Study of the Barringer Refractor Plate Correlation Spectrometer as a remote sensing instrument

Barringer refractor plate correlation spectrometer as remote sensing instrument of pollutant gases in atmospher

Ternary and quaternary oxides of Bi, Sr, and Cu

Before the discovery of superconductivity in an oxide of Bi, Sr, and Cu, the system Bi-Sr-Cu-O had not been studied, although several solid phases had been identified in the two-component regions of the ternary system Bi2O3-SrO-CuO. The oxides Sr2CuO3, SrCu2O2, SrCuO2, and Bi2CuO4 were then well known and characterized, and the phase diagram of the binary system Bi2O3 -SrO had been established in the temperature range 620 to 1000 C. Besides nine solutions of compositions Bi(2-2x) Sr(x) O(3-2x) and different symmetries, this diagram includes three definite compounds of stoichiometries Bi(2)SrO4, Bi2Sr2O5, and Bi2Sr3O6 (x = 0.50, 0.67 and 0.75 respectively), only the second of which with known unit-cell of orthorhombic symmetry, dimensions (A) a = 14.293(2), b = 7.651(2), c = 6.172(1), and z = 4. The first superconducting oxide in the system Bi-Sr-Cu-O was initially formulated as Bi2Sr2Cu2O(7+x), with an orthorhombic unit-cell of parameters (A) a = 5.32, b = 26.6, c = 48.8. In a preliminary study the same oxide was formulated with half the copper content, Bi(2)Sr(2)CuO(6+x), and indexed its reflections assuming an orthorhombic unit-cell of dimensions (A) a = 5.390(2), b = 26.973(8), c = 24.69(4). Subsequent studies by diffraction techniques have confirmed the composition 2:2:1. A new family of oxygen-deficient perovskites, was characterized, after identifying by x ray diffraction the phases present in the products of thermal treatments of about 150 mixtures of analytical grade Bi2O3, Sr(OH)2-8H2O and CuO at different molar ratios. X ray diffraction data are presented for some other oxides of Bi and Sr, as well as for various quaternary oxides, among them an oxide of Bi, Sr, and Cu

Acidosis Is a Key Regulator of Osteoblast Ecto-Nucleotidase Pyrophosphatase/Phosphodiesterase 1 (NPP1) Expression and Activity

Previous work has shown that acidosis prevents bone nodule formation by osteoblasts in vitro by inhibiting mineralisation of the collagenous matrix. The ratio of phosphate (Pi) to pyrophosphate (PPi) in the bone microenvironment is a fundamental regulator of bone mineralisation. Both Pi and PPi, a potent inhibitor of mineralisation, are generated from extracellular nucleotides by the actions of ecto‐nucleotidases. This study investigated the expression and activity of ecto‐nucleotidases by osteoblasts under normal and acid conditions. We found that osteoblasts express mRNA for a number of ecto‐nucleotidases including NTPdase 1–6 (ecto‐nucleoside triphosphate diphosphohydrolase) and NPP1‐3 (ecto‐nucleotide pyrophosphatase/phosphodiesterase). The rank order of mRNA expression in differentiating rat osteoblasts (day 7) was Enpp1 > NTPdase 4 > NTPdase 6 > NTPdase 5 > alkaline phosphatase > ecto‐5‐nucleotidase > Enpp3 > NTPdase 1 > NTPdase 3 > Enpp2 > NTPdase 2. Acidosis (pH 6.9) upregulated NPP1 mRNA (2.8‐fold) and protein expression at all stages of osteoblast differentiation compared to physiological pH (pH 7.4); expression of other ecto‐nucleotidases was unaffected. Furthermore, total NPP activity was increased up to 53% in osteoblasts cultured in acid conditions (P < 0.001). Release of ATP, one of the key substrates for NPP1, from osteoblasts, was unaffected by acidosis. Further studies showed that mineralised bone formation by osteoblasts cultured from NPP1 knockout mice was increased compared with wildtypes (2.5‐fold, P < 0.001) and was partially resistant to the inhibitory effect of acidosis. These results indicate that increased NPP1 expression and activity might contribute to the decreased mineralisation observed when osteoblasts are exposed to acid conditions

Shannon entropy and particle decays

We deploy Shannon's information entropy to the distribution of branching fractions in a particle decay. This serves to quantify how important a given new reported decay channel is, from the point of view of the information that it adds to the already known ones. Because the entropy is additive, one can subdivide the set of channels and discuss, for example, how much information the discovery of a new decay branching would add; or subdivide the decay distribution down to the level of individual quantum states (which can be quickly counted by the phase space). We illustrate the concept with some examples of experimentally known particle decay distributions.Comment: 12 pages, 18 plots; to appear in Nuclear Physics

Imaging the asymmetric dust shell around CI Cam with long baseline optical interferometry

We present the first high angular resolution observation of the B[e] star/X-ray transient object CI Cam, performed with the two-telescope Infrared Optical Telescope Array (IOTA), its upgraded three-telescope version (IOTA3T) and the Palomar Testbed Interferometer (PTI). Visibilities and closure phases were obtained using the IONIC-3 integrated optics beam combiner. CI Cam was observed in the near-infrared H and K spectral bands, wavelengths well suited to measure the size and study the geometry of the hot dust surrounding CI Cam. The analysis of the visibility data over an 8 year period from soon after the 1998 outburst to 2006 shows that the dust visibility has not changed over the years. The visibility data shows that CI Cam is elongated which confirms the disc-shape of the circumstellar environment and totally rules out the hypothesis of a spherical dust shell. Closure phase measurements show direct evidence of asymmetries in the circumstellar environment of CI Cam and we conclude that the dust surrounding CI Cam lies in an inhomogeneous disc seen at an angle. The near-infrared dust emission appears as an elliptical skewed Gaussian ring with a major axis a = 7.58 +/- 0.24 mas, an axis ratio r = 0.39 +/- 0.03 and a position angle theta = 35 +/- 2 deg.Comment: 9 pages, 5 figures, accepted MNRA

Extraction of phenolic compounds in controlled macerations of Pedro Ximenez grapes

Crushed grapes of cv. Pedro Ximenez were macerated together with their must for 4, 16, 24 and 48 h at temperatures of 10, 15 and 25°C. The musts obtained after pressing were used for the determination of 14 phenolic compounds from the following fractions: hydroxybenzoic acids, hydroxycinnamic acids, other nonflavonoids, flavan-3-ols and flavonols. The temperature was found not to exert a marked influence on the extraction of the phenolic compounds in the first 16 h of maceration. After that time, however, it had a significant effect, so maceration times longer than 16 h are inadvisable unless subsequent oxidation is applied. The analytical results obtained showed that the flavan-3-ols, catechin and epicatechin were extracted at the highest rates, related with maceration temperature, followed by hydroxbenzoic acids, other nonflavonoids, hydroxycinnamic acids and flavonols. The flavan-3-ol fraction was also extracted in higher proportions under the different conditions assayed, through very closely followed by that of hydroxybenzoic acids

Flavour in "Pedro Ximénez" grape musts subjected to maceration processes

Crushed grapes of  Vitis vinifera cv. Pedro Ximenez were macerated at 10, 15 and 25°C for 4, 16, 24 and 48 hours. The musts obtained after pressing were used for the determination of higher alcohols, esters and terpene compounds. The data was subjected to discriminant analysis, obtaining three functions of difficult interpretation. A fruitiness index (SIGMA favourable aromas/SIGMA unfavourable aromas) x 100 and the total of phenolic compounds were subjected to variance and multiple range analyses which revealed significant differences (p&lt;0.01) for maceration times and temperatures. Taking into account the fruitiness index and phenolic compound values, as well as the significant differences obtained by multifactorial (time-temperature) variance analysis, the 24 h-10°C, 4 h-15°C, 16 h-15°C and 24 h-15°C were the best condition

Neural network monitoring of resistance welding processes

Control of weld quality is one of the most important and complex processes to be carried out on production lines. Neural networks have shown good results in fields such as modelling and control of physical processes. It is suggested in this article that a neural classifier should be used to carry out non‐destructive on‐line analysis. This system has been developed and installed at resistance welding stations. Results confirm the validity of neural networks used for this type of application

Science with the Keck Interferometer ASTRA Program

The ASTrometric and phase-Referenced Astronomy (ASTRA) project will provide phase referencing and astrometric observations at the Keck Interferometer, leading to enhanced sensitivity and the ability to monitor orbits at an accuracy level of 30-100 microarcseconds. Here we discuss recent scientific results from ASTRA, and describe new scientific programs that will begin in 2010-2011. We begin with results from the "self phase referencing" (SPR) mode of ASTRA, which uses continuum light to correct atmospheric phase variations and produce a phase-stabilized channel for spectroscopy. We have observed a number of protoplanetary disks using SPR and a grism providing a spectral dispersion of ~2000. In our data we spatially resolve emission from dust as well as gas. Hydrogen line emission is spectrally resolved, allowing differential phase measurements across the emission line that constrain the relative centroids of different velocity components at the 10 microarcsecond level. In the upcoming year, we will begin dual-field phase referencing (DFPR) measurements of the Galactic Center and a number of exoplanet systems. These observations will, in part, serve as precursors to astrometric monitoring of stellar orbits in the Galactic Center and stellar wobbles of exoplanet host stars. We describe the design of several scientific investigations capitalizing on the upcoming phase-referencing and astrometric capabilities of ASTRA.Comment: Published in the proceedings of the SPIE 2010 conference on "Optical and Infrared Interferometry II