaciones Científicas PIE-201460E01

A Feature-Based Comparison of Evolutionary Computing Techniques for Constrained Continuous Optimisation

Evolutionary algorithms have been frequently applied to constrained continuous optimisation problems. We carry out feature based comparisons of different types of evolutionary algorithms such as evolution strategies, differential evolution and particle swarm optimisation for constrained continuous optimisation. In our study, we examine how sets of constraints influence the difficulty of obtaining close to optimal solutions. Using a multi-objective approach, we evolve constrained continuous problems having a set of linear and/or quadratic constraints where the different evolutionary approaches show a significant difference in performance. Afterwards, we discuss the features of the constraints that exhibit a difference in performance of the different evolutionary approaches under consideration.Comment: 16 Pagesm 2 Figure

Search for associations containing young stars (SACY) VII. New stellar and substellar candidate members in the young associations

The young associations offer us one of the best opportunities to study the properties of young stellar and substellar objects and to directly image planets thanks to their proximity ($<$200 pc) and age ($\approx$5-150 Myr). However, many previous works have been limited to identifying the brighter, more active members ($\approx$1 M$_\odot$) owing to photometric survey sensitivities limiting the detections of lower mass objects. We search the field of view of 542 previously identified members of the young associations to identify wide or extremely wide (1000-100,000 au in physical separation) companions. We combined 2MASS near-infrared photometry ($J$, $H$, $K$) with proper motion values (from UCAC4, PPMXL, NOMAD) to identify companions in the field of view of known members. We collated further photometry and spectroscopy from the literature and conducted our own high-resolution spectroscopic observations for a subsample of candidate members. This complementary information allowed us to assess the efficiency of our method. We identified 84 targets (45: 0.2-1.3 M$_\odot$, 17: 0.08-0.2 M$_\odot$, 22: $<$0.08 M$_\odot$) in our analysis, ten of which have been identified from spectroscopic analysis in previous young association works. For 33 of these 84, we were able to further assess their membership using a variety of properties (X-ray emission, UV excess, H$_\alpha$, lithium and K I equivalent widths, radial velocities, and CaH indices). We derive a success rate of 76-88% for this technique based on the consistency of these properties. Once confirmed, the targets identified in this work would significantly improve our knowledge of the lower mass end of the young associations. Additionally, these targets would make an ideal new sample for the identification and study of planets around nearby young stars.Comment: 28 pages, 24 figures, accepted in A&

Diagnóstico Prénatal de Hemocromatose Neonatal: Será possível?

Introdução: A Hemocromatose Neonatal é uma doença hepática rara de início intrauterino, definida por insuficiência hepática neonatal associada a siderose extra-hepática. A doença hepática gestacional aloimune foi estabelecida como causa da lesão hepática fetal. Atualmente, não existe uma abordagem eficaz para o diagnóstico prénatal. Caso Clínico: Grávida de 23 anos apresentou às 32 semanas de gestação oligohidrâmnios e focos hepáticos hiperecogénicos. O recém-nascido prematuro desenvolveu falência orgânica multissistémica e faleceu ao segundo dia de vida, apesar de cuidados de suporte intensivos. A autópsia permitiu o diagnóstico de Hemocromatose Neonatal. Conclusão: A identificação ecográfica de focos nodulares hiperecogénicos no fígado fetal pode ser sugestiva de Hemocromatose Neonatal. Investigações adicionais são necessárias para identificar o complexo aloimunitário específico no sangue materno. O estabelecimento do diagnóstico num feto ou recém- -nascido afetado pode ter um grande impacto no prognóstico da doença e no desfecho de futuras gravidezes

Dynamical evolution of active detached binaries on log Jo - log M diagram and contact binary formation

Orbital angular momentum (Jo), systemic mass (M) and orbital period (P) distributions of chromospherically active binaries (CAB) and W Ursae Majoris (W UMa) systems were investigated. The diagrams of log Jo - log P, log M - log P and log Jo-log M were formed from 119 CAB and 102 W UMa stars. The log Jo-log M diagram is found to be most meaningful in demonstrating dynamical evolution of binary star orbits. A slightly curved borderline (contact border) separating the detached and the contact systems was discovered on the log Jo - log M diagram. Since orbital size (a) and period (P) of binaries are determined by their current Jo, M and mass ratio q, the rates of orbital angular momentum loss (dlog Jo/dt) and mass loss (dlog M/dt) are primary parameters to determine the direction and the speed of the dynamical evolution. A detached system becomes a contact system if its own dynamical evolution enables it to pass the contact border on the log Jo - log M diagram. Evolution of q for a mass loosing detached system is unknown unless mass loss rate for each component is known. Assuming q is constant in the first approximation and using the mean decreasing rates of Jo and M from the kinematical ages of CAB stars, it has been predicted that 11, 23 and 39 cent of current CAB stars would transform to W UMa systems if their nuclear evolution permits them to live 2, 4 and 6 Gyrs respectively.Comment: 28 pages, including 6 figures and 2 tables, accepted for publication in MNRA